Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.     

Silver in Tokyo Bay estuarine waters and Japanese rivers

Dissolved and particulate concentrations of silver in Tokyo Bay estuarine waters and Japanese rivers were determined in this study. The dissolved silver concentrations in the surface water of Tokyo Bay range from 5.9 to 15.1 pmol kg⁻¹, which is comparable to those in the surface water of the Japan Sea, but two or three times higher than those in the surface water of the open ocean. However, elevated concentrations of dissolved silver are not found in Tokyo Bay compared with those in other highly urbanized estuaries, such as San Francisco Bay (20∼243 pmol kg⁻¹). In the Tokyo Bay estuary, silver typically exhibits non-conservative mixing behavior, which is a common feature in the other estuaries reported previously. Dissolved silver concentrations decrease with salinity from the rivers to the mouth of Tokyo Bay. Silver is efficiently scavenged by suspended particulates, as evidenced by the high conditional distribution coefficients for silver throughout the estuary (log K_d > 5.0 ± 0.6). The silver fluxes into Tokyo Bay via inflowing rivers and atmospheric deposition were estimated as 83 kg y⁻¹ and 15 kg y⁻¹, respectively. A simple budget calculation shows that the silver supplied from rivers and atmosphere must be rapidly scavenged within the Tokyo Bay estuary.     

Long-term bottom water warming in the north Ross Sea

We measured potential temperature, salinity, and dissolved oxygen profiles from the surface to the bottom at two locations in the north Ross Sea (65.2°S, 174.2°E and 67.2°S, 172.7°W) in December 2004. Comparison of our data with previous results from the same region reveals an increase in potential temperature and decreases in salinity and dissolved oxygen concentration in the bottom layer (deeper than 3000 m) over the past four decades. The changes were significantly different from the analytical precisions. Detailed investigation of the temperature, salinity, dissolved oxygen and σ ₃ value distributions and the bottom water flow in the north Ross Sea suggests a long-term change in water mass mixing balance. That is to say, it is speculated that the influence of cool, saline, high-oxygen bottom water (high-salinity Ross Sea Bottom Water) formed in the southwestern Ross Sea has possibly been decreased, while the influences of relatively warmer and fresher bottom water (low-salinity Ross Sea Bottom Water) and the Adélie Land Bottom Water coming from the Australia-Antarctic Basin have increased. The possible impact of global warming on ocean circulation needs much more investigation.     

Hedonic approaches based on spatial econometrics and spatial statistics: application to evaluation of project benefits

This study discusses the theoretical foundation of the application of spatial hedonic approaches—the hedonic approach employing spatial econometrics or/and spatial statistics—to benefits evaluation. The study highlights the limitations of the spatial econometrics approach since it uses a spatial weight matrix that is not employed by the spatial statistics approach. Further, the study presents empirical analyses by applying the Spatial Autoregressive Error Model (SAEM), which is based on the spatial econometrics approach, and the Spatial Process Model (SPM), which is based on the spatial statistics approach. SPMs are conducted based on both isotropy and anisotropy and applied to different mesh sizes. The empirical analysis reveals that the estimated benefits are quite different, especially between isotropic and anisotropic SPM and between isotropic SPM and SAEM; the estimated benefits are similar for SAEM and anisotropic SPM. The study demonstrates that the mesh size does not affect the estimated amount of benefits. Finally, the study provides a confidence interval for the estimated benefits and raises an issue with regard to benefit evaluation.     

Process length variation of the cyst of the dinoflagellate Protoceratium reticulatum in the North Pacific and Baltic‐Skagerrak region: calibration as an annual density proxy and first evidence of pseudo‐cryptic speciation

Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σ_{t annual} = ?0.8674 × average process length + 1029.3 (R² = 0.84), with a standard error of 0.78 kg m^?3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σ_{t annual} = 3.5457 × average process length ? 993.28 (R² = 0.86), with a standard error of 3.09 kg m^?3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo‐cryptic speciation within this species. Copyright © 2012 John Wiley & Sons, Ltd.     

