Rhinocerotid tooth enamel 18O/16O variability between 23 and 12 Ma in southwestern France

The relationship between the oxygen isotope ratio of mammal tooth enamel and that of drinking water was used to reconstruct changes in the Miocene oxygen isotope ratio of rainfall (meteoric water ${\delta }^{18}$O_MW). These, in turn, are related to climatic parameters (temperature, precipitation and evaporation rate). ${\delta }^{18}$O values of rhinocerotid teeth from the Aquitaine Basin (southwestern France) suggest a significant climatic change between 17 and 12 Ma, characterized by cooling together with precipitation increase, in agreement with other terrestrial and oceanic records. To cite this article: I. Bentaleb et al., C. R. Geoscience 338 (2006).     

Galileo single frequency ionospheric correction: performances in terms of position

For GPS single frequency users, the ionospheric contribution to the error budget is estimated by the well-known Klobuchar algorithm. For Galileo, it will be mitigated by a global algorithm based on the NeQuick model. This algorithm relies on the adaptation of the model to slant Total Electron Content (sTEC) measurements. Although the performance specifications of these algorithms are expressed in terms of delay and TEC, the users might be more interested in their impact on positioning. Therefore, we assessed the ability of the algorithms to improve the positioning accuracy using globally distributed permanent stations for the year 2002 marked by a high level of solar activity. We present uncorrected and corrected performances, interpret these and identify potential causes for Galileo correction discrepancies. We show vertical errors dropping by 56–64 % due to the analyzed ionospheric corrections, but horizontal errors decreasing by 27 % at most. By means of a fictitious symmetric satellite distribution, we highlight the role of TEC gradients in residual errors. We describe mechanisms permitted by the Galileo correction, which combine sTEC adaptation and topside mismodeling, and limit the horizontal accuracy. Hence, we support further investigation of potential alternative ionospheric corrections. We also provide an interesting insight into the ionospheric effects possibly experienced during the next solar maximum coinciding with Galileo Initial Operation Capability.     

Micro- and nano-textural evidence of Ti(–Ca–Fe) mobility during fluid–rock interactions in carbonaceous lawsonite-bearing rocks from New Zealand

Understanding the mobility of chemical elements during fluid–rock interactions is critical to assess the geochemical evolution of a rock undergoing burial and metamorphism and, more generally, to constrain the geochemical budget of the subduction factory. In particular, determining the behavior and mobility of Ti in aqueous fluids constitutes a great challenge that is still under scrutiny. Here, we study plant fossils preserved in blueschist metasedimentary rocks from the Marybank Formation (New Zealand). Using scanning and transmission electron microscopies (SEM and TEM), we show that the carbonaceous material (CM) composing the fossils contains abundant nano-inclusions of Ti- and Fe-oxides. These nanocrystals are mainly anatase, rutile, and Fe–Ti oxides. The mineral composition observed within the fossils is significantly different from that detected in the surrounding rock matrix. We propose that Ti and Fe might have been mobilized by the alteration of a detrital Ti–Fe-rich protolith during an early diagenetic event under acidic and reducing conditions. Aqueous fluids rich in organic ligands released by the degradation of organic matter may have been involved. Moreover, using mass balance and petrological observations, we show that the contrasted mineralogy between the rock matrix and the fossil CM might be the consequence of the chemical isolation of fossil CM during the prograde path of the rock. Such an isolation results from the early formation of quartz and Fe-rich phyllosilicate layers enclosing the fossil as characterized by SEM and TEM investigations. Overall, this study shows that investigating minerals associated with CM down to the nanometer scale in metamorphic rocks can provide a precious record of early prograde geochemical conditions.     

