The importance of oxygen isotope provenance in relation to solute content of bulk meltwaters at Imersuaq Glacier,West Greenland

Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s^?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ¹⁸O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), SO₄^2? and δ¹⁸O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl^? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ¹⁸O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ¹⁸O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.     

On the inclusion of ground-based gravity measurements to the calibration process of a global rainfall-discharge reservoir model: case of the Durzon karst system (Larzac, southern France)

This work examines the relevance of the inclusion of ground-based gravity data in the calibration process of a global rainfall-discharge reservoir model. The analysis is performed for the Durzon karst system (Larzac, France). The first part of the study focuses on the hydrological interpretation of the ground-based gravity measurements. The second part of the study investigates further the information content of the gravity data with respect to water storage dynamics modelling. The gravity-derived information is found unable to either reduce equifinality of the single-objective, discharge-based model calibration process or enhance model performance through assimilation.     

Reflections on the current state of global climate response

What is the significance of the 2007 United Nations Climate Change Conference in Bali? The formal outcomes, especially the ‘Bali Action Plan’, are described and commented on, along with the challenges for negotiating a post-2012 agreement in Copenhagen during 2008 and 2009. The article concludes that the outcome of the Bali meeting is insufficient when compared to the nature of the challenge posed by climate change. However, it can nevertheless be considered a success in terms of ‘Realpolitik’ in paving the way for the negotiations ahead, because some real changes have been discerned in the political landscape. The challenges for the road towards Copenhagen are manifold: the sheer volume and complexity of the issues and the far-reaching nature of decisions such as differentiation between non- Annex I countries pose significant challenges in themselves, while the dependency on the electoral process in the USA introduces a high element of risk into the whole process. The emergence of social justice as an issue turns climate policy into an endeavour to improve the world at large—thereby adding to the complexity. And, finally, the biggest challenge is the recognition that the climate problem requires a global solution, that Annex I and non-Annex I countries are mutually dependent on each other and that only cooperation regarding technology in combination with significant financial support will provide the chance to successfully tackle climate change.     

Ries crater and suevite revisited—Observations and modeling Part I: Observations

We report results of an interdisciplinary project devoted to the 26 km‐diameter Ries crater and to the genesis of suevite. Recent laboratory analyses of “crater suevite” occurring within the central crater basin and of “outer suevite” on top of the continuous ejecta blanket, as well as data accumulated during the past 50 years, are interpreted within the boundary conditions imposed by a comprehensive new effort to model the crater formation and its ejecta deposits by computer code calculations (Artemieva et al. 2013). The properties of suevite are considered on all scales from megascopic to submicroscopic in the context of its geological setting. In a new approach, we reconstruct the minimum/maximum volumes of all allochthonous impact formations (108/116 km³), of suevite (14/22 km³), and the total volume of impact melt (4.9/8.0 km³) produced by the Ries impact event prior to erosion. These volumes are reasonably compatible with corresponding values obtained by numerical modeling. Taking all data on modal composition, texture, chemistry, and shock metamorphism of suevite, and the results of modeling into account, we arrive at a new empirical model implying five main consecutive phases of crater formation and ejecta emplacement. Numerical modeling indicates that only a very small fraction of suevite can be derived from the “primary ejecta plume,” which is possibly represented by the fine‐grained basal layer of outer suevite. The main mass of suevite was deposited from a “secondary plume” induced by an explosive reaction (“fuel‐coolant interaction”) of impact melt with water and volatile‐rich sedimentary rocks within a clast‐laden temporary melt pool. Both melt pool and plume appear to be heterogeneous in space and time. Outer suevite appears to be derived from an early formed, melt‐rich and clast‐poor plume region rich in strongly shocked components (melt ? clasts) and originating from an upper, more marginal zone of the melt pool. Crater suevite is obviously deposited from later formed, clast‐rich and melt‐poor plumes dominated by unshocked and weakly shocked clasts and derived from a deeper, central zone of the melt pool. Genetically, we distinguish between “primary suevite” which includes dike suevite, the lower sublayer of crater suevite, and possibly a basal layer of outer suevite, and “secondary suevite” represented by the massive upper sublayer of crater suevite and the main mass of outer suevite.     