Diurnal freeze–thaw depth in rockwalls: Field measurements and theoretical considerations

Rock temperatures were monitored for a year at two alpine rockwalls in the Akaishi Range, Japan, where permafrost is absent. Diurnal frost and thaw penetration depths were evaluated from subsurface isotherms drawn on the basis of the temperature records at 0, 10 and 40 cm depths. The surface of the rockwalls experienced more than 100 diurnal freeze-thaw cycles, most of which accompanied a frost or thaw penetration shallower than 50 cm, and several long duration cycles with deeper frost or thaw penetration. Theoretical frost and thaw depths were also calculated by incorporating the surface freezing indices into the modified Berggren equation, the results from which were then compared with the actual values. The modified Berggren equation provided values that showed a strong correlation with observed depths, despite somewhat underestimating the actual values. Using the modified Berggren equation, the seasonal frost depth in the observed winter was estimated to be about 4·5 m. The frost and thaw depths are considered to give the maximum estimation of the depth to which frost-induced cracking can propagate in the bedrock.     

Rock weathering processes and landform development in the Sør Rondane Mountains, Antarctica

Field observations of weathering processes and the related landforms, combined with laboratory analyses of weathering products, permit a synthetic evaluation of Late Cenozoic weathering environments in the Sør Rondane Mountains, Antarctica, an arid upland characterized by low temperatures and strong winds. Rates and character of weathering depend mainly on moisture availability and the bedrock geology. Under the humid weathering regime that occurs only locally around the margin of the present sheet, frequent diurnal freeze-thaw cycles in summer cause relatively rapid rock fragmentation. Most of the mountains are situated in the arid weathering regime, under which rock breakdown is very slow unless the rock contains plenty of salts. Salt weathering becomes more intensive and extensive with exposure age, as a result of salt accumulation in rock, eventually producing soils as small as fine-silt size. Lack of clay mineralization even in weathered rocks having been exposed above the ice sheet prior to 4 Ma ago indicates that hydrolysis or carbonation of rock minerals has been insignificant during the past 4 Ma. The final products of weathering are due mainly to salt action and reflect the parent lithology. Resistant fine-grained granite forms strongly oxidized tors carved with tafoni, or fields of mushroom-like boulders overlying the fractured bedrock. Less resistant rocks, like biotite gneiss and amphibolite, produce stone pavements underlain by saline, silty soils up to 30–40 cm thick, the thickness of which corresponds to the maximum thaw depth.     

The rate of bedrock weathering by frost action: Field measurements and a predictive model

Shattering rate, surface temperature, moisture content, and the physical and strength properties of bedrock were measured in four rockwall sites of the Japanese Alps. Five-year observations revealed that the bedrock shattering rate was usually much higher in the freeze-thaw period from October to next May than in the frost-free period from June to September. This indicates that frost action is the most important shattering process, although unusual heavy rainstorms in summer are also responsible for the shattering. A combination of some empirical relationships derived from recent laboratory experiments leads to a predictive model of the frost shattering rate. This model shows that the annual shattering rate is dependent on the annual freeze-thaw frequency on the rock surface, and the degree of saturation and tensile strength of the rock masses. The coefficients involved in the model were determined using the field data.     

Rates of tafoni weathering on uplifted shore platforms in Nojima-Zaki,Boso Peninsula,Japan

Many tafoni occur on the faces of marine cliffs on three uplifted shore platforms with different altitudes and with known ages of emergence. The mean value of the ten largest depths of tafoni, D (cm), was obtained and the period of their formation, t (years), was estimated. The relationship between the two variables was found to be D = 20·3 × (1?e^?0.005t).     

ASCA observations of the Galactic superluminal sources GRO J1655–40 and GRS 1915+105

We summarize the ASCA observations of the two Galactic superluminal sources GRO J1655–40 and GRS 1915+105, focusing on theabsorption line features.The high spectroscopic capability of ASCA enabled us to detectiron-K absorption line features from both objects. This is direct evidence for the presence of highly ionized plasma in a non-spherical configuration around a black hole, and is considered to be a unique signature of superluminal jet systems. The candidate of the line-absorber would be a part of an accretion disk at a distance of 10^9-11 cm from the central X-ray source.