Dynamics of arsenic adsorption in the targeted arsenic-safe aquifers in Matlab, south-eastern Bangladesh: Insight from experimental studies

Targeting shallow low-As aquifers based on sediment colour may be a viable solution for supplying As-safe drinking water to rural communities in some regions of Bangladesh and West Bengal in India. The sustainability of this solution with regard to the long-term risk of As-safe oxidized aquifers becoming enriched with As needs to be assessed. This study focuses on the adsorption behaviour of shallow oxidized sediments from Matlab Region, Bangladesh, and their capacity to attenuate As if cross-contamination of the oxidized aquifers occurs. Water quality analyses of samples collected from 20 tube-wells in the region indicate that while there may be some seasonal variability, the groundwater chemistry in the reduced and oxidized aquifers was relatively stable from 2004 to 2009. Although sediment extractions indicate a relatively low amount of As in the oxidized sediments, below 2.5 mg kg⁻¹, batch isotherm experiments show that the sediments have a high capacity to adsorb As. Simulations using a surface complexation model that considers adsorption to amorphous Fe(III) oxide minerals only, under-predict the experimental isotherms. This suggests that a large proportion of the adsorption sites in the oxidized sediments may be associated with crystalline Fe(III) oxides, Mn(IV) and Al(III) oxides, and clay minerals. Replicate breakthrough column experiments conducted with lactose added to the influent solution demonstrate that the high adsorption capacity of the oxidized sediments may be reduced if water drawn down into the oxidized aquifers contains high levels of electron donors such as reactive dissolved organic C.     

Arsenic release from biotite into a Holocene groundwater aquifer in Bangladesh

Continuous core sediments (to a depth of 90.1 m) taken at a transitional area of Holocene and Pleistocene deposits in Sonargaon, Bangladesh were characterized for their mineralogy and chemistry. Among the sediments of the lower part of the Holocene aquifer (depth: 18–29 m), where most domestic wells are installed, As is mostly fixed in biotite and organic phases. A positive correlation of As concentration with those of Al and Fe but not that of total organic C clearly suggests that biotite is a primary source of As. Although microbial reduction–dissolution of As-containing Fe oxyhydroxides is thought to cause As-enriched groundwater in the Ganges–Brahmaputra–Meghna delta plain, the authors conclude that chemical weathering of biotite is the primary formation mechanism and prevailing reducing conditions contribute to the expansion of As-enriched groundwater in the study area.     

Response of the Dupi Tila aquifer to intensive pumping in Dhaka,Bangladesh

This paper focuses on the water-quantity issues facing Dhaka because of the rapid exploitation of the Dupi Tila aquifer. Dhaka is one of the world's largest groundwater-dependent cities, relying on water withdrawn from this underlying semiconfined sand aquifer. A meteoric rise in well construction in both the private and public sectors in recent years has produced an estimated 1,300 boreholes that tap the aquifer in urban and suburban parts of the city. Analysis of construction records for public-supply wells drilled between 1970 and 2000 shows that water levels are falling in several areas of the city despite apparently favorable recharge conditions. The productivity of boreholes as measured by specific capacity has also declined significantly. Even though the aquifer system is vital to the infrastructure of the city it remains a poorly quantified resource, and until this is resolved by investment in evaluation studies, attempts to efficiently manage the resource in a sustainable way will be frustrated.

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Resumen Este artículo trata de los aspectos cuantitativos relacionados con la sobreexplotación del acuífero de Dupi Tila, que suministra a la ciudad de Dhaka (Bangladesh). Ésta es una de las mayores ciudades del mundo con dependencia de las aguas subterráneas, y se abastece de un acuífero semiconfinado formado por arenas. El aumento meteórico en la construcción de pozos durante los últimos años, tanto en el sector público como en el privado, ha provocado que haya unas 1.300 captaciones del acuífero en las zonas urbana y suburbana de la ciudad. El análisis de los registros constructivos de pozos de abastecimiento público entre 1970 y 2000 muestra que los niveles piezométricos están descendiendo en diversas áreas de la ciudad, a pesar de la existencia de condiciones aparentemente favorables de recarga. La productividad de los pozos, determinada por su capacidad específica, también ha disminuido significativamente. Aunque el sistema acuífero es vital para la infraestructura de la ciudad, los recursos aún no han sido cuantificados adecuadamente. Hasta que este asunto no sea resuelto mediante la inversión en estudios de evaluación, los intentos por gestionar eficientemente los recursos de forma sustentable serán infructuosos.

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Résumé Cet article porte sur les pertes en quantité subies par Dacca du fait de l'exploitation rapide de l'aquifère de Dupi Tila. Dacca est l'une des villes dépendant de l'eau souterraine les plus importantes du monde, prélevant l'eau d'un aquifère sableux sous-jacent semi-captif. On estime à 1,300 forages l'accroissement des creusements de puits aussi bien dans le secteur privé que public dans ces dernières années; ils prélèvent dans l'aquifère dans la partie urbaine et à la périphérie de la ville. L'analyse des déclarations de creusement de puits pour l'AEP forés entre 1970 et 2000 montre que les niveaux d'eau ont chuté dans plusieurs zones de la ville malgré des conditions de recharge apparemment favorables. La productivité des puits mesurée par la capacité spécifique a également diminué significativement. Même si le système aquifère est vital pour l'infrastructure de la ville, il reste une ressource médiocrement quantifiée, et tant que ceci ne sera pas résolu par un investissement dans des études d'évaluation, les tentatives pour gérer efficacement la ressource de façon durable échoueront.

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