High‐ to ultrahigh‐temperature metamorphism in the lower crust: An example resulting from Hikurangi Plateau collision and slab rollback in New Zealand

Lower crustal xenoliths erupted from an intraplate diatreme reveal that a portion of the New Zealand Gondwana margin experienced high‐temperature (HT) to ultrahigh‐temperature (UHT) granulite facies metamorphism just after flat slab subduction ceased at c. 110–105 Ma. P–T calculations for garnet–orthopyroxene‐bearing felsic granulite xenoliths indicate equilibration at ~815 to 910°C and 0.7 to 0.8 GPa, with garnet‐bearing mafic granulite xenoliths yielding at least 900°C. Supporting evidence for the attainment of HT and UHT conditions in felsic granulite comes from re‐integration of exsolution in feldspar (~900–950°C at 0.8 GPa), Ti‐in‐zircon thermometry on Y‐depleted overgrowths on detrital zircon grains (932°C ± 24°C at aTiO₂ = 0.8 ± 0.2), and correlation of observed assemblages and mineral compositions with thermodynamic modelling results (≥850°C at 0.7 to 0.8 GPa). The thin zircon overgrowths, which were mainly targeted by drilling through the cores of grains, yield a U–Pb pooled age of 91.7 ± 2.0 Ma. The cause of Late Cretaceous HT‐UHT metamorphism on the Zealandia Gondwana margin is attributed to collision and partial subduction of the buoyant oceanic Hikurangi Plateau in the Early Cretaceous. The halt of subduction caused the fore‐running shallowly dipping slab to rollback towards the trench position and permitted the upper mantle to rapidly increase the geothermal gradient through the base of the extending (former) accretionary prism. This sequence of events provides a mechanism for achieving regional HT–UHT conditions in the lower crust with little or no sign of this event at the surface.     

The influence of solar‐induced thermal stresses on the mechanical weathering of rocks in humid mid‐latitudes

The role of solar‐induced thermal stresses in the mechanical breakdown of rock in humid‐temperate climates has remained relatively unexplored. In contrast, numerous studies have demonstrated that cracks in rocks found in more arid mid‐latitude locations exhibit preferred northeast orientations that are interpreted to be a consequence of insolation‐related cracking. Here we hypothesize that similar insolation‐related mechanisms may be efficacious in humid temperate climates, possibly in conjunction with other mechanical weathering processes. To test this hypothesis, we collected rock and crack data from a total of 310 rocks at a forested field site in North Carolina (99 rocks, 266 cracks) and at forested and unforested field sites in Pennsylvania (211 rocks, 664 cracks) in the eastern United States. We find that overall, measured cracks exhibit statistically preferred strike orientations (47° ± 16), as well as dip angles (52° ± 24°), that are similar in most respects to comparable datasets from mid‐latitude deserts. There is less variance in strike orientations for larger cracks suggesting that cracks with certain orientations are preferentially propagated through time. We propose that diurnally repeating geometries of solar‐related stresses result in propagation of those cracks whose orientations are favorably oriented with respect to those stresses. We hypothesize that the result is an oriented rock heterogeneity that acts as a zone of weakness much like bedding or foliation that can, in turn, be exploited by other weathering processes. Observed crack orientations vary somewhat by location, consistent with this hypothesis given the different latitude and solar exposure of the field sites. Crack densities vary between field sites and are generally higher on north‐facing boulder‐faces and in forested sites, suggesting that moisture‐availability also plays a role in dictating cracking rates. These data provide evidence that solar‐induced thermal stresses facilitate mechanical weathering in environments where other processes are also likely at play. Copyright © 2015 John Wiley & Sons, Ltd.