A multi-parameter extension of temperature/salinity diagram techniques for the analysis of non-isopycnal mixing

The technique of water mass analysis based on temperature-salinity curves is extended to more than three water masses (or water masses defined by temperature-salinity curves rather than points) by including one or more additional parameters and solving the equations of linear mixing without additional assumptions. The oceanographical significance of the result is studied by means of examples. It is shown that the method is particularly useful for investigations of mesoscale mixing as observed in frontal zones where interleaving and intrusions are commonly observed, and that it can be used for obtaining bulk estimates of the impact of non-isopycnal, small-scale mixing events on the mesoscale fields. Possible parameters are discussed and sources of errors reviewed. Examples are used to show that major nutrients can be used as parameters to detect non-isopycnal mixing although limitations in the historical data and low data accuracy lead to considerable error bounds at present. It is argued that introduction of continuous flow analysis techniques and continuous vertical profiling in marine chemistry will greatly improve the potential of the method.     

Organic carbon content in surface sediments—defining regional provinces

Approaches to quantify the organic carbon accumulation on a global scale generally do not consider the small-scale variability of sedimentary and oceanographic boundary conditions along continental margins. In this study, we present a new approach to regionalize the total organic carbon (TOC) content in surface sediments (<5 cm sediment depth). It is based on a compilation of more than 5500 single measurements from various sources. Global TOC distribution was determined by the application of a combined qualitative and quantitative-geostatistical method. Overall, 33 benthic TOC-based provinces were defined and used to process the global distribution pattern of the TOC content in surface sediments in a 1°×1° grid resolution. Regional dependencies of data points within each single province are expressed by modeled semi-variograms. Measured and estimated TOC values show good correlation, emphasizing the reasonable applicability of the method. The accumulation of organic carbon in marine surface sediments is a key parameter in the control of mineralization processes and the material exchange between the sediment and the ocean water. Our approach will help to improve global budgets of nutrient and carbon cycles.     

The Structure of Coral Communities at Hurghada in the Northern Red Sea

Abstract. The community structure of hard and soft corals, with an emphasis on hard corals, was determined by means of line-transects on 9 on-and off-shore reefs of different type and different wave exposure in the Northern Red Sea near Hurghada in Egypt. Coral communities were found to differentiate along a horizontal wind- and wave-exposure gradient. Exposed communities were dominated by Acropora species, sheltered communities by Porites species, and semi-exposed communities by Millepora species. Also, vertical within-reef zonations following a depth gradient were observed; these were unique for each exposure-determined community type. Average transect diversity was highest on semi-exposed reefs, lowest on sheltered reefs. Reef slopes were more diverse than other reef zones. The observed community structure was compared with data from the literature, and widely distributed, roughly comparable hard and soft coral communities were identified.     

Groundwater isoscapes in a montane headwater catchment show dominance of well‐mixed storage

We conducted an integrated groundwater–surface water monitoring programme in a 3.2‐km² experimental catchment in the Scottish Highlands by sampling all springs, seepages, and wells in six, spatially extensive synoptic surveys over a 2‐year period. The catchment has been glaciated, with steep hillslopes and a flat valley bottom. There is around 70% glacial drift cover in lower areas. The solid geology, which outcrops at higher elevations, is granite and metamorphic schist. The springs and seepages generally occur at the contact between the solid geology and drift or at breaks of slopes in the valley bottom. Samples were analysed for stable isotopes, Gran alkalinity and electrical conductivity. Despite the surveys encompassing markedly different antecedent conditions, the isotopic composition of groundwater at each location exhibited limited temporal variability, resulting in a remarkable persistence of spatial patterns indicating well‐mixed shallow, groundwater stores. Moreover, line‐conditioned excess values derived from the isotope data indicated no evidence of fractionation affecting the groundwater, which suggests that most recharge occurs in winter. The alkalinity and electrical conductivity of groundwater reflected geological differences in the catchment, being highest where more weatherable calcareous rocks outcrop at higher altitudes in the catchment. Springs draining these areas also had the most variable isotope composition, which indicated that they have shorter residence times than the drift covered part of the catchment. The study showed that even in geologically heterogeneous upland catchments, groundwater can be characterized by a consistent isotopic composition, reflecting rapid mixing in the recharge zone. Our work, thus, emphasizes the critical role of groundwater in upland catchments and provides tracer data that can help constrain quantitative groundwater models.     

HESS observations of extragalactic objects

The HESS experiment (High Energy Stereoscopic System), consisting of four imaging atmospheric Cherenkov telescopes (IACTs) in Namibia, has observed many extragalactic objects in the search for very high energy (VHE) γ-ray emission. These objects include active galactic nuclei (AGN), notably Blazars, Seyferts, radio galaxies, starburst galaxies and others. Beyond the established sources, γ-ray emission has been detected for the first time from several of these objects by HESS, and their energy spectra and variability characteristics have been measured. Multi-wavelength campaigns, including X-ray satellites, radio telescopes, and optical observations, have been carried out for AGNs, in particular for PKS 2155-304, H 2356-309 and 1ES 1101-232, for which the implications concerning emission models are presented. Also results from the investigations of VHE flux variability from the giant radio galaxy M 87 are shown. For the HESS Collaboration.     

