The development of Fe-nodules surrounding biological material mediated by microorganisms

Takashikozo is a phenomenon of Quaternary sediments in Japan. They are cylindrical Fe-oxyhydroxide nodules that form as plaques round plant roots, where Fe is preferentially concentrated to develop a solid wall. Structural features suggest that after the roots have decayed, the central space where the roots were situated acts as a flow path for oxidized water. Analysis of microbial 16S rDNA extracted from the nodules identified iron-oxidizing bacteria encrusted round the roots where they are the likely initiators of nodule formation. Direct microscopic observation revealed an accumulation of Fe-oxyhydroxides that fill the pore spaces and is also likely to be linked with the encrusting microbial colonies. Geological history and nanofossil evidence suggest that these Fe-nodules may have been buried at a depth of up to several tens of meters for at least 10⁵ years in reducing Quaternary sediments. Thus Fe-oxyhydroxide nodules that have formed in a geological environment at the interfaces between water and rock by microbial mediation can persist under reducing conditions. If this is the case, the phenomenon is significant as an analogue of post-closure conditions in radioactive waste repositories, since it could influence nuclide migration.     

Geochemistry of Mesozoic intracontinental basalts from Yunnan, southern China: Implications for geochemical evolution of the subcontinental lithosphere

Summary Southwestern Yunnan, comprising the Yangtze and Shan-Thai microcontinents and the Simao block, has successively undergone subduction of an oceanic plate, followed by a collision of the microcontinents and intracontinental rifting associated with basaltic volcanism during Late Paleozoic to Mesozoic.The Triassic Nanjian basalts, erupted on the Yangtze microcontinent, have more enriched isotopic ratios and higher LREE/HFSE and LREE/HREE ratios. This suggests the existence of an enriched subcontinental lithosphere under the Yangtze microcontinent which stabilized over long periods of the earth's history (> 2Ga).The Middle Jurassic Simao basalts have more depleted geochemical features and also have element enrichments characteristic of a subduction zone environment, although the basalts were erupted in an intracontinental graben. It may be inferred that the lithospheric mantle of the Simao block was modified by subduction processes during Latest Carboniferous to Late Triassic prior to the onset of the Middle Jurassic continental rifting. The lack of correlation between depletion of HFSE, Y and HREE, and relative enriched Nd isotopic ratios suggests that the source depletion of the Simao basalts is not an old feature and has been contemporaneous with the subduction-related enrichment through mantle metasomatism shortly before the basalts were produced.The Middle Jurassic Baoshan basalts which erupted during the continental rifting on the Shan-Thai microcontinent have an Sr-Nd isotopic composition similar to the bulk earth and higher concentrations of incompatible trace elements. These features suggest that the subcontinental lithosphere under the Shan-Thai microcontinent underwent mantle metasomatism just prior to eruption of the Baoshan basalt.

---

Geochemie mesozoischer interkontinentaler Basalte aus Jünnan, Südchina: Hinweise auf die geochemische Entwicklung der subkontinentalen Lithosphäre

Zusammenfassung Südwestjünnan umfaßt den Jangtse und den Shan-Thai Mikrokontinent und den Simao Block. Das Gebiet wurde von aufeinander folgenden Subduktionsphasen einer ozeanischen Platte betroffen, auf die Kollision der Mikrokontinente und interkontinentales Rifting folgte. Dieses war mit basaltischem Vulkanismus während des späten Paläozoikums bis ins Mesozoikum assoziiert.Die triassischen Nanjian-Basalte, die auf dem Jangtse Mikrokontinent eruptierten, haben mehr angereicherte Isotopenverhältnisse und höhere LREE/HFSE und LREE/HREE Verhältnisse. Dieses weist auf eine angereicherte subkontinentale Lithosphäre unter dem Jangtse Mikrokontinent hin, die sich während langer Perioden der Erdgeschichte stabilisierte (>2Ga).Die mittel jurassischen Simao-Basalte haben eine mehr verarmte geochemische Signatur aber auch Elementanreicherungen, die für ein Subduktionszonen-Milieu charakteristisch sind, obwohl die Basalte in einem interkontinentalen Graben ausgetreten sind. Man kann daraus schließen, daß der lithosphärische Mantel des Simao-Blockes durch Subduktionsprozesse während des jüngsten Karbons bis in die späte Trias vor dem Beginn des mittel-jurassischen kontinentalen Riftings modifiziert worden war. Das Fehlen einer Korrelation zwischen der Anreicherung von HFSE, Y und HREE und relativ angereicherter Nd-Isotopenverhältnisse weist darauf hin, daß die Verarmung der Quelle der Simaobasalte nicht weit zurückreicht. Sie dürfte viel eher gleichaltrig mit der subduktions-bedingten Anreicherung durch Mantel-Metasomatose kurz vor der Entstehung der Basalte sein.Die mittel-jurassischen Baoshan-Basalte, die während des kontinentalen Riftings auf den Shan-Thai Mikrokontintent eruptierten, haben eine Sr-Nd-Isotopensignatur, die ähnlich der Gesamterde ist, jedoch höhere Konzentrationen inkompatibler Spurenelemente zeigt. All dies legt nahe, daß die subkontinentale Lithosphäre unter dem Shan-Thai-Mikrokontinent kurz vor der Eruption der Baoshan-Basalte von Mantel-Metasomatose betroffen worden ist.

