Degradation of lubricating oils by marine bacteria observed by quantitative mass spectrometry

Bacterial degradation of the hydrocarbons of lubricating oils was investigated by mass spectrometric analysis which gives both total amount and the composition of hydrocarbon types of residual oil. An unused lubricating oil, which mainly consisted of hydrocarbon types with only a small percentage ofn-alkanes, was degraded by marineBacillus sp. andPseudomonas sp. with 55 % and 25 % decreases in 10 days, respectively. Susceptibility of respective hydrocarbon types to biodegradation was in the following order: alkanes > non-condensed cycloalkanes, mono-aromatics > condensed cycloalkanes. A used lubricating oil of different brand showed a larger decrease than the unused oil. Both species of bacteria degraded large portions of alkane fraction of Arabian light crude oil.     

Postglacial stratigraphic evolution of a current-influenced sandy shelf: offshore Kujukuri strandplain,central Japan

Sandy shelf sediments are important elements of clastic sedimentary systems because of their wide distribution in the geological record and their significance as hydrocarbon reservoirs. Although many studies have investigated shelf sediments influenced by waves or tidal currents, little is known about shelf sediments influenced by oceanic currents, particularly their lithofacies characteristics and stratigraphic evolution. This study investigated the stratigraphic evolution of shelf sediments off the Kujukuri strandplain facing the Pacific Ocean, which is influenced by the strong Kuroshio Current. Sediment cores were obtained from six locations on the Kujukuri shelf (34 to 124 m water depth) using a vibrocorer. The dominant lithofacies is mud-free sand with low-angle cross-lamination associated with alternating beds of finer and coarser sand with cross-lamination. These display depositional processes influenced by storm waves and the Kuroshio Current, respectively. This finding is consistent with the previously presented modern and historical observations of the Kuroshio Current and estimates of the storm-wave base. Radiocarbon dates show that the sediment succession formed during the last transgressive and highstand stages after 13·1 ka. The depositional processes during the stages represent a transition from storm waves with abundant sediment supply to both storm waves and the Kuroshio Current with sediment starvation mainly due to its trapping in the strandplain. Comparison to other Holocene–Modern shelf systems suggests that the sandy shelf successions are strongly influenced by oceanic currents under conditions of limited riverine input and open coastal geometry. The resultant sand-dominated succession is characterized by reversal of the proximal to distal grain-size trend compared to the fining for most other recognized wave/storm-dominated shelf successions. This is because of seaward increase in the influence of the Kuroshio Current. Thus, shelf deposits are naturally complex, and these may be further complicated by the additional influence of oceanic currents above the usual wave-dominated and tide-dominated end members.     

Latest Jurassic–earliest Cretaceous radiolarian fauna from the Xialu chert in the Yarlung Zangbo suture zone, southern Tibet: Comparison with coeval western Pacific radiolarian faunas and paleoceanographic implications

Abstract The Xialu chert radiolarian fauna is latest Jurassic–earliest Cretaceous in age (Pseudodictyomitra carpatica zone) and contains many taxa in common with coeval northern hemisphere middle‐latitude (temperate) radiolarian faunas represented by the Torinosu fauna in southwest Japan. Common elements include Eucyrtidiellum pyramis (Aita), Protunuma japonicus Matsuoka & Yao, Sethocapsa pseudouterculus Aita, Sethocapsa (?) subcrassitestata Aita, Archaeodictyomitra minoensis (Mizutani), Stichocapsa praepulchella Hori and Xitus gifuensis (Mizutani). The Xialu fauna is less similar to low‐latitude (tropical) assemblages represented by the Mariana fauna. For this reason, the Xialu fauna is regarded as representative of a southern hemisphere middle‐latitude (temperate) fauna. A mirror‐image bi‐temperate provincialism to the equator in radiolarian faunas is reconstructed for the Ceno‐Tethys and Pacific Ocean in latest Jurassic–earliest Cretaceous time.     

High-sensitive measurement of uranium LIII-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials

The uranium L_III-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg⁻¹ were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U L_III-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.     

Planform evolution of deltas with graded alluvial topsets: Insights from three‐dimensional tank experiments,geometric considerations and field applications

