Controls on spatial and temporal distribution of Precambrian eolianites

Inversely graded stratification, generated by the migration of wind ripples, and adhesion structures permit unequivocal identification of Precambrian eolianites. These criteria, in combination with scale of cross-beds, angle of inclination of foresets, geometry of depositional units, and associated non-eolian facies, are used to discriminate between Precambrian dune/draa, dune-plinth, sand-sheet, and interdune deposits that formed in inland and coastal settings. Based on an analysis of published literature, fundamental conclusions can be drawn on the spatial and temporal distribution of Precambrian eolianites. The oldest reported eolianites are from the ca. 2.1 Ga Deweras Group in Zimbabwe and Hurwitz Group in Canada and numerous examples of eolianites are reported from the 1.8 Ga and younger rock record. Lack of Archean and early Paleoproterozoic eolianites and their widespread development after 1.8 Ga are examined with respect to: absence of vegetation, crustal growth and tectonic setting, relative sea-level fluctuations, unfavorable atmospheric and/or climatic change, and non-recognition. The lack of pre-2.2 Ga eolianites may be related to reworking by braided rivers combing across non-vegetated floodplains, reworking of coastal eolianites during transgression or their non-recognition in the Early Precambrian record. The temporal concentration of eolianites at 1.8 Ga may best be related to the early stages of breakup and the assembly phases of supercontinents.     

SSBUV and NOAA-11 SBUV/2 Solar Variability Measurements

The Shuttle SBUV (SSBUV) and NOAA-11 SBUV/2 instruments measured solar spectral UV irradiance during the maximum and declining phase of solar cycle 22. The SSBUV data accurately represent the absolute solar UV irradiance between 200–405 nm, and also show the long-term variations during eight flights between October 1989 and January 1996. These data have been used to correct long-term sensitivity changes in the NOAA-11 SBUV/2 data, which provide a near-daily record of solar UV variations over the 170–400 nm region between December 1988 and October 1994. The NOAA-11 data demonstrate the evolution of short-term solar UV activity during solar cycle 22.     

A new look at the isotropy of narrow-line emission in extragalactic radio sources

We undertake a quantitative investigation, using Monte Carlo simulations, of the amount by which quasars are expected to exceed radio galaxies in optical luminosity in the context of the 'receding torus' model. We compare these simulations with the known behaviour of the [O  III ] λ5007 and [O  II ] λ3727 emission lines and conclude that [O  III ] is the better indicator of the strength of the underlying non-stellar continuum.     

Petrology of the 1979 eruption of Soufriere volcano,St. Vincent,Lesser Antilles

Major element, trace element, and Sr isotope data are used to study the temporal variation in the chemistry of the ejecta from the 1979 eruption of Soufriere volcano, St. Vincent, and to compare the compositions of the 1979 and 1971/2 magmas. Both the 1971/2 and 1979 products were basaltic andesites almost identical in petrography. A small temporal variation in chemistry is apparent in the 1979 samples but these cannot be related to the 1971/2 lava by fractional crystallisation of phenocryst phases, and the two eruptions may therefore have sampled different batches of magma. ⁸⁷Sr/⁸⁶Sr ratios of the two magmas were identical within analytical error.Microprobe analyses of phenocryst phases and glasses from the 1979 ejecta are presented. Clinopyroxene phenocryst cores with very high Mg/Fe ratios indicate that the basaltic andesites are products of fractionation of magnesian parents. Such magmas are represented by lavas on St. Vincent similar to the microphyric alkali picrites found to the south in Grenada. A common origin for the basaltic andesites of both islands by fractional crystallisation of picritic magmas is suggested. Dacitic glass is abundant in the groundmass of scoria blocks from the eruption. It does not represent the liquid originally in equilibrium with the phenocryst phases, but rather this liquid modified by quench crystallisation. Published interpretations suggesting that dacitic glass compositions in tephra from eruptions of the Soufriere are evidence of mixed-magma eruptions are therefore rejected.     