---

---

With 8 Figures

---

Visiting Fellow, Geology Department, Australian National University, Australia     

http://www.sciencedirect.com/science/article/pii/S1674987115000870

Cap Carbonates overlie the Marinoan Snowball Earth-related glacial diamictite,and possibly record the drastic surface environmental change and biological evolution after the Snowball Earth.We conducted on-land drilling from the Liantuo Formation,through the Nantuo,to the lower Doushantuo Formation in the Three Gorges area of South China to collect fresh,continuous samples in the Three Gorges area.We obtained high-resolution chemostratigraphies of δ~(13)C and δ~(18)O values of carbonates from the topmost part of the Nantuo Formation to the Cap Carbonate,in order to decode the detailed surface environmental change in the shallow marine setting.The δ~(13)C chemostratigraphy possesses some unique characteristics:(1) stable δ~(13)C values as a whole,but ubiquitous low δ~(13)C anomalies through the Cap Carbonate,(2) increase of the δ~(13)C values from-3 to +5‰ across the C2/C3 boundary,(3) no δ~(13)C anomaly between the C1 and C2 boundary,and(4) presence of an anomalous high δ~(13)C value(+2.3‰)and a faint positive correlation between δ~(13)C and δ~(18)O values in the C1 unit.Evidence of quite low δ~(13)C anomalies(with a nadir of-41‰),ubiquitous negative δ~(13)C anomalies through the Cap Carbonate,and a high δ~(13)C anomaly accompanied with a faint positive correlation between δ~(13)C and δ~(18)O values in the C1 unit supports decomposition and formation of methane hydrate during Cap Carbonate formation.The drastic increase of δ~(13)C values from the upper C2 to C3 units indicates enhancement of primary productivity and organic carbon burial,possibly due to high continental fluxes after the Snowball Earth event,evidenced by high Sr isotope values.The increase is restricted to the proximal side of the inner shelf in South China,and the timing of the increase of δ~(13)C values of carbonates is earlier at Three Gorges area than any other area,suggesting that the enhancement of primary productivity started in the proximal environment because of higher continental influxes.The increase in oxygen contents of seawater due to the enhanced primary productivity possibly resulted in the emergence of multicellular animals soon after Cap Carbonate deposition.     

Modulation of tropical cyclogenesis in the western North Pacific by the quasi-biweekly oscillation

The quasi-biweekly oscillation(QBWO) is the second most dominant intraseasonal mode over the western North Pacific(WNP) during boreal summer. In this study, the modulation of WNP tropical cyclogenesis(TCG) by the QBWO and its association with large-scale patterns are investigated. A strong modulation of WNP TCG events by the QBWO is found.More TCG events occur during the QBWO's convectively active phase. Based on the genesis potential index(GPI), we further evaluate the role of environmental factors in affecting WNP TCG. The positive GPI anomalies associated with the QBWO correspond well with TCG counts and locations. A large positive GPI anomaly is spatially correlated with WNP TCG events during a life cycle of the QBWO. The low-level relative vorticity and mid-level relative humidity appear to be two dominant contributors to the QBWO-composited GPI anomalies during the QBWO's active phase, followed by the nonlinear and potential intensity terms. These positive contributions to the GPI anomalies are partly offset by the negative contribution from the vertical wind shear. During the QBWO's inactive phase, the mid-level relative humidity appears to be the largest contributor, while weak contributions are also made by the nonlinear and low-level relative vorticity terms.Meanwhile, these positive contributions are partly cancelled out by the negative contribution from the potential intensity.The contributions of these environmental factors to the GPI anomalies associated with the QBWO are similar in all five flow patterns—the monsoon shear line, monsoon confluence region, monsoon gyre, easterly wave, and Rossby wave energy dispersion associated with a preexisting TC. Further analyses show that the QBWO strongly modulates the synoptic-scale wave trains(SSWs) over the WNP, with larger amplitude SSWs during the QBWO's active phase. This implies a possible enhanced(weakened) relationship between TCG and SSWs during the active(inactive) phase. This study improves our understanding of the modulation of WNP TCG by the QBWO and thus