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541.
Oxygen isotope, mineral trace element, and measured and reconstructed whole-rock compositions are reported for the high MgO eclogite xenolith suite (16 to 20 wt% MgO in the whole rock) from the Koidu Kimberlite complex, Sierra Leone. In contrast to the previously published data for low MgO eclogites (6 to 13 wt% MgO) from this area, high MgO eclogites equilibrated at higher temperatures (1080 to 1130°C vs. 890 to 930°C) have only mantlelike δ18O and show variable degrees of light rare earth element (REE) enrichment. Analyses of multiple mineral generations suggest that the heterogeneous REE patterns of the high MgO eclogites reflect variable degrees of metasomatic overprinting. High MgO and Al2O3 contents of the eclogites suggest a cumulate origin, either as high-pressure (2 to 3 GPa) garnet-pyroxene cumulates or low-pressure (<1 GPa) plagioclase-pyroxene-olivine cumulates. Trace element modeling suggests a low-P origin for eclogites with flat heavy REE patterns and a high-P origin for eclogites with fractionated heavy REE. Flat heavy REE patterns, the presence of Sr anomalies, and low to moderate transition element contents in the low-P group are consistent with a low-pressure origin as metamorphosed olivine gabbros and troctolites. These metagabbroic high MgO eclogites either could represent the basal section of subducted oceanic crust or foundered mafic lower continental crust. In the former case, the metagabbroic high MgO eclogites may be genetically related to the Koidu low MgO suite. Crystal fractionation trends suggest that the metapyroxenitic high MgO eclogites formed at lower pressures than their current estimated equilibrium pressures (>4 GPa).  相似文献   
542.
Standing internal waves, so-called seiches, are ubiquitous in reservoirs and lakes. Although the stratification in such basin is often continuous, the modeling of seiches has been confined mostly to two-layer models. Such models are unable to give reliable insights into the vertical structure of the seiches, which might be crucial for the understanding of vertical mixing in natural water basins. To obtain this kind of information a two-dimensional computer model has been developed, which takes both continuous stratification and bottom topography into account. The results of this model are presented. The computed seiche modes reveal that (1) several large-scale modes can exist with similar eigenfrequencies, (2) the modes have a tendency to develop narrow jets and (3) only the lowest modes are strongly influenced by the bottom topography.  相似文献   
543.
544.
Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct–Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C1 through C5) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg− 1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH4. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH4 concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.  相似文献   
545.
This paper describes a methodology that combines the outputs of (1) the Integrated Model to Assess the Greenhouse Effect (IMAGE Version 1.0) of the Netherlands National Institute of Public Health and Environmental Protection (RIVM) (given a greenhouse gas emission policy, this model can estimate the effects such as global mean surface air temperature change for a wide variety of policies) and (2) ECHAM-1/LSG, the Global Circulation Model (GCM) of the Max-Planck Institute for Meteorology in Hamburg, Germany. The combination enables one to calculate grid point surface air temperature changes for different scenarios with a turnaround time that is much quicker than that for a GCM. The methodology is based upon a geographical pattern of the ratio of grid point temperature change to global mean values during a certain period of the simulation, as calculated by ECHAM-1/LSG for the 1990 Scenarios A and D of the Intergovernmental Panel on Climate Change (IPCC). A procedure, based upon signal-to noise ratios in the outputs, enabled us to estimate where we have confidence in the methodology; this is at about 23% to 83% of the total of 2,048 grid points, depending upon the scenario and the decade in the simulation. It was found that the methodology enabled IMAGE to provide useful estimates of the GCM-predicted grid point temperature changes. These estimates were within 0.5K (0.25K) throughout the 100 years of a given simulation for at least 79% (74%) of the grid points where we are confident in applying the methodology. The temperature ratio pattern from Scenario A enabled IMAGE to provide useful estimates of temperature change within 0.5K (0.25K) in Scenario D for at least 88% (68%) of the grid points where we have confidence; indicating that the methodology is transferable to other scenarios. Tests with the Geophysical Fluid Dynamics Laboratory GCM indicated, however, that a temperature ratio pattern may have to be developed for each GCM. The methodology, using a temperature ratio pattern from the 1990 IPCC Scenario A and involving IMAGE, gave gridded surface air temperature patterns for the 1992 IPCC radiative-forcing Scenarios C and E and the RIVM emission Scenario B; none of these scenarios has been simulated by ECHAM-1/LSG. The simulations reflect the uncertainty range of a future warming.The work reported by the authors was carried out during their stay at the project Forestry and Climate Change of the International Institute for Applied Systems Analysis, Laxenburg, Austria.  相似文献   
546.
547.