Mesozoic magnetic lineations in the Mozambique Basin

East-west-trending Mesozoic magnetic anomalies M2 through M22 have been identified in the northern Mozambique Basin. These anomalies are best matched by sea floor created at 50°S trending N120°E and spreading at a rate of around 1.5 cm/yr. The northward increase in age inferred from the identifications of these anomalies are compatible with observed decrease in the “reliable” heat flow values from 1.4 to 1.1 μcal/cm² s to the north in the basin. The anomalies terminate in the southern part of the Mozambique Channel against a magnetic quiet zone to the north. Both the Mozambique Basin anomalies and those recently observed off Antarctica are strong evidence in favour of a Gondwanaland reconstruction that places Dronning Maud Land against southern Mozambique, and a late Jurassic or older separation between Africa and Antarctica.     

Quantitative Simulation of the Hydrothermal Systems of Crystallizing Magmas on the Basis of Transport Theory and Oxygen Isotope Data: An analysis of the Skaergaard Intrusion

Application of the principles of transport theory to studiesof magma-hydrothermal systems permits quantitative predictionsto be made of the consequences of magma intruding into permeablerocks. Transport processes which redistribute energy, mass,and momentum in these environments can be represented by a setof partial differential equations involving the rate of changeof extensive properties in the system. Numerical approximationand computer evaluation of the transport equations effectivelysimulates the crystallization of magma, cooling of the igneousrocks, advection of chemical components, and chemical and isotopicmass transfer between minerals and aqueous solution. Numerical modeling of the deep portions of the Skaergaard magma-hydrothermalsystem has produced detailed maps of the temperature, pressure,fluid velocity, integrated fluid flux, ¹⁸O-values in rock andfluid, and extent of nonequilibrium exchange reactions betweenfluid and rock as a function of time for a two-dimensional cross-sectionthrough the pluton. An excellent match was made between calculated¹⁸O-values and the measured ¹⁸O-values in the three principalrock units, basalt, gabbro, and gneiss, as well as in xenolithsof roof rocks that are now embedded in Layered Series; the latterwere evidently depleted in ¹⁸O early in the system's coolinghistory, prior to falling to the bottom of the magma chamber.The best match was realized for a system in which the bulk rockpermeabilities were 10^–13 cm² for the intrusion, 10^–11cm² for basalt, and 10^–16 cm² for gneiss; reaction domainsizes were 0.2 cm in the intrusion and gneiss and 0.01 cm inthe basalts, and activation energy for the isotope exchangereaction between fluid and plagioclase was 30 kcal/mole. The calculated thermal history of the Skaergaard system wascharacterized by extensive fluid circulation that was largelyrestricted to the permeable basalts and to regions of the plutonstratigraphically above the basalt-gneiss unconformity. Althoughfluids circulated all around the crystallizing magma, fluidflow paths were deflected around the magma sheet during theinitial 130,000 years. At that time, crystallization of thefinal sheet of magma and fracture of the rock shifted the circulationsystem toward the center of the intrusion, thereby minimizingthe extent of isotope exchange between rocks near the marginof the intrusion at this level. For comparison, similar calculationswere also made for pure conductive cooling; it was found thatthe rate of crystallization of the magma body was not changed.The solidified pluton cooled by a factor of about 2 faster inthe presence of a hydrothermal system. Transport rates of thermal energy out of the intrusion and oflow-¹⁸O fluids into the intrusion controlled the overall isotopeexchange process. During the initial 150,000 years, temperatureswere high and reaction rates were fast; thus, fluids flowinginto the intrusion quickly equilibrated with plagioclase. However,the temperature decreased between 120,000 and 175,000 yearsand caused a decrease in reaction rates and an increase in theequilibrium fractionation factor between plagioclase and fluid.Consequently, during this time period fluids in the intrusiontended to be out of equilibrium with plagioclase. After 175,000years temperatures had decreased sufficiently that reactionrates became insignificant, but convection rates were largeenough to redistribute fluid and enlarge the regions where fluidand plagioclase were out of equilibrium. By 400,000 years, thepluton had cooled to approximately ambient temperatures, andthe final ¹⁸O values were ‘frozen in’. Reactionsbetween hydrothermal fluid and the intrusion occurred over abroad range in temperature, 1000-200 °C, but 75 per centof the fluid circulated through the intrusion while its averagetemperature was >480 °C. This relatively high temperatureis consistent with the observation that only minor amounts ofhydrothermal alteration products were formed in the naturalsystem, even where several per mil shifts in ¹⁸O were detected. The relative quantities of fluid to rock integrated over theentire cooling history were 0.52 for the upper part of intrusion,0.88 for the basalt, 0.003 for the gneiss, and 0.41 for theentire domain. Almost all of the fluid flowed into the intrusionfrom the basalt host rocks that occur adjacent to the side contactsof the intrusion. Convection transferred about 20 per cent ofthe total heat contained in the gabbro upward into the overlyingbasalts; the remaining 80 per cent of the heat was transferredby conduction.     