The profile of a river that conveys sediment without net deposition and net erosion is referred to as ‘graded’ with respect to vertical aggradation of the river segment. Three experimental series, designed in terms of the autostratigraphic view of alluvial grade, were conducted to clarify the diagnostic spatial behaviour of graded alluvial–deltaic rivers: an ‘R series’, which utilized a moving boundary setting with a stationary base level; an ‘F series’ in a fixed boundary setting with a stationary base level to produce ‘forced grade’; and an ‘M series’ in a moving boundary setting with constant base‐level fall to produce ‘autogenic grade.’ The results of the three experimental series, combined with geometrical modelling of the effects of basin water depth and other experimental data, suggest the following: (i) in a graded alluvial–deltaic system, lateral shifting and avulsing of active distributary channels are suppressed regardless of whether the downstream boundary of the deltaic system is fixed; (ii) in a delta with a downstream‐fixed boundary, the graded streams are stabilized within a valley that is incised in the axial part of the delta plain, whereby the alluvial plain outside the valley is abandoned and terraced; (iii) in moving boundary settings, the graded river simply extends basinward as a linearly elongated channel and lobe system without cutting a valley; and (iv) a modern forced‐graded alluvial river is most likely to be found in a valley incised into a fan delta in front of very deep water, and the stratigraphic signal of fossil autogenic‐graded rivers will be found in deltaic successions that accumulated in the outer to marginal areas of deltaic continental shelves during sea‐level falls. This renewed autostratigraphic view of alluvial grade suggests a thorough reconsideration of the conventional understanding that an alluvial river feeding a progradational delta is graded with a stationary base level.     

Simulation of the Collection of Catch Crops for the Recovery of Agricultural Resources using Geographic and Statistical Data

The cultivation of catch crops has great potential in agricultural areas for the recovery of nutrients, mitigation of groundwater contamination, and secondary utilization of harvestry. To estimate the potential volume of catch crops that can be collected at prospective locations, we simulated the cultivation and collection process at a regional scale using geographic and statistical data. Three types of geographic data, namely the locations of greenhouses, collecting stations and road networks, were used in a geographic information system to compute the volume of collected catch crops and carrying distance between greenhouses and collecting stations. Carbon emission from transportation of the catch crop was calculated using an improved ton‐km method, and the results were compared with the carbon content of the catch crop to evaluate the carbon balance. We found that the total fresh weight of the collected catch crops was 67900 t, of which 70% was collected at the top 15 of 73 stations. Carbon emissions from transportation ranged from >1 to 12% of the carbon content of the catch crop. The analytical method used in this study can readily be applied to other environmental studies concerning the collection of agricultural products and other biomass resources.     

Age determination of marine sediments in the western North Pacific by as partic acid chronology

The ages of fossil planktonic foraminifera,Pulleniatina obliquiloculata, in sediments (core 3bPC) from the western North Pacific were determined by aspartic acid chronology, which uses the racemization reaction rate constant of aspartic acid (k_Asp). Aspartic acid racemization-based ages (Asp ages) ranged from 7,600 yrBP at the surface, to 307,000 yrBP at a depth of 352.9 cm in the sediments. This sediment core was also dated by the glacial-interglacial fluctuation of δ¹⁸O chronology, and the ages determined by both chronologies were compared. The ages derived from aspartic acid chronology and δ¹⁸O stratigraphy were more or less consistent, but there appeared to be some differences in age estimates between these two dating methods at some depths within the core. In the core top sediments, the likely cause for the age discrepancy could be the loss of the surface sediment during sampling of the core. At depths of 66.3 and 139 cm within the core, Asp ages indicated reduced sedimentation rates duringca. 60,000-80,000 yrBP andca. 140,000–190,000 yrBP. The maximum age differences in both chronologies are 33,000 yr and 46,600 yr during each of these periods. These anomalous reductions in sedimentation rates occurring during these periods could possibly be related to some geological events, such as an increased dissolution effect of the calcium carbonate in the western North Pacific. Another possible reason for these age differences could be the unreliability in δ¹⁸O ages of core 3bPC as they were estimated by δ¹⁸O ages of another core, 3aPC.     

Algal Growth Potential and the limiting nutrient in Mikawa Bay

The Algal Growth Potential (AGP) of water samples collected off Gamagori in Mikawa Bay was measured from May 1978 through February 1979, and the limiting nutrient was determined using regression analysis and enrichment bioassays. The surface and bottom water samples had AGP that produced increments of chemical oxygen demand (COD) of 2.1 mg l^–1 and 3.1 mg l^–1, respectively, on average. These values ofCOD correspond to 46% and 97% of the average COD values of the raw water samples at the surface and bottom, respectively. Seasonal changes of AGP showed a close correlation with those of dissolved inorganic nitrogen (DIN) concentration. Enrichment bioassays showed that DIN was the most deficient nutrient. The DIN:phosphate-phosphorus (PO₄ ^3–-P) ratios and DIN: dissolved phosphorus (DP) ratios in the water samples were below the cellular N:P ratios of the natural algal populations. These results suggest that AGP was mainly limited by DIN concentration.     

Tidal currents influenced by topographic eddies in Uchiumi Bay

In the current record taken in Uchuimi Bay during summer in 1990, we find anomalous features that the tidal currents during spring and neap tides are quite different in both speed and direction, and the transition between them takes place suddenly. Relation between the variation of tidal current and the observed internal tide is examined, but they are poorly correlated. By examining the direction and phase of the current, it is inferred that these anomalous features are caused by the influence of topographic eddies formed perioidically in Uchiumi Bay.