The “Zero-order Model” revisited: Paul Schindler's influence on the development of trace metal scavenging models

In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.     

The point spread function of the soft X-ray telescope aboard Yohkoh

The point spread function of the SXT telescope aboardYohkoh has been measured in flight configuration in three different X-ray lines at White Sands Missile Range. We have fitted these data with an elliptical generalization of the Moffat function. Our fitting method consists of ² minimizationin Fourier space, especially designed for matching of sharply peaked functions. We find excellent fits with a reduced ² of order unity or less for single exposure point spread functions over most of the CCD. Near the edges of the CCD the fits are less accurate due to vignetting. From fitting results with summation of multiple exposures we find a systematic error in the fitting function of the order of 3% near the peak of the point spread function, which is close to the photon noise for typical SXT images in orbit. We find that the full width to half maximum and fitting parameters vary significantly with CCD location. However, we also find that point spread functions measured at the same location are consistent to one another within the limit determined by photon noise. A best analytical fit to the PSF as function of position on the CCD is derived for use in SXT image enhancement routines. As an aside result we have found that SXT can determine the location of point sources to about a quarter of a 2.54 arc sec pixel.This paper is dedicated to the memory of our friend and colleague Kermit Smith, who died in June 1993, after a valient fight with leukemia.     

The American whale oil industry: A look back to the future of the American petroleum industry?

The American whaling industry rose from humble beginnings off Long island to become an international giant. In its peak year, 1846, 735 ships and 70,000 people served the industry. As whale stocks and reserves decreased, whalers were forced to go farther and farther from their New England home ports. Voyages became longer, and risks on required return-on-investment became higher. The easy money of Atlantic and Pacific whaling was no more: the only remaining profitable ventures were to Arctic and Antarctic waters. Many ships returned empty, if at all. in 1871, most of the Arctic whaling fleet was crushed by early winter ice and lost. This calamity, in conjunction with the long-term diminishing whale stocks, the diversion of investment capital to more profitable ventures, and the discovery, development, and refinement of abundant petroleum crude oil, struck the death blow to the American whaling industry. By 1890, only 200 whaling vessels were at work, and by 1971, no American commercial whaling ship sailed the world's oceans.It is apparent that no single event caused the final, rapid decline. However, a single calamity, in an already stressed industry, that was self-insured and commercially interlinked, precipitated the end. Today's American petroleum industry, although adopting some principles of the American whaling industry, also has embraced other activities such as work process reengineering and customer alliances, which may preempt, or postpone, a similar catastrophic demise.     

The origin of polygonal troughs on the Northern Plains of Mars

Viking photographs have revealed extraordinary systems of crudely polygonal troughs in three different areas of the northern plains of Mars. Trough widths average 200–800 m and average trough spacing is 5–10 km. The widest troughs have flat floors and steep sides which suggest that they are either grabens or tension cracks which have been partially filled. The following three arguments support the garben interpretation: (1) Two clear examples of vertical offsets along trough walls indicate that the troughs formed by downdropping of the floors. (2) Troughs similar in scale and morphology to those of the Martian northern plains form concentric and radial patterns in the Caloris Basin on Mercury. Most likely, they are extensional fractures or grabens resulting from uplift of the basin floor (Strom et al., 1975). The Caloris analogy suggests that the troughs on Mars are similar tectonic features related either to uplift or expansion of the planet. Fourteen rose diagrams of trough azimuths in southeastern Acidalia Planita show that locally they exhibit preferred orientations roughly parallel to the topographic contours, but overall there is no strong regional pattern. (3) The scale of tension crack systems is limited by the depth of fracturing because the extent of stress relief perpendicular to a crack is proportional to the crack depth. Observations of terrestrial tension cracks suggest a lower limit on crack depths of about one-tenth of the average spacing. Thus, if the Martian troughs are tension cracks, they would be expected to have depths of at least 500–1000 m. Mechanical considerations indicate that it is difficult to generate such deep cracks by surficial tension due to thermal cooling and contraction in permafrost, desiccation, or cooling of lava flows. Deep-seated tension of tectonic origin generally results in normal faults and not tension cracks.     

Saturn's rings: Particle composition and size distribution as constrained by observations at microwave wavelengths: II. Radio interferometric observations

The sizes, composition, and number of particles comprising the rings of Saturn may be meaningfully constrained by a combination of radar- and radio-astronomical observations. In a previous paper, we have discussed constraints obtained from radar observations. In this paper, we discuss the constraints imposed by complementary “passive” radio observations at similar wavelengths. First, we present theoretical models of the brightness of Saturn's rings at microwave wavelengths (0.34–21.0 cm), including both intrinsic ring emission and diffuse scattering by the rings of the planetary emission. The models are accurate simulations of the behavior of realistic ring particles and are parameterized only by particle composition and size distribution, and ring optical depth. Second, we have reanalyzed several previously existing sets of interferometric observations of the Saturn system at 0.83-, 3.71-, 6.0-, 11.1-, and 21.0-cm wavelengths. These observations all have spatial resolution sufficient to resolve the rings and planetary disk, and most have resolution sufficient to resolve the ring-occulted region of the disk as well. Using our ring models and a realistic model of the planetary brightness distribution, we are able to establish improved constraints on the properties of the rings. In particular, we find that: (a) the maximum optical depth in the rings is ～ 1.5 ± 0.3 referred to visible wavelengths; (b) a significant decrease in ring optical depth from λ3.7 to λ21.0 cm allows us to rule out the possibility that more than ～30% of the cross section of the rings is composed of particles larger than a meter or so; this assertion is essentially independent of uncertainties in particle adsorption coefficient; and (c) the ring particles cannot be primarily of silicate composition, independently of particle size, and the particles cannot be primarily smaller than ～0.1 cm, independently of composition.     