Using experimental data to reduce the single-building sigma of fragility curves: case study of the BRD tower in Bucharest, Romania

The lack of knowledge concerning modelling existing buildings leads to significant variability in fragility curves for single or grouped existing buildings. This study aims to investigate the uncertainties of fragility curves, with special consideration of the single-building sigma. Experimental data and simplified models are applied to the BRD tower in Bucharest, Romania, a RC building with permanent instrumentation. A three-step methodology is applied： （1） adjustment of a linear MDOF model for experimental modal analysis using a Timoshenko beam model and based on Anderson＇s criteria, （2） computation of the structure＇s response to a large set of accelerograms simulated by SIMQKE software, considering twelve ground motion parameters as intensity measurements （IM）, and （3） construction of the fragility curves by comparing numerical interstory drift with the threshold criteria provided by the Hazus methodology for the slight damage state. By introducing experimental data into the model, uncertainty is reduced to 0.02 considering Sd ） as seismic intensity IM and uncertainty related to the model is assessed at 0.03. These values must be compared with the total uncertainty value of around 0.7 provided by the Hazus methodology.     

Re-Os Isotopic Measurements at the Femtomole Level in Natural Samples

Here we describe a new chemical separation method for Os and an improved mass spectrometric procedure for Re and Os. This technique is based on the selective extraction of OsO₄ from aqueous solution in liquid bromine. Among other advantages, this procedure avoids the cumbersome distillation procedure for Os and uses only commercial "off the shelf" PFA teflon labware. Blank levels for 0.5 g sample sizes are: 0.06 pg and 0.5 pg for Os and Re respectively. Samples containing as little as 1 pg g⁻¹ Os can be analysed reliably with this method. Adaptation to other dissolution methods is also discussed.     

The Spatial and Temporal Characteristics of Pc3 Geomagnetic Activity over Canada in 2000, as a Guide to Planning the Times of Aeromagnetic Surveys

Geomagnetic activity affects aeromagnetic surveys. Geomagnetic variations are quite complex and can be quantified in different ways. A measure of geomagnetic activity that is useful for planning aeromagnetic surveys is the Pc3 pulsation index developed by the Australian Space Weather Agency. Purposeful to developing guidelines for planning aeromagnetic surveys in Canada, we study the variations in Pc3 index amplitude over Canada in 2000. This study shows distinct patterns associated with the sub-auroral zone, the auroral zone, and the polar cap. Average Pc3 index activity is higher during the months of February, July, September, and November in the auroral and sub-auroral zones. The station in the polar cap exhibits maximum activity near midday during the summer months. Detailed analysis of a magnetic storm shows that Pc3 index amplitude during the beginning of the solar storm is least important at the polar cap. The mean Pc3 index also relates to solar wind parameters such as the solar wind velocity and the vertical polarity of the interplanetary magnetic field. Analysis of the morning maximum of the Pc3 index observed in the auroral zone can be used to develop guidelines for planning aeromagnetic surveys in Canada and other areas of the world affected by auroral zones.     

Trace element geochemistry of CR chondrite metal

We report trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) of metal grains from nine different CR chondrites, distinguishing grains from chondrule interior (“interior grains”), chondrule surficial shells (“margin grains”), and the matrix (“isolated grains”). Save for a few anomalous grains, Ni‐normalized trace element patterns are similar for all three petrographic settings, with largely unfractionated refractory siderophile elements and depleted volatile Au, Cu, Ag, S. All three types of grains are interpreted to derive from a common precursor approximated by the least‐melted, fine‐grained objects in CR chondrites. This also excludes recondensation of metal vapor as the origin of the bulk of margin grains. The metal precursors were presumably formed by incomplete condensation, with evidence for high‐temperature isolation of refractory platinum‐group‐element (PGE)‐rich condensates before mixing with lower temperature PGE‐depleted condensates. The rounded shape of the Ni‐rich, interior grains shows that they were molten and that they equilibrated with silicates upon slow cooling (1–100 K h^?1), largely by oxidation/evaporation of Fe, hence their high Pd content, for example. We propose that Ni‐poorer, amoeboid margin grains, often included in the pyroxene‐rich periphery common to type I chondrules, result from less intense processing of a rim accreted onto the chondrule subsequent to the melting event recorded by the interior grains. This means either that there were two separate heating events, which formed olivine/interior grains and pyroxene/margin grains, respectively, between which dust was accreted around the chondrule, or that there was a single high‐temperature event, of which the chondrule margin records a late “quenching phase,” in which case dust accreted onto chondrules while they were molten. In the latter case, high dust concentrations in the chondrule‐forming region (at least three orders of magnitude above minimum mass solar nebula models) are indicated.     

