The COST733 circulation type classification software: an example for surface ozone concentrations in Central Europe

In the framework of the COST733 Action ??Harmonisation and Applications of Weather Types Classifications for European Regions?? a new circulation type classification software (hereafter, referred to as cost733class software) is developed. The cost733class software contains a variety of (European) classification methods and is flexible towards choice of domain of interest, input variables, time step, number of circulation types, sequencing and (weighted) target variables. This work introduces the capabilities of the cost733class software in which the resulting circulation types (CTs) from various circulation type classifications (CTCs) are applied on observed summer surface ozone concentrations in Central Europe. Firstly, the main characteristics of the CTCs in terms of circulation pattern frequencies are addressed using the baseline COST733 catalogue (cat 2.0), at present the latest product of the new cost733class software. In a second step, the probabilistic Brier skill score is used to quantify the explanatory power of all classifications in terms of the maximum 8 hourly mean ozone concentrations exceeding the 120-??g/m³ threshold; this was based on ozone concentrations from 130 Central European measurement stations. Averaged evaluation results over all stations indicate generally higher performance of CTCs with a higher number of types. Within the subset of methodologies with a similar number of types, the results suggest that the use of CTCs based on optimisation algorithms are performing slightly better than those which are based on other algorithms (predefined thresholds, principal component analysis and leader algorithms). The results are further elaborated by exploring additional capabilities of the cost733class software. Sensitivity experiments are performed using different domain sizes, input variables, seasonally based classifications and multiple-day sequencing. As an illustration, CTCs which are also conditioned towards temperature with various weights are derived and tested similarly. All results exploit a physical interpretation by adapting the environment-to-circulation approach, providing more detailed information on specific synoptic conditions prevailing on days with high surface ozone concentrations. This research does not intend to bring forward a favourite classification methodology or construct a statistical ozone forecasting tool but should be seen as an introduction to the possibilities of the cost733class software. It this respect, the results presented here can provide a basic user support for the cost733class software and the development of a more user- or application-specific CTC approach.     

An exploratory study on the use of enzyme activities as sediment tracers: biochemical fingerprints?

Little information exists on the potential of soil enzyme activities,which are sensitive to soil properties and management,for the characterization of sediment sources at the catchment scale.The objective of this study is to explore and evaluate enzyme activity as tracer for sediment fingerprinting in the Hiv catchment(55 km~2),Iran.Therefore,four enzymes were measured from 42 different sampling sites,covering three sediment source areas(rangeland/surface erosion,orchard/surface erosion,and streambank erosion),as well as from 12 sediment samples from reservoir check dams (sediment sinks).The results indicate that,based upon backward mode discriminant analysis,βglucosidase and dehydrogenase,allowed more than 95%of the samples to be correctly assigned to their source areas.These enzymes were selected as input data for a mixing-model to determine the relative contribution of the sampled sediment sources.The mean contributions from rangeland, orchard and streambank sources in the study area were estimated as 11.3%,15.1%and 73.7%, respectively.Using geochemical tracers,the mean contribution from rangeland,orchard and streambank sources was estimated as 14.1%,9.5%and 74.8%,respectively.Combined biochemical and geochemical tracers,similar values were obtained(18.7%,10.7%and 70.7%,respectively).Our results indicate that soil enzyme activity allows for a good characterization of sediment sources,and can provide a complementary tool to currently existing sediment fingerprinting approaches.However, the method should be also tested in other regions.     

Inter-laboratory comparison of oxygen isotope compositions from biogenic silica

Several techniques have been introduced in the last decades for the dehydration and release of O₂ from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ¹⁸O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ¹⁸O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ¹⁸O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ¹⁸O analyses, available on request through the relevant laboratories.     

