Crystal recycling in the steady-state system of the active Stromboli volcano: a 2.5-ka story inferred from in situ Sr-isotope and trace element data

In situ Sr-isotope data by microdrilling, coupled with major and trace element analyses, have been performed on plagioclase and clinopyroxene from seven samples collected during the 2002–2003 eruptive crisis at Stromboli volcano (Aeolian Islands, Italy). On 28 December 2002, the persistent moderate explosive activity was broken by an effusive event lasting about 7 months. A more violent explosion (paroxysm) occurred on 5 April 2003. Two magma types were erupted, namely a volatile-poor and highly porphyritic magma (HP-magma) poured out as scoria or lava and a volatile-rich, phenocryst-poor magma (LP-magma) found as pumice. LP-magma differs from the HP-magma also for its slightly less-evolved chemistry, the groundmass composition and the lower Sr-isotope ratios. Micro-Sr-isotope data show the presence of zoned minerals in strong isotope disequilibrium, as previously found in products erupted in 1984, 1985 and 1996 AD, with ⁸⁷Sr/⁸⁶Sr values generally decreasing from cores to rims of minerals. Only some outer rims testify for equilibrium with the host groundmass. The internal mineral zones with high Sr-isotope ratios (0.70665–0.70618) are interpreted as ‘antecrysts’, crystallised during the previous activity and recycled in the present-day system since the opening shoshonitic activity of the Recent Period, which occurred at about 2.5 ka ago. This result has implications for the dynamics of the present-day plumbing system of Stromboli at intermediate pressure (about 2–3 km depth) and allows us to propose a model whereby an HP-magma reservoir is directly interconnected at the bottom with a cumulate crystal much reservoir. Efficient mixing between residing HP- and input LP-magmas can occur in this reservoir, due to more similar rheological characteristics of the two magmas than in the conduit, where crystallisation is enhanced by degassing. Antecrysts (and possibly melts) re-enter in the HP-magma reservoir both from the bottom, recycled by ascending LP-magmas crossing the crystal mush, and from the top, recycled by descending degassed and dense HP-magma, residual of the periodic Strombolian explosions at the surface. The isotope variation measured in the groundmasses allows calculating the proportion of the LP-magma entering the shallow HP-magma reservoir at ~20%. From this proportion, we estimate that the total volume of LP-magma input during 2002–2003 closely matches the magma volume erupted in the effusive event, suggesting a steady-state system at broadly constant volume. The comparison with estimates of the LP-magma volume ejected by the paroxysm indicates that the LP-magma amount directly reaching the surface during the 5 April paroxysm is minimal with respect to that entering the system.     

The Lago di Varano: Hydrologic Characteristics and Sediment Composition

Abstract. The Lago di Varano is situated on the north side of the Gargano National Park (southeast Italy) and covers a surface area of about 65 km². It communicates with the Adriatic Sea through two artificial canals (Foce Capoiale and Foce Varano) located at the two ends of a long and narrow coastal dune. This work presents preliminary results of four seasonal surveys (1999–2000) carried out to measure chemical and physical parameters of the water column (temperature, salinity, dissolved oxygen and pH) and to analyse a number of biogeochemical characteristics of surface sediments (organic matter, total phosphorus, total nitrogen and total Hg, As, Pb, Cd, Cr, Cu and Ni content). Water analysis indicated poor exchange between the coastal pond and the open sea, limited to autumn and winter. Surface sediments were rich in organic matter, whose distribution was influenced by chemical-physical and hydrodynamic variations in the water column. At the sediment level, the highest values of Cd were found in the central zone of the basin, while the highest Cr values were measured in the central and southeastern areas. With the exception of Cd and Pb, the metal content did not indicate anthropogenic pollution, in particular when compared with the Venice Lagoon and the Central Adriatic Sea.     

The recovery of the old nova RS Car (1895)

Low-resolution spectra, taken at La Silla (ESO), identify the old nova RS Car (1895) as a ∼18 mag star located 7 arcsec southwest from the previous published position. This suggests a much brighter absolute magnitude of the old nova, M _v ∼5.4, than previously suspected. The spectrum reveals a continuum energy distribution typical of optically thick accretion discs and quite a high excitation state of the gas. The possible detection of the AlO λ 4843 emission band is discussed.     