Research on the sediment‐surface water transition zone in three study site regions, different in hydrological conditions, was conducted to estimate to which extent nitrate in surface water can contribute to riverbed sediment oxidation and thus prevent release of sediment phosphorus to surface water. Consequently, the Du tch Flow Model (DUFLOW) based water quality model “Spreewald” and results from the emission model “ Mo delling N utrient E missions in Ri ver S ystems” (MONERIS) were used to estimate to which extent wastewater treatment plants (WWTPs) could contribute to the NO3concentration in surface waters if they were operated without denitrification. It is demonstrated that an effective phosphorus retention in sediments by means of surface water NO3is possible only under specific conditions, i. e. (i) a sufficient supply of surface water to the sediment by advective fluxes, (ii) a sufficient amount of sediment iron to provide phosphorus binding sites in the case of sediment oxidation, (iii) a redox system not leading to a rapid NO3 and FeOOH depletion and to phosphorus release from organic pools by high microbial activities. Model results show that in‐stream denitrification processes counteract a significant increase of NO3surface water concentrations from WWTPs operated without denitrification during summer, when eutrophication risk through phosphorus is highest. The increase of NO3surface water concentrations in winter due to decreased denitrification in the surface water is of minor relevance for phosphorus release from sediments.  相似文献   
548.
Pore water of sediments plays an important role in aquatic systems as mediator and as the reactive zone between the sediment and surface water. Sediment pore waters with high ionic strength from acidified pit lakes were investigated to obtain information about the influence on the lake water quality. The analysis of soluble reactive phosphorus, nitrate, ammonium, silica, dissolved organic carbon, ferrous iron, sulfate, chloride, sodium, potassium, calcium, magnesium, manganese, and total dissolved iron was predetermined as the dataset required for evaluation of water quality. The data collection procedure was optimised by designing a methodology for stabilisation, dilution of pore water samples and adaptation of analytical methods. The developed methodology was evaluated with respect to the effort required in the laboratory under routine conditions. In the first round of analyses, 72% of 638 individual analyses from a random selection of pore water profiles were found to be within the calibration ranges. Remedial actions to handle the remaining 28% of invalid analytical results are exemplified. Differences between comparative analyses of some ions by continuous flow analysis, ion chromatography, and atomic emission spectroscopy were evaluated. The majority of results measured by ion chromatography differed on a highly significant level from results measured by atomic emission spectroscopy. Possible reasons, originating from the extreme sample matrix, are discussed. Finally, the designed methodology and the results of the method comparison are used to recommend the selection of analytical methods under specific conditions.  相似文献   
549.
A basin-wide change from an older homogeneous bioturbated to a younger laminated facies occurs in sediments from the 26-m-deep, permanently anoxic Store Lungegårdsvannet fjord. The younger facies consists of alternating packages of light and dark layers, each containing millimetre-scale laminae. The composition of the dark layers differs from that of the light layers in the occurrence of predominantly marine benthic diatoms, larger grain size, lower loss-on-ignition (LOI) and lower trace metal (Cu, Pb, Zn) concentrations. Total trace metal concentrations correlate with the redox-sensitive trace elements Mo and V (r>0.8) and with LOI (r=0.6). The correlation of the minerogenic matter and the grain-size related elements Al and Li is poor (r=0.2). The shoaling of the sill depth and reduction of the fjord area resulting in the reduction of bottom water exchange accounted for the shift from bioturbated to laminated sediments during the end of the last century. The alternating changes within the laminated facies are the result of alternating wind forces. During years of calm wind conditions (1908-1919 and 1945-1961), undisturbed sedimentation of organic matter from primary production and an associated accumulation of trace metals prevail. Years of high wind force (1919-1945 and 1961-1991) trigger shore erosion and an increased influx of minerogenic matter.  相似文献   
550.
We propose a method to remove the mass-sheet degeneracy that arises when the mass of galaxy clusters is inferred from gravitational shear. The method utilizes high-redshift standard candles that undergo weak lensing. Natural candidates for such standard candles are type Ia supernovae (SNe Ia).
When corrected with the light-curve shape (LCS), the peak magnitude of SNe Ia provides a standard candle with an uncertainty in apparent magnitude of Δ m ≃0.1–0.2. Gravitational magnification of a background SN Ia by an intervening cluster would cause a mismatch between the observed SN Ia peak magnitude compared with that expected from its LCS and redshift. The average detection rate for SNe Ia with a significant mismatch of ≥2Δ m behind a cluster at z ≃0.05–0.15 is about 1–2 supernovae per cluster per year at J , I , R ≲25–26.
Since SNe are point-like sources for a limited period, they can experience significant microlensing by massive compact halo objects (MACHOs) in the intracluster medium. Microlensing events caused by MACHOs of ∼10−4 M⊙ are expected to have time-scales similar to that of the SN light curve. Both the magnification curve by a MACHO and the light curve of a SN Ia have characteristic shapes that allow us to separate them. Microlensing events caused by MACHOs of smaller mass can unambiguously be identified in the SN light curve if the latter is continuously monitored. The average number of identifiable microlensing events per nearby cluster ( z ≲0.05) per year is ∼0.02 ( f /0.01), where f is the fraction of the cluster mass in MACHOs of masses 10−7< M macho/M⊙<10−4.  相似文献   
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