Deriving characteristic parameters of the convective boundary layer from sodar measurements of the vertical velocity variance

This paper deals with the derivation of the convective mixing height and the characteristic convective velocity w _* from profiles of _w measured by sodar. The parameters were obtained by fitting an analytical profile to the observed data. Results were compared with values obtained by the meteorological preprocessor of a dispersion model and from noon radiosoundings. In addition, a Monte Carlo method was applied to study the influence of measurement errors. It turned out that it is inherently difficult to determine the depth of deep mixed layers from sodar measurements with a limited range, although the determination of w _* should be possible. However, a significant underestimation of _w , and thus w _*, was found, which is probably due to disproportional sampling of updrafts and downdrafts.     

Modelling the multiphase near-surface chemistry related to ozone depletions in polar spring

Near-total depletions of ozone have been observed in the Arctic spring since the mid 1980s. The autocatalytic reaction cycles involving reactive halogens are now recognized to be of main importance for ozone depletion events in the polar boundary layer. We present sensitivity studies using the model MISTRA in the box-model mode on the influence of chemical species on these ozone depletion processes. In order to test the sensitivity of the chemistry under polar conditions, we compared base runs undergoing fluxes of either Br₂, BrCl, or Cl₂ to induce ozone depletions, with similar runs including a modification of the chemical conditions. The role of HCHO, H₂O₂, DMS, Cl₂, C₂H₆, HONO, NO₂, and RONO₂ was investigated. Cases with elevated mixing ratios of HCHO, H₂O₂, DMS, Cl₂, and HONO induced a shift in bromine speciation from Br / BrO to HOBr/HBr, while high mixing ratios of C₂H₆ induced a shift from HOBr/HBr to Br/BrO. The shifts from Br/BrO to HOBr/HBr accelerated the aerosol debromination, but also increased the total amount of deposited bromine at the surface (mainly via increased deposition of HOBr). For all NO_y species studied (HONO, NO₂, RONO₂) the chemistry is characterized by an increased bromine deposition on snow reducing the amount of reactive bromine in the air. Ozone is less depleted under conditions of high mixing ratios of NO_x. The production of HNO₃ led to the acid displacement of HCl, and the release of chlorine out of salt aerosol (Cl₂ or BrCl) increased.     

Simulation of daily energy budget and mean soil temperatures at an arid site

Summary Soil temperature is often inadequately based upon relatively few measurements at widely dispersed locations. Within arid regions, such as the desert southwestern United States, soils, microclimates, and thus soil temperature may be markedly heterogeneous. Because extensive measurement of soil temperature is often not feasible, models are needed that simulate soil temperature based on readily available soil survey and above-ground weather information. This paper describes a simple energy-budget based model for simulating daily mean temperatures within a bare arid land soil. The model requires basic information on soil physical properties, and daily weather data including air temperature, windspeed, rainfall, and solar radiation to calculate daily surface energy budget components and surface temperature. One of two alternative numerical methods is then used to calculated subsurface temperatures. Tests of the model using 1987 daily temperature data from an arid site at Yuma, Arizona resulted in root mean square deviations within 1.4°C between daily modeled and measured temperatures at both 0.05 and 0.10 m depths. Sensitivity analysis showed modeled temperatures at 0.05 m depth to be most sensitive to parameters affecting the surface energy balance such as air temperature and solar radiation. Modeled temperatures at 1.0m depth were relatively more sensitive to initial temperature conditions and to parameters affecting distribution of energy within the profile such as thermal conductivity.With 3 Figures     

Investigating suspended particulate matter in coastal waters using the fractal theory

Ocean Dynamics - Suspended particulate matters (SPM) in coastal waters were investigated with an approach combining suspended particulate matter concentrations (SPMCs) measured by an optical...     

Seismic shear distribution among interconnected cantilever walls of different lengths

Mid‐rise to high‐rise buildings in seismic areas are often braced by slender reinforced concrete (RC) walls, which are interconnected by RC floor diaphragms. In design, it is typically assumed that the lateral forces are distributed in proportion to the wall's elastic stiffness. Pushover analyses of systems comprising walls of different lengths have, however, shown that large compatibility forces can develop between them, which should be considered in design, but the analyses have also shown that the magnitude of the computed forces is very sensitive to the modelling assumptions. Using the results of a complex shell element model as benchmark, different simple hand‐calculation methods and inelastic beam element models are assessed and improved to yield reliable estimates of the base shear distribution among the individual walls comprising the interconnected wall system. Copyright © 2014 John Wiley & Sons, Ltd.     

