Chemistry and Sulfur Isotopes of the Chert-Clastic Sequence Surrounding the Kajika Massive Sulfide Ores at the Ashio Copper Mine, Ashio Terrane, Central Japan

Abstract. Chemical and sulfur isotopic compositions were obtained for a series of rocks within the chert‐clastic sequence surrounding the Kajika massive sulfide ore horizon at Shibukawasawa in the Ashio copper‐mining district, Ashio Terrane, central Japan. The sequence is lithologically classified into three units: chert, siliceous shale with basic volcanics, and sandstone‐shale, in ascending stratigraphic order. The Kajika ore horizon corresponds to the lowermost part of the unit that contains siliceous shale with basic volcanics. The rocks around the Kajika ore horizon are enriched in P₂O₅ (max. 0.22 %), Ba (max. 2400 ppm), Cu (595 ppm), V (323 ppm), Pb (168 ppm), Zn (124 ppm), and Mo (24 ppm) in siliceous shale; and Ba (4220 ppm), Zr (974 ppm), Cr (718 ppm), Ni (492 ppm), V (362 ppm), Zn (232 ppm), Nb (231 ppm), and Co (71 ppm) in the basic volcanics. The siliceous shale is enriched in a number of redox‐sensitive elements such as Cu, V, Pb, Zn, and Mo, which are known to be enriched in black shale and anoxic and hydrothermal sediments. The δ³⁴S values of sulfides in the chert and sandstone‐shale lie in the range of 0±2 %, and those in the siliceous shale range from ‐5 to ‐14 %. The measured δ³⁴S values in the basic volcanics are ‐0.3, ‐2.7, and ‐31.5 %. These heavier δ³⁴S signatures (around 0 %) recorded throughout the sequence indicate that the rocks formed under anoxic bottom‐water conditions. Slightly lighter δ³⁴S values recorded in siliceous shale might reflect significant mixing of sulfides that formed by sulfate‐reducing bacteria in an overlying oxic environment. The long‐term duration of anoxic conditions indicated by the heavier δ³⁴S signature is considered to have played an important role in protecting the Kajika sulfide ores from oxidative decomposition and preserving the ores in sedimentary accumulations.     

Borehole image analysis of the Nankai Accretionary Wedge, ODP Leg 196: Structural and stress studies

Electrical images recorded with Resistivity-At-Bit (RAB) from two sites drilled during Ocean Drilling Program (ODP) Leg 196 were analyzed to study the effects of subduction at the Nankai margin. For the first time in the history of scientific deep-sea drilling in ODP, in situ complete borehole images of the décollement zone were obtained. Analyses of all drilling-induced fracture data indicated that the maximum horizontal compressive stress (S_Hmax) axes have an azimuth of 303°, and analyses of breakout data from RAB images indicated an azimuth of 310°. These azimuths approximate the convergence direction of the Philippine Sea plate towards the Eurasian plate. The frontal thrust at Site 808 was encountered at about 389 mbsf. Density, porosity, resistivity, and gamma ray data change across the frontal thrust. The décollement zone at the deformation front was identified between 937 and 965 mbsf. The base of the décollement is sharply defined as the maximum extent of conductive fracturing and is marked by abrupt changes in physical properties [Mikada, H., Becker, K., Moore, J.C., Klaus, A., Austin, G.L., Bangs, N.L., Bourlange, S., Broilliard, J., Brückmann, W., Corn, E.R., Davis, E.E., Flemings, P.B., Goldberg, D.B., Gulick, S.S., Hansen, M.B., Hayward, N., Hills, D.J., Hunze, S., Ienaga, M., Ishiguro, H., Kinoshita, M., Macdonald, R.D., McNeill, L., Obana, S., Hong, O.S., Peacock, S., Pettigrew, T.L., Saito, S., Sawa, T., Thaiprasert, N., Tobin, H.J., Tsurumi, H., 2002. Proc. ODP, Initial Rep., 196, College Station, TX, (Ocean Drilling Program)]. The upper boundary of the décollement is marked by several sets of conductive fractures and by high variability in physical properties. The décollement zone is characterized by intense brittle fracturing. These fractures are considered to be the consequence of cyclic stresses and high fluid pressures in this zone. We analyzed fracture dips and their orientations at both sites and found that they are all consistent with a unique stress field model surrounding the two sites.     