Re-assessing the surface cycling of molybdenum and rhenium

We re-evaluate the cycling of molybdenum (Mo) and rhenium (Re) in the near-surface environment. World river average Mo and Re concentrations, initially based on a handful of rivers, are calculated using 38 rivers representing five continents, and 11 of 19 large-scale drainage regions. Our new river concentration estimates are 8.0 nmol kg⁻¹ (Mo), and 16.5 pmol kg⁻¹ (Re, natural + anthropogenic). The linear relationship of dissolved Re and in global rivers (R² = 0.76) indicates labile continental Re is predominantly hosted within sulfide minerals and reduced sediments; it also provides a means of correcting for the anthropogenic contribution of Re to world rivers using independent estimates of anthropogenic sulfate. Approximately 30% of Re in global rivers is anthropogenic, yielding a pre-anthropogenic world river average of 11.2 pmol Re kg⁻¹. The potential for anthropogenic contribution is also seen in the non-negligible Re concentrations in precipitation (0.03-5.9 pmol kg⁻¹), and the nmol kg⁻¹ level Re concentrations of mine waters. The linear Mo- relationship (R² = 0.69) indicates that the predominant source of Mo to rivers is the weathering of pyrite. An anthropogenic Mo correction was not done as anthropogenically-influenced samples do not display the unambiguous metal enrichment observed for Re. Metal concentrations in high temperature hydrothermal fluids from the Manus Basin indicate that calculated end-member fluids (i.e. Mg-free) yield negative Mo and Re concentrations, showing that Mo and Re can be removed more quickly than Mg during recharge. High temperature hydrothermal fluids are unimportant sinks relative to their river sources 0.4% (Mo), and 0.1% (pre-anthropogenic Re). We calculate new seawater response times of 4.4 × 10⁵ yr (τ_Mo) and 1.3 × 10⁵ yr (τ_Re, pre-anthropogenic).     

Phosphate oxygen isotopes: Insights into sedimentary phosphorus cycling from the Benguela upwelling system

Marine sediments are the main sink in the oceanic phosphorus (P) cycle. The activity of benthic microorganisms is decisive for regeneration, reflux, or burial of inorganic phosphate (P_i), which has a strong impact on marine productivity. Recent formation of phosphorites on the continental shelf and a succession of different sedimentary environments make the Benguela upwelling system a prime region for studying the role of microbes in P biogeochemistry. The oxygen isotope signature of pore water phosphate (δ¹⁸O_P) carries characteristic information of microbial P cycling: Intracellular turnover of phosphorylated biomolecules results in isotopic equilibrium with ambient water, while enzymatic regeneration of P_i from organic matter produces distinct offsets from equilibrium. The balance of these two processes is the major control for δ¹⁸O_P.Our study assesses the importance of microbial P cycling relative to regeneration of P_i from organic matter from a transect across the Namibian continental shelf and slope by combining pore water chemistry (sulfate, sulfide, ferrous iron, P_i), steady-state turnover rate modeling, and oxygen isotope geochemistry of P_i.We found δ¹⁸O_P values in a range from 12.8‰ to 26.6‰, both in equilibrium as well as pronounced disequilibrium with water. Our data show a trend towards regeneration signatures (disequilibrium) under low mineralization activity and low P_i concentrations, and microbial turnover signatures (equilibrium) under high mineralization activity and high P_i concentrations. These findings are opposite to observations from water column studies where regeneration signatures were found to coincide with high mineralization activity and high P_i concentrations. It appears that preferential P_i regeneration in marine sediments does not necessarily coincide with a disequilibrium δ¹⁸O_P signature. We propose that microbial P_i uptake strategies, which are controlled by P_i availability, are decisive for the alteration of the isotope signature. This hypothesis is supported by the observation of efficient microbial P_i turnover (equilibrium signatures) in the phosphogenic sediments of the Benguela upwelling system.     

Characteristics of a paleosol and its implication for the Critical Zone development,Rocky Mountain Front Range of Colorado,USA

Activity and stability phases as well as geomorphic processes within the Critical Zone are well known. Erosion and deposition of sediments represent activity; soils represent geomorphic stability phases. Data are presented from a 4 m deep sediment section that was dated by luminescence techniques. Upslope erosion and resulting sedimentation started in the late Pleistocene around 18 ka until 12 ka. Conditions at the study site then changed, which led to the formation of a well-developed soil. Radiocarbon dating of the organic matter yielded ages between 8552 and 8995 cal. BP. From roughly 6.2 to 5.4 ka another activity phase accompanied by according sediment deposition buried the soil and a new soil, a Cambisol, was formed at the surface. The buried soil is a strongly developed Luvisol. The black colors in the upper part of the buried soil are not the result of pedogenic accumulation of normal organic matter within an A-horizon. Nuclear magnetic resonance spectroscopy clearly documents the high amount of aromatic components (charcoal), which is responsible for the dark color. This indicates severe burning events at the site and the smaller charcoal dust (black carbon) was transported to deeper parts of the profile during the process of clay translocation.     

