Lithium isotope geochemistry of marine pore waters - Insights from cold seep fluids

Lithium concentration and isotope data (δ⁷Li) are reported for pore fluids from 18 cold seep locations together with reference fluids from shallow marine environments, a sediment-hosted hydrothermal system and two Mediterranean brine basins. The new reference data and literature data of hydrothermal fluids and pore fluids from the Ocean Drilling Program follow an empirical relationship between Li concentration and δ⁷Li (δ⁷Li = −6.0(±0.3) · ln[Li] + 51(±1.2)) reflecting Li release from sediment or rocks and/or uptake of Li during mineral authigenesis. Cold seep fluids display δ⁷Li values between +7.5‰ and +45.7‰, mostly in agreement with this general relationship. Ubiquitous diagenetic signals of clay dehydration in all cold seep fluids indicate that authigenic smectite-illite is the major sink for light pore water Li in deeply buried continental margin sediments. Deviations from the general relationship are attributed to the varying provenance and composition of sediments or to transport-related fractionation trends. Pore fluids on passive margins receive disproportionally high amounts of Li from intensely weathered and transported terrigenous matter. By contrast, on convergent margins and in other settings with strong volcanogenic input, Li concentrations in pore water are lower because of intense Li uptake by alteration minerals and, most notably, adsorption of Li onto smectite. The latter process is not accompanied by isotope fractionation, as revealed from a separate study on shallow sediments. A numerical transport-reaction model was applied to simulate Li isotope fractionation during upwelling of pore fluids. It is demonstrated that slow pore water advection (order of mm a⁻¹) suffices to convey much of the deep-seated diagenetic Li signal into shallow sediments. If carefully applied, Li isotope systematics may, thus, provide a valuable record of fluid/mineral interaction that has been inherited several hundreds or thousands of meters below the actual seafloor fluid escape structure.     

Subsurface storm flow formation at different hillslopes and implications for the ‘old water paradox’

Although many studies over the past several decades have documented the importance of subsurface stormflow (SSF) in hillslopes, its formation is still not well understood. Therefore, we studied SSF formation in the vadose soil zone at four different hillslopes during controlled sprinkling experiments and natural rainfall events. Event and pre‐event water fractions were determined using artificially traced sprinkling water and ²²²Rn as natural tracer. SSF formation and the fraction of pre‐event water varied substantially at different hillslopes. Both intensity of SSF and fraction of pre‐event water depended on whether SSF in preferential flow paths was fed directly from precipitation or was fed indirectly from saturated parts of the soil. Soil water was rapidly mobilized from saturated patches in the soil matrix and was subsequently released into larger pores, where it mixed with event water. Substantial amounts of pre‐event water, therefore, were contained in fast flow components like subsurface storm flow and also in overland flow. This finding has consequences for commonly used hydrograph separation methods and might explain part of the ‘old water paradox’. Copyright © 2007 John Wiley & Sons, Ltd.     

Erprobung des Dreissena-Monitors,eines neuen Biotestsystems mit der Zebramuschel (Dreissena polymorpha), in der Rhein-Gütemeßstation Karlsruhe Evaluation of the Dreissena-monitor at the River Rhine — a New Biological Monitoring System Based on the Zebra Mussel Dreissena polymorpha

Object of the present study is a new biomonitor using Dreissena polymorpha PALLAS as testorganism. The status of the shell gape and the valve movements are parameters to indicate toxic discharges. With the aid of some toxicity tests using trichloroethylene, chloroform, ethylparathion, and copper(II)sulfate, the detection efficiency of the “Dreissena-monitor” was described and compared with those of biomonitors in literature. The use of the monitors in the control of sewage, drinking water, and natural waters is discussed. The critical concentrations at which an alarm was set by the “Dreissena-monitor” were 0.03 to 0.1 mg/L with copper(II)sulfate, 7.5 to 8.2 mg/L with trichloroethylene, 33 mg/L with chloroform, and 0.8 to 0.9 mg/L ethyl parathion. Thereby, the alarm was always set within 5 to 35 minutes. Possible fields of application are especially the control of sewage effluents and their immediate environments.     

Spatio‐temporal variability of water and energy fluxes – a case study for a mesoscale catchment in pre‐alpine environment

Water and energy fluxes at and between the land surface, the subsurface and the atmosphere are inextricably linked over all spatio‐temporal scales. Our research focuses on the joint analysis of both water and energy fluxes in a pre‐alpine catchment (55 km²) in southern Germany, which is part of the Terrestrial Environmental Observatories (TERENO). We use a novel three‐dimensional, physically based and distributed modelling approach to reproduce both observed streamflow as an integral measure for water fluxes and heat flux and soil temperature measurements at an observation location over a period of 2 years. While heat fluxes are often used for comparison of the simulations of one‐dimensional land surface models, they are rarely used for additional validation of physically based and distributed hydrological modelling approaches. The spatio‐temporal variability of the water and energy balance components and their partitioning for dominant land use types of the study region are investigated. The model shows good performance for simulating daily streamflow (Nash–Sutcliffe efficiency > 0.75). Albeit only streamflow measurements are used for calibration, the simulations of hourly heat fluxes and soil temperatures at the observation site also show a good performance, particularly during summer. A limitation of the model is the simulation of temperature‐driven heat fluxes during winter, when the soil is covered by snow. An analysis of the simulated spatial fields reveals heat flux patterns that reflect the distribution of the land use and soil types of the catchment. The water and energy partitioning is characterized by a strong seasonal cycle and shows clear differences between the selected land use types. Copyright © 2016 The Authors Hydrological Processes Published by John Wiley & Sons Ltd.