Hydrological modelling for assessing spatio-temporal groundwater recharge variations in the water-stressed Amathole Water Supply System,Eastern Cape,South Africa

To increase the resilience of regional water supply systems in South Africa in the face of anticipated climatic changes and a constant increase in water demand, water supply sources require diversification. Many water-stressed metropolitan regions in South Africa depend largely on surface water to cover their water demand. While climatic and river discharge data is widely available in these regions, information on groundwater resources – which could support supply source diversification – is scarce. Groundwater recharge is a key parameter that is used to estimate groundwater amounts that can be sustainably exploited at a sub-watershed level. Therefore, the objective of this study was to develop a reliable hydrological modelling routine that enables the assessment of regional spatio-temporal variations of groundwater recharge to discern the most promising areas for groundwater development. Accordingly, we present a semi-distributed hydrological modelling approach that incorporates water balance routines coupled with baseflow modelling techniques to yield spatio-temporal variations of groundwater recharge on a regional level. The approach is demonstrated for the actively managed catchment areas of the Amathole Water Supply System situated in a semi-arid part of the Eastern Cape of South Africa. In the investigated study area, annual groundwater recharge exhibits a high spatio-temporal heterogeneity and is estimated to vary between ~0.5% and 8% of annual rainfall. Despite some uncertainties induced by limited data availability, calibration and validation of the model were found to be satisfactory and yielded model results similar to (point) data of annual groundwater recharge reported in earlier studies. Our approach is therefore found to derive crucial information for efficiently targeting more detailed groundwater exploration studies and could work as a blueprint for orientating groundwater potential exploration in similar environments.     

Prograded foredunes of Western Australia's macro‐tidal coast – implications for Holocene sea‐level change and high‐energy wave impacts

The Holocene evolution of the Canning Coast of Western Australia has largely been overlooked so far mainly due to its remoteness and low population density. We report on new data from a sequence of foredunes inside the macro‐tidal Admiral Bay, 110 km southwest of Broome. Based on sediment cores, differential global positioning system (dGPS)‐based elevation transects, and stratigraphical analyses on outcrops of the relict foredunes, we aim at reconstructing Holocene coastal changes and relative sea levels (RSLs), as well as identifying and dating imprints of extreme‐wave events. Sedimentary analyses comprise the documentation of bedding structures, foraminiferal content and macrofaunal remains, grain size distribution, and organic matter. The chronological framework is based on 26 carbon‐14 accelerator mass spectrometry (¹⁴C‐AMS) datings. Marine flooding of the pre‐Holocene surface landward of the 2.5 km‐wide foredune barriers occurred 7400–7200 cal bp , when mangroves colonized the area. After only 200–400 years, a high‐energy inter‐tidal environment established and prevailed until c. 4000 cal bp , before turning into the present supralittoral mudflat. During that time, coastal regression led to beach progradation and the formation of aligned foredunes. Drivers of progradation were a stable RSL or gradual RSL fall after the mid‐Holocene and a positive sand budget. The foredunes overlie upper beach deposits located up to >2 m above the present upper beach level and provide evidence for a higher mid‐Holocene RSL. Discontinuous layers of coarse shells and sand are intercalated in the foredunes, indicating massive coastal flooding events. One such layer was traced over three dune ridges and dated to c. 1700–1550 cal bp . However, it seems that most tropical cyclones induce net erosion rather than deposition at aligned foredunes and thus, they are only suitable for reconstructing temporal variability if erosional features or sedimentation reliably tied to these events can be identified and dated accurately. Copyright © 2014 John Wiley & Sons, Ltd.     

Microbial Degradation of Tar Oil Compounds under Different Redox Conditions

The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.     

On the Effect of Surface Heat-Flux Heterogeneities on the Mixed-Layer-Top Entrainment

We used a set of large-eddy simulations to investigate the effect of one-dimensional stripe-like surface heat-flux heterogeneities on mixed-layer top entrainment. The profiles of sensible heat flux and the temporal evolution of the boundary-layer depth revealed decreased entrainment for small heat-flux amplitudes and increased entrainment for large heat-flux amplitudes, compared to the homogeneously-heated mixed layer. For large heat-flux amplitudes the largest entrainment was observed for patch sizes in the order of the boundary-layer depth, while for significantly smaller or larger patch sizes entrainment was similar as in the homogeneous case. In order to understand the underlying physics of this impact, a new approach was developed to infer local information on entrainment by means of the local flux divergence. We found an entrainment maximum over the centre of the stronger heated surface patch, where thermal energy is accumulated by the secondary circulation (SC) that was induced by the surface heterogeneity. Furthermore, we observed an entrainment maximum over the less heated patch as well, which we suppose is to be linked to the SC-induced horizontal flow convergence at the top of the convective boundary layer (CBL). For small heat-flux amplitudes a counteracting effect dominates that decreases entrainment, which we suppose is the horizontal advection of cold air in the lower, and warm air in the upper, CBL by the SC, stabilizing the CBL and thus weakening thermal convection. Moreover, we found that a mean wind can reduce the heterogeneity-induced impact on entrainment. If the flow is aligned perpendicular to the border between the differentially-heated patches, the SC and thus its impact on entrainment vanishes due to increased horizontal mixing, even for moderate wind speeds. However, if the flow is directed parallel to the border between the differentially-heated patches, the SC and thus its impact on entrainment persists.