The Northern Giudicarie and the Meran-Mauls fault (Alps,Northern Italy) in the light of new paleomagnetic and geochronological data from boudinaged Eo-/Oligocene tonalites

This study concentrates on small intrusions along two important faults of the Giudicarie fault system, the Northern Giudicarie and the Meran-Mauls fault, summarised under the term tonalitic lamellae. Magnetic fabric analyses in combination with structural field data indicate dextral strike slip deformation along the NE–SW striking northern part of the Giudicarie fault system, the Meran-Mauls fault, overprinted by younger thrusting. The regional stressfield was oriented approximately NNW–SSE during Tertiary times. The distinctive change in deformation along the Meran-Mauls fault from dextral strike slip to top-SE thrusting may be caused by a rotation or bending of the fault after the intrusion of the tonalites and the formation of their horizontal magnetic foliation. Based on the assumption of a preliminary straight Periadriatic lineament bent by the NNW-wards advancement of the Southalpine indenter, the tonalitic lamellae may be interpreted as lenses sheared off from the Adamello batholith during indentation. New U/Pb data on zircon show that some of the lamellae are of Oligocene (Rupelian), others of Late Eocene (Priabonian) age. An amphibole-gabbro lens occurring on the Meran-Mauls fault provides a Middle Eocene (Bartonian) age. Among the major Periadriatic plutons, only the southern units of the Adamello batholith also intruded in the Eocene that suggests a strong correlation between the tonalitic lamellae and the Adamello batholith. The analyses of the remanent magnetisation and the Curie point determinations argue for magnetite as the main carrier of a viscous magnetisation blocked at relatively low temperatures. This indicates slow cooling of the investigated intrusions along the Giudicarie fault system down to approximately 300°C, which is in contrast to the fast cooling determined for the Adamello intrusion units currently at the surface. The new zircon fission track data also show later cooling of the tonalites along the Giudicarie fault system when compared with the Adamello batholith in the south and the Mauls lamellae in the north, indicating that this area contains magmatic bodies exhumed from a deeper structural level than in the Adamello and the Mauls region. This may be due to important top-SE thrusting and transpressive faulting in the footwall of the Northern Giudicarie fault and the Meran-Mauls fault.     

Listric versus planar normal fault geometry: an example from the Eisenstadt-Sopron Basin (E Austria)

In a gravel pit at the eastern margin of the Eisenstadt-Sopron Basin, a satellite of Vienna Basin (Austria), Neogene sediments are exposed in the hanging wall of a major normal fault. The anticlinal structure and associated conjugated secondary normal faults were previously interpreted as a rollover anticline above a listric normal fault. The spatial orientation and distribution of sedimentary horizons and crosscutting faults were mapped in detail on a laser scan of the outcrop wall. Subsequently, in order to assess the 3D distribution and geometry of this fault system, a series of parallel ground penetrating radar (GPR) profiles were recorded behind the outcrop wall. Both outcrop and GPR data were compiled in a 3D structural model, providing the basis for a kinematic reconstruction of the fault plane using balanced cross-section techniques. However, the kinematic reconstruction results in a geologically meaningless normal fault cutting down- and up-section. Additionally, no evidence for a weak layer serving as ductile detachment horizon (i.e. salt or clay horizon) can be identified in stratigraphic profiles. Instead, the observed deflection of stratigraphic horizons may be caused by a displacement gradient along a planar master fault, with a maximum displacement in the fault centre, decreasing towards the fault tips. Accordingly, the observed deflection of markers in the hanging wall—and in a nearby location in the footwall of the normal fault—is interpreted as large-scale fault drag along a planar fault that records a displacement gradient, instead of a rollover anticline related to a listric fault.