Identification of Quaternary thrusts, folds and faults in a low seismicity area: examples in the Southern Alps (France)

In low seismicity areas, folds, faults and striated pebbles in recent alluvial deposits can demonstrate the Quaternary activity of tectonic structures and can reveal their kinematics. In the Digne nappe (Southern Alps), an out-of-sequence thrust occurred in the late Quaternary in response to WSW-trending compression. The presence of late Quaternary compressional deformation in the Valavoire thrust could have resulted from the activity of the underlying Durance flexure with a maximum Pliocene–Quaternary uplift rate of about 0.1 mm yr⁻¹. The Quaternary top surface of the Valensole basin, that truncates SW-vergent thrust propagation folds, is folded above the Lambruissier anticline. Exceptional conditions resulted in the local preservation of this Quaternary fold morphology created with a minimum uplift-rate of 0.05 mm yr⁻¹ under a NE-trending compression. At the front of the Digne nappe the deformation is characterized by WSW to WNW trends of compression and low strain rates during the Quaternary period.     

Calculating the long-term displacement rates of a normal fault from the high-resolution stratigraphic record (early Tethyan rifting, French Alps)

Displacement rates of normal faults deduced from stratigraphic data are often unreliable. Here we calculate the velocity of motion on a normal fault from the variations in accommodation potential on both sides of the fault within a high‐resolution time‐frame established by biostratigraphy and physical stratigraphy. Our example is the Ornon normal fault bounding the Early Jurassic Bourg‐d'Oisans Basin formed during Tethyan rifting. We show that motion on the fault was discontinuous when examined at high resolution and over a long time interval. During a first interval (Hettangian to Sinemurian Arietites bucklandi zone) a low rate of displacement (=202–423 m Myr^?1) coeval with diffused extensional deformation throughout the sedimentary basin is observed. A second interval of localized deformation (Early Sinemurian Caenisites turneri zone) is characterized by higher rates of displacement on the fault (1846 m Myr^?1). Our results concur with recent numerical models identifying the main stages of extensional deformation.     

A 48-kyr-long slip rate history for the Jordan Valley segment of the Dead Sea Fault

We investigate the late Quaternary active deformation along the Jordan Valley segment of the left-lateral Dead Sea Fault and provide new insights on the behaviour of major continental faults. The 110-km-long fault segment shows systematic offsets of drainage systems surveyed at three sites along its southern section. The isotopic dating of six paleoclimatic events yields a precise chronology for the onset of six generations of gully incisions at 47.5 ka BP, 37.5 ka BP, 13 ka BP, 9 ka BP, 7 ka BP, and 5 ka BP. Additionally, detailed mapping and reconstructions provide cumulative displacements for 20 dated incisions along the fault trace. The individual amounts of cumulative slip consistently fall into six distinct classes. This yields: i) an average constant slip rate of 4.7 to 5.1 mm/yr for the last 47.5 kyr and ii) a variable slip rate ranging from 3.5 mm/yr to 11 mm/yr over 2-kyr- to 24-kyr-long intervals. Taking into account that the last large earthquake occurred in AD 1033, we infer 3.5 to 5 m of present-day slip deficit which corresponds to a Mw  7.4 earthquake along the Jordan Valley fault segment. The timing of cumulative offsets reveals slip rate variations critical to our understanding of the slip deficit and seismic cycle along major continental faults.