Solar gravitational redshift

Wavelengths of solar spectrum lines should be shifted toward the red by the Sun's gravitational field as predicted by metric theories of gravity according to the principle of equivalence. Photographic wavelengths of 738 solar Fe i lines and their corresponding laboratory wavelengths have been studied. The measured solar wavelength minus the laboratory wavelength (_observed) averaged for the strong lines agrees well with the theoretically predicted shift (_theoretical). Studies show that the departures depend on line strength. No dependence of the departures on wavelength was found within the existing data.By studying strong lines over a wide spectral range, velocity shifts caused by the complex motions in the solar atmosphere seem to affect the results in a minimal fashion.     

Infrared imaging of Jupiter in the 8–14-micrometer spectral region

High spatial resolution images of Jupiter were produced on the Hale 200-in. telescope in August 1974 and October 1975. A programmable wobbling secondary was used to raster scan the planet with 64 by 64 1-arsec pixels. Images were made with broadband (8–14 μm) and several 1- and 2-μm wide filters. All images reveal a belt and zone structure similar to visible pjotographs. Belts, in the broadband data, appear to be about 2°K hotter than the zones, but contrast varies markedly in different parts of the 8–14-μm spectral region. The lowest belt-zone contrast is found in the hydrogen opacity dominated region at 12.5 μm, while images at 9.5 μm exhibit the greatest contrast. Isolated areas are observed to be as much as 4°K hotter than surrounding areas at 9.5 μm. This large contrast is probably due to variations in the distribution of the ammonia clouds in the upper atmosphere.     

The Mees CCD imaging spectrograph

The Mees CCD (MCCD) instrument is an imaging spectroscopy device which uses the 25 cm coronagraph telescope and the 3.0 m Coudé spectrograph at Mees Solar Observatory (MSO) on Haleakala, Maui. The instrument works with resolving power up to R 200 000 with significant throughput from 3934 Å (Caii K) to 10 000 Å. A fast guiding active mirror stabilizes the image during observations. A rapidly writing magnetic tape storage system allows observations to be recorded at 256 kbytes s^–1. Currently, the MCCD is used for imaging spectroscopy of solar flares at 6563 Å (H), and velocity measurements of umbral oscillations; future plans include emission line studies of active region coronae, and photospheric studies of solar oscillations.     

Recent crustal subsidence at Yellowstone Caldera,Wyoming

Following a period of net uplift at an average rate of 15±1 mm/year from 1923 to 1984, the east-central floor of Yellowstone Caldera stopped rising during 1984–1985 and then subsided 25±7 mm during 1985–1986 and an additional 35±7 mm during 1986–1987. The average horizontal strain rates in the northeast part of the caldera for the period from 1984 to 1987 were: ₁ = 0.10 ± 0.09 strain/year oriented N33° E±9° and ₂ = 0.20 ± 0.09 strain/year oriented N57° W±9° (extension reckoned positive). A best-fit elastic model of the 1985–1987 vertical and horizontal displacements in the eastern part of the caldera suggests deflation of a horizontal tabular body located 10±5 km beneath Le Hardys Rapids, i.e., within a deep hydrothermal system or within an underlying body of partly molten rhyolite. Two end-member models each explain most aspects of historical unrest at Yellowstone, including the recent reversal from uplift to subsidence. Both involve crystallization of an amount of rhyolitic magma that is compatible with the thermal energy requirements of Yellowstone's vigorous hydrothermal system. In the first model, injection of basalt near the base of the rhyolitic system is the primary cause of uplift. Higher in the magmatic system, rhyolite crystallizes and releases all of its magmatic volatiles into the shallow hydrothermal system. Uplift stops and subsidence starts whenever the supply rate of basalt is less than the subsidence rate produced by crystallization of rhyolite and associated fluid loss. In the second model, uplift is caused primarily by pressurization of the deep hydrothermal system by magmatic gas and brine that are released during crystallization of rhyolite and them trapped at lithostatic pressure beneath an impermeable self-sealed zone. Subsidence occurs during episodic hydrofracturing and injection of pore fluid from the deep lithostatic-pressure zone into a shallow hydrostatic-pressure zone. Heat input from basaltic intrusions is required to maintain Yellowstone's silicic magmatic system and shallow hydrothermal system over time scales longer than about 10⁵ years, but for the historical time period crystallization of rhyolite can account for most aspects of unrest at Yellowstone, including seismicity, uplift, subsidence, and hydrothermal activity.