http://dx.doi.org/10.1016/j.gsf.2016.06.013

The Archean continental crusts account for ca.20% of the present volume,but the thermal history of the Earths' mantle suggests much more continental crusts were formed in the early Archean.Because the Archean continental crust underwent severe metamorphism,it is important to avoid influence by the later thermal events.We carried out a comprehensive geochronological work of Cathodoluminescence(CL) observation and U-Pb dating of zircons from orthogneisses and supracrustal rocks over the Saglek Block to obtain their protolith ages.The zircons were classified into three domains of core,mantle and rims,and the cores were further classified into three groups of inherited,altered and zoned cores based on the zonation on the CL images.We estimated the protolith ages from Pb-Pb ages of the zoned-cores of zircons with low U contents.We made a detailed sketch of a small outcrop in St.John's Harbour South(SJHS) area,and classified the orthogneisses and mafic enclaves into seven generations based on the geologic occurrence.The first and second generations comprise mafic rocks and lack magmatic zircons.We conducted CL imaging and U-Pb dating of zircons from the third,sixth and seventh generation of the orthogneisses to estimate the protolith ages at 3902 L 25,3892 ± 33 and 3897 ± 33 Ma for each,supporting the presence of the over 3.9 Ca Iqaluk Gneiss.The geological occurrence that the mafic rocks occur as enclaves within the 3.9 Ga Iqaluk Gneiss indicates that they are the oldest supracrustal rocks in the world.Our geochronological and geological studies show the Uivak Gneiss is quite varied in lithology and age from 3.6 to 3.9 Ga,and tentatively classified into six groups based on their ages.The oldest Uivak Gneiss components including the Iqaluk Gneiss are present around the SJHS area,and the orthogneisses become young as it is away.The lines of evidence of overprinting of younger granitoid on older granitoid in small outcrops and geological-map scale as well as presence of inherited zircons even in the oldest suite suggests that crustal reworking played an important role on erasing the ancient crusts.     

Measurement of the sea surface emissivity

The sea surface emissivity in the infrared region is determined on the basis of data analyses. Net radiation, surface irradiance and other oceanographical and meteorological variables are measured throughout most of the year at the oceanographical observatory tower in Tanabe Bay, Japan. We have found that 0.984±0.004 is a reliable emissivity value from the night time data. Surface emission radiates not from the subsurface water but from the sea surface. The thermal skin layer on the sea surface, however, is disturbed and disappears under high wind speed over 5 m/s through the analyses of the radiation observation using the emissivity value of 0.984. Under low wind speed, the sea surface can be cooler or warmer than the subsurface due to overlying thermal conditions and the skin layer can be neutral as the transient process between them. By using an emissivity value of 0.984, the temperature difference between the sea surface temperature and the temperature determined from surface irradiance that has been reported in the satellite data analyses is found to be reduced by half.     

Synthesis of γ-Mg2SiO4

Magnesium orthosilicate with spinel structure (γ-Mg₂SiO₄) was synthesized at about 250 kbar and 1000°C. Unit cell dimension was established to be 8.076 ± 0.001Å. X-ray powder diffraction pattern revealed a significant difference between γ-Mg₂SiO₄ and other γ-M₂SiO₄ spinels (M = Fe, Co, and Ni) in the intensities of (111) and (331) reflections, both of which are virtually absent in the Mg₂SiO₄ spinel. This feature could be thoroughly understood by the calculation of the intensities for several silicate spinels.     

A fluidized landslide on a natural slope by artificial rainfall

An experiment to induce a fluidized landslide by artificial rainfall was conducted on a natural slope at Mt. Kaba-san in the village of Yamato, Ibaraki Prefecture, Japan. The experimental slope was 30 m long, 5 m wide, and the average slope gradient was 33°. A landslide initiated 24,627.5 s (410 m/27.5 s) after the start of sprinkling at a rainfall intensity of 78 mm/h. The landslide mass was 14 m long and 1.2 m deep (at maximum). It first slid, then fluidized, and changed into a debris flow. The travel distance was up to 50 m in 17s. The apparent friction angle of the fluidized landslide was 16.7°. Formation of the sliding surface was detected by soil-strain probes. Motion of the surface of the failed landslide mass was determined by stereo photogrammetry.     