Mantle and crustal processes in the magmatism of the Campania region: inferences from mineralogy, geochemistry, and Sr–Nd–O isotopes of young hybrid volcanics of the Ischia island (South Italy)

Ischia, one active volcano of the Phlegraean Volcanic District, prone to very high risk, is dominated by a caldera formed 55 ka BP, followed by resurgence of the collapsed area. Over the past 3 ka, the activity extruded evolved potassic magmas; only a few low-energy explosive events were fed by less evolved magmas. A geochemical and Sr–Nd–O isotope investigation has been performed on minerals and glass from products of three of such eruptions, Molara, Vateliero, and Cava Nocelle (<2.6 ka BP). Data document strong mineralogical, geochemical, and isotopic heterogeneities likely resulting from mingling/mixing processes among mafic and felsic magmas that already fed the Ischia volcanism in the past. Detailed study on the most mafic magma has permitted to investigate its origin. The mantle sector below Ischia underwent subduction processes that modified its pristine chemical, isotopic, and redox conditions by addition of ≤1 % of sediment fluids/melts. Similar processes occurred from Southeast to Northwest along the Apennine compressive margin, with addition of up to 2.5 % of sediment-derived material. This is shown by volcanics with poorly variable, typical δ¹⁸O mantle values, and ⁸⁷Sr/⁸⁶Sr progressively increasing toward typical continental crust values. Multiple partial melting of this modified mantle generated distinct primary magmas that occasionally assimilated continental crust, acquiring more ¹⁸O than ⁸⁷Sr. At Ischia, 7 % of Hercynian granodiorite assimilation produced isotopically distinct, K-basaltic to latitic magmas. A SW–NE regional tectonic structure gave these magmas coming from large depth the opportunity to mingle/mix with felsic magmas stagnating in shallower reservoirs, eventually triggering explosive eruptions.     

Are we going to live in a post-NATO world? A critical perspective on trends,obstacles and possibilities

The main research question investigated in this paper is the following: will a post-NATO world emerge during the next decades? The relevance of such a question is a consequence of the political and economic changes that have seen the light as a result of the power shift of international relations after the end of the Cold War. In spite of this, some contradictory tendencies, such as the weakening of the European pole within the NATO block, the US-NATO enlargement and its military aggressiveness, are generating a number of significant obstacles to the emergence of a post-NATO world. We will argue that the existence of these obstacles could be interpreted as some steps toward the historical downsizing of the US-EU-NATO hegemony. A “post-NATO” world does not necessarily imply the end of NATO, but rather the end of its hegemonic military presence on the global stage. Firstly, we will put the question into context mentioning the debates around NATO’s future and underlining the path undertaken by the Alliance in the frame of the redefinition of the aims of its “strategic concepts”. In this perspective, we will underline the direct link which exists between US strategic needs and NATO’s evolution in the post-Cold war era. Secondly, we will argue that the recent process of military expansionism led by NATO is remarkably de-legitimizing its actions on the global stage. Such a process, along with the current world system shift toward the end of unipolarity, is likely to provoke dramatic consequences in terms of international insecurity and the spreading of war. Thirdly, we will briefly compare the US and Chinese foreign actions, arguing that the space of international legitimacy is radically changing. This fact represents another brick supporting the idea of the emergence of a post-NATO world system in the future of international relations.     

An improved method for delineating source protection zones for karst springs based on analysis of recession curve data

A standard method for delineating source protection zones, particularly for karst and carbonate springs, has been improved. The method, based on recession curve analysis, defines four vulnerability scenarios with an evaluation of the appropriate dimensions of the protection areas, accommodating situations where field-test data are not available. The new approach makes it easier to separate the components of the spring discharge hydrograph. The objective is to achieve simplification, and an effective, more rigorous, procedure in the determination of the parameters used by Mangin’s model—Mangin A (1975) Contribution a l’étude hydrodynamique des aquifères karstiques-Troisieme partie: Constitution et fonctionnement des aquifères karstiques (Contribution to the hydrodynamic study of karst aquifers, part 3: formation and work of karst aquifers). Ann Speleol 30(1):21–124. The original procedure, plus the lack of sufficient data, was open to subjective interpretation. With the aid of modern technology, a very large quantity of data is now available and it is necessary to process it using denoise type computer-based filters before passing to interpretation. Working with discharge data series, a statistical approach is proposed to give an analytical solution for determining the values of fundamental parameters of the recession curve model. The new procedure is defined and compared with the original methodology. The new approach has been tested and applied to a number of karst springs in Italy. A case history for a spring located in the Piedmont region of the Maritime Alps, is presented. The proposed new procedure can be utilised to mark the limits of the protection zones of tapped groundwater supplied for potable use, as required by European and local legislation.     