Investigating young water fractions in a small Mediterranean mountain catchment: Both precipitation forcing and sampling frequency matter

The proportion of water younger than 2–3 months (young water fraction, F_yw) has become increasingly investigated in catchment hydrology. F_yw is typically estimated by comparing seasonal tracer cycles in precipitation and streamflow, through water sampling. However, some open research questions remain, such as: (i) whether part of the summer precipitation should be discarded because the high evapotranspiration demand, (ii) how well F_yw serves as a metric to compare catchments, and (iii) how sampling frequency affects F_yw estimates. To address these questions, we investigated F_yw in soil-, ground- and stream waters for the small Mediterranean Can Vila catchment. Rainfall was sampled at 5-mm intervals. Mobile soil water and groundwater were sampled fortnightly. Stream water was sampled depending on flow at variable time intervals (30 min to 1 week). Over 58 months, this sampling provided 1,529 δ¹⁸O determinations. Isotopic analyses results led us to include summer precipitation in the input signal. We found the highest F_yw in mobile soil waters (34%), while this was almost zero for groundwater except during wet periods. For stream waters, F_yw depended on the discharge variations, so that the flow-weighted young water fraction () was 22.6%, whereas the time-weighted F_yw was just 6.2%. Both and its discharge sensitivity (S_d) varied when different 12-month sampling periods were investigated. The young water fraction that would be obtained from a virtual thorough sampling () was estimated from the S_d and the observed stream flow. This showed an underestimation of by 25% for the frequent dynamic sampling and 66% for weekly sampling, due to missing high flows. Our results confirm that F_yw and its discharge sensitivity are metrics very sensitive to meteorological forcing during the analysed period. Thus, comparisons between catchments need long-term mean annual values and their variability. Our findings also support the dependence of F_yw estimates on the sampling rate and show the advantages of flow-weighted analysis. Finally, catchment water turnover investigations should be accompanied by the analysis of flow duration curves.     

Holocene environmental history in high‐Arctic North Greenland revealed by a combined biomarker and macrofossil approach

In this study, we use a combined biomarker and macrofossil approach to reconstruct the Holocene climate history recorded in Trifna Sø, Skallingen area, eastern North Greenland. Chronological information is derived from comparison of lithological, biogeochemical and macrofossil characteristics with a well‐dated record from nearby Lille Sneha Sø. Following local deglaciation around c. 8 cal. ka BP, the local peak warmth occurred between c. 7.4 and 6.2 cal. ka BP as indicated by maximum macrofossil abundances of warmth‐demanding plants (Salix arctica and Dryas integrifolia) and invertebrates (Daphnia pulex and Chironomidae). Warm conditions were dominated by terrestrial organic matter (OM) sedimentation as implied by the alkane‐based P_aq ratio, but increased aquatic productivity is indicated when temperature was highest around 6.5 cal. ka BP. The n‐C₂₉/n‐C₃₁ alkane ratio shows that vegetation in the catchment was dominated by shrubs after deglaciation, but shifted towards relatively more grassy/herbaceous vegetation during peak warmth. After 5.4 cal. ka BP, the disappearance of warmth‐demanding plant and invertebrate macrofossils indicates cooling in the Skallingen area. This cooling was characterized by a significant shift towards dominance of aquatic OM sedimentation in Trifna Sø as implied by high P_aq ratios. Cooling was also associated with a shift in vegetation type from dwarf‐shrub heaths towards relatively more herbaceous vegetation in the catchment, stronger erosion and more oligotrophic conditions in the lake. Our data show that mean air temperatures inferred using branched glycerol dialkyl glycerol tetraethers (brGDGTs) do not seem to accurately reflect the local climatic history. Irrespective of calibration, methylation of branched tetraethers (MBT) palaeothermometry cannot be reconciled with the macrofossil evidence and seems to be biased by either changing brGDGT sources (in situ vs. soil‐derived) or changing species assemblages and/or an unknown physiological response to changing environmental conditions at high latitude.     

What do biphasic flow experiments reveal on the variability of exposure on alluvial fans and which implications for risk assessment result from this?

Sudden avulsions, unexpected channel migrations and backfilling phenomena are autogenic phenomena that can considerably change the propagation patterns of sediment-laden flows on alluvial fans. Once the initial and boundary conditions of the hazard scenario with a given return period are determined, the assessment of the associated exposed areas is based on one numerical, essentially deterministic, process simulation which may not adequately capture the underlying process variability. We generated sediment-laden flows on an experimental alluvial fan by following a “similarity-of-process concept”. Specifically, we considered a convexly shaped alluvial fan model layout featuring a curved guiding channel. As loading conditions, we defined a reference, an increased and a reduced level for the released water volume and the predisposed solid fraction, respectively. Further, we imposed two different stream power regimes and accomplished, for each factor combination, eight experimental runs. The associated exposure areas were recorded by video and mapped in a GIS. We then analysed exposure data and determined exposure probability maps superposing the footprints of the eight repetitions associated with each experimental loading condition. The patterns of exposure referred to the specific loading conditions showed a noticeable variability related to the main effects of the total event volume, the solid fraction, the interactions between them, and the imposed stream power in the feeding channel. Our research suggests that adopting a probabilistic notion of exposure in risk assessment and mitigation is advisable. Further, a major challenge consists in adapting numerical codes to better reflect the stochastics of process propagation for more reliable flood hazard assessments.

     

On the applicability of viscosity-based capillary bundle concepts to predict the penetration behaviour of polymer solutions into sand

Acta Geotechnica - The increasing use of polymer solutions as support fluids in pile drilling, diaphragm walling or tunnelling applications demands a more detailed discussion of their penetration...