Experimental and Numerical Investigations of Ground Deformation Using Chemical Grouting for Pipeline Foundation

Based on experimental and numerical investigations, the present paper focuses on under ground scope (UGS) chemical grouting method that can actually improve the pipeline surrounding foundation to solve pipeline saggy damage. According to the experimental results, a solution-type injection material could make lager soil deformation, using less total slurry amount than suspension-type injection material. Therefore, a suspension-type injection material with shorter gel time is more suitable for the UGS method, making it more effective to reinforce the pipeline foundation and restore pipelines. The results of some patterns of injection tests revealed relationship between the behavior of the grouting material and the deformation of the soil. It is found that the material can be injected into a foundation by fracture grouting if the permeation coefficient is lower than 1.00 × 10⁻³ mm/s. The situation was analyzed by using 2-D finite element method analysis software Phase2, and the analysis result proposes that the real data and simulation data are nearly the same in impermeable soil. Furthermore, even if the construction object is permeable soil, it can also be become impermeable soil by two phases grouting: soil improvement grouting and restoration grouting.     

Permian Peri‐glacial Deposits from Central Mongolia in Central Asian Orogenic Belt: A Possible Indicator of the Capitanian Cooling Event

A dropstone‐bearing, Middle Permian to Early Triassic peri‐glacial sedimentary unit was first discovered from the Khangai–Khentei Belt in Mongolia, Central Asian Orogenic Belt. The unit, Urmegtei Formation, is assumed to cover the early Carboniferous Khangai–Khentei accretionary complex, and is an upward‐fining sequence, consisting of conglomerates, sandstones, and varved sandstone and mudstone beds with granite dropstones in ascending order. The formation was cut by a felsic dike, and was deformed and metamorphosed together with the felsic dike. An undeformed porphyritic granite batholith finally cut all the deformed and metamorphosed rocks. LA‐ICP‐MS, U–Pb zircon dating has revealed the following ²⁰⁶Pb/²³⁸U weighted mean igneous ages: (i) a granite dropstone in the Urmegtei Formation is 273 ± 5 Ma (Kungurian of Early Permian); (ii) the deformed felsic dike is 247 ± 4 Ma (Olenekian of Early Triassic); and (iii) the undeformed granite batholith is 218 ± 9 Ma (Carnian of Late Triassic). From these data, the age of sedimentation of the Urmegtei Formation is constrained between the Kungurian and the Olenekian (273–247 Ma), and the age of deformation and metamorphism is constrained between the Olenekian and the Carnian (247–218 Ma). In Permian and Triassic times, the global climate was in a warming trend from the Serpukhovian (early Late Carboniferous) to the Kungurian long and severe cool mode (328–271 Ma) to the Roadian to Bajocian (Middle Jurassic) warm mode (271–168 Ma), with an interruption with the Capitanian Kamura cooling event (266–260 Ma). The dropstone‐bearing strata of the Urmegtei Formation, together with the glacier‐related deposits in the Verkhoyansk, Kolyma, and Omolon areas of northeastern Siberia (said to be of Middle to Late Permian age), must be products of the Capitanian cooling event. Although further study is needed, the dropstone‐bearing strata we found can be explained in two ways: (i) the Urmegtei Formation is an autochthonous formation indicating a short‐term expansion of land glacier to the central part of Siberia in Capitanian age; or (ii) the Urmegtei Formation was deposited in or around a limited ice‐covered continent in northeast Siberia in the Capitanian and was displaced to the present position by the Carnian.     

Stable hydrogen isotope measurement of archaeal ether-bound hydrocarbons

Compound-specific hydrogen isotope analysis of ether-bound isoprenoid hydrocarbons from archaeal membranes has been developed using chemical degradation and gas chromatography/pyrolysis/isotope ratio mass spectrometry. The ether-bound hydrocarbons are quantitatively converted to saturated hydrocarbons by cleavage of ether bonds with HI followed by H₂ reduction in the presence of PtO₂. The δD value of ether-bound hydrocarbon moieties are corrected by way of isotopic mass balance calculation for the hydrogen incorporated during the hydrogenation. The method was successfully applied to determination of the δD values of biphytane moieties in glycerol dialkyl glycerol tetraethers (GDGTs) from a Sulfolobus sp. culture and a marine sediment.