Comparison between rocking analysis and kinematic analysis for the dynamic out‐of‐plane behavior of masonry walls

This paper provides a contribution to the rocking analysis of masonry walls by making a comparison with the kinematic analysis suggested by the Italian code. It is shown that the latter approach is generally over‐conservative and therefore potentially inappropriate for historic buildings, where rehabilitation can be expensive and can affect their cultural value. The equation of motion given by the Housner formulation, corresponding to the movement of a rigid block, is here modified to account for different boundary conditions at different heights of the wall. These boundary conditions or horizontal restraints can represent vaults, transverse walls, or retrofitting devices such as steel tie‐rods. A systemic analysis of walls having different dimensions and slenderness is performed, and the results from the Italian code and rocking analysis are compared. Finally, the improvement in the response offered by retrofitting devices is discussed in terms of reduction of amplitude ratio. Copyright © 2015 John Wiley & Sons, Ltd.     

Spatio‐temporal patterns of channel changes in response to a major flood event: the case of the Magra River (central–northern Italy)

On October 25^th 2011, the Magra River (central–northern Italy) was affected by a significant flood event with an estimated return interval ranging from 30 to 200 years. This study investigates the morphological responses of the Magra River to this major flood event with the aims of (i) documenting the channel changes which occurred in response to the flood; (ii) analysing this response within the context of the historical trend of width changes; (iii) investigating the possible factors controlling the spatial pattern and the intensity of the observed changes. Significant channel widening was documented along the entire length studied (about 34 km), ranging from 3% to 90% of the pre‐flood channel width. Braided reaches were characterized by the most severe planimetric changes. Although characterized by high rates of change, these variations are, however, amply included in the historical range of channel width variability over approximately the last 150 years (from 1877 to present day), and are comparable with ( though generally lower than) the channel width of the 1950s. Statistical analyses (simple and multiple regressions) between the observed changes in channel width and a series of selected morphological and hydraulic controlling factors showed no robust correlations to explain the spatial pattern and the variability of channel adjustments. Instead, major adjustments occurred along reaches characterized by the confluence of those streams draining the sub‐catchments where the storm was concentrated. Copyright © 2014 John Wiley & Sons, Ltd.     

A late Triassic 40Ar/39Ar age for the El Hammam high-REE fluorite deposit (Morocco): mineralization related to the Central Atlantic Magmatic Province?

El Hammam is the only fluorite mine in Morocco (production 100,000 t/year). The fluorite mineralization is in an array of fluorite–calcite veins and is characterized by unusually high REE content in carbonate minerals (1,400 ppm in calcite; up to 2,000 ppm in siderite) and in fluorite (about 600 ppm). Since the 1960s, the genesis of the deposit has been attributed to a mesothermal hydrothermal event connected with late-Variscan granitic intrusions. Precise ⁴⁰Ar/³⁹Ar dating of hydrothermal K-feldspar yields an age of formation of the El Hammam deposit at 205 ± 1 Ma. Its genesis is therefore associated in time and space with the development of the Triassic–Jurassic basins and the associated anorogenic continental flood basalts of the Moroccan Mesetian Middle Atlas. The source of the hydrothermal mineralization (magmatic and/or metamorphic) is discussed.     

The State of the Adriatic Sea Centered on the Small Pelagic Fish Populations

Abstract. The paper provides an overview of the state of the small pelagic fish in the Adriatic Sea. The North Adriatic is reviewed for the 1976–1998 period and the South Adriatic for the 1987–1998 period. First the fluctuations in time and in space of the pelagic biomass, as a whole and per species, are presented. Then the dramatic collapse of anchovy stock and its apparent association with the decrease of surface temperature is discussed. Finally the changes of the anchovy and sardine catches are compared and analysed with respect to their abundances in the sea. The conclusion is that acoustic and satellite methods are able to provide a large amount of information on the variability in the pelagic populations; this is essential for an appropriate management of these resources. There is still a need, however, to refine the methods and to integrate this kind of information with further environmental data (including natural predators).