Determination of predevelopment denudation rates of an agricultural watershed (Cayaguás River, Puerto Rico) using in-situ-produced Be in river-borne quartz

Accurate estimates of watershed denudation absent anthropogenic effects are required to develop strategies for mitigating accelerated physical erosion resulting from human activities, to model global geochemical cycles, and to examine interactions among climate, weathering, and uplift. We present a simple approach to estimate predevelopment denudation rates using in-situ-produced cosmogenic ¹⁰Be in fluvial sediments. Denudation processes in an agricultural watershed (Cayaguás River Basin, Puerto Rico) and a matched undisturbed watershed (Icacos River Basin) were compared using ¹⁰Be concentrations in quartz for various size fractions of bed material. The coarse fractions in both watersheds bear the imprint of long subsurface residence times. Fine material from old shallow soils contributes little, however, to the present-day sediment output of the Cayaguás. This confirms the recent and presumably anthropogenic origin of the modern high denudation rate in the Cayaguás Basin and suggests that pre-agricultural erosional conditions were comparable to those of the present-day Icacos.     

Exposed cross-sections through the continental crust: implications for crustal structure,petrology, and evolution

The continental crust is exposed in cross-section at numerous sites on the earth's surface. These exposures, which appear to have formed by obduction along great faults during continental collision, may be recognized by exposures of deep crustal rocks exhibiting asymmetric patterns of metamorphic grade and age across the faults and by distinctive Bouguer anomaly patterns reflecting dipping basement structure and an anomalously deep mantle. From an examination of five complexes which meet these criteria, it is concluded that the most prominent layering in the crust is not compositional but metamorphic. The lower crust consists of granulite facies rocks of mafic to intermediate composition while the intermediate and shallow levels consist predominantly of amphibolite facies gneisses and greenschist facies supracrustal rocks, respectively. Post-metamorphic granitic intrusions are common at intermediate to shallow levels. Position of discontinuities in refraction velocity, where present, commonly correspond to changes in composition or metamorphic grade with depth. The continental crust is characterized by lateral and vertical heterogeneities of varying scale which are the apparent cause of the complex seismic reflections recorded by COCORP. Field observations, coupled with geochemical data, indicate a complex evolution of the lower crust which can include anatexis, multiple deformation, polymetamorphism and reworking of older crustal material. The complexity of the crust is thus the result of continuous evolution by recycling and metamorphism through time in a variety of tectonic environments.     

Plutonium,radiocesium and radiocobalt in sediments of the Hudson River estuary

Anthropogenic radionuclides have reached the Hudson estuary as global fallout from nuclear weapons testing and through local releases from commercial nuclear reactors. Significant activities of²³⁸Pu and^239,240Pu (fallout-derived),¹³⁴Cs and⁶⁰Co (reactor-released), and¹³⁷Cs (derived from both sources), have accumulated in the sediments throughout the estuary, with the primary zone of accumulation near the downstream end of the system in New York harbor. The estuary appears to have trapped nearly all of the^239,240Pu delivered as fallout, and consequently, ocean dumping of dredged harbor sediment is currently the primary means for the net transport of these nuclides to coastal waters. In contrast, only 10–30% of the¹³⁷Cs,¹³⁴Cs and⁶⁰Co delivered to the estuary have been retained on the fine particles which accumulate at a rapid rate in the harbor.The primary factors which have governed the distribution of anthropogenic radionuclides in Hudson sediments are: (1) spread of fine particles labeled with both fallout and reactor nuclides throughout the axis of the estuary, (2) differences in timing of the peak fallout years (1962–1964) and years of maximum reactor releases (1971–1972), (3) large variations in sediment accumulation rates, ranging from a few millimeters per year or less to many tens of centimeters per year, (4) appreciable desorption of¹³⁷Cs and¹³⁴Cs from particles at higher salinities, and (5) possible enhanced desorption of⁶⁰Co at higher salinities (relative to¹³⁴Cs and¹³⁷Cs) which may be associated with the release of reduced manganese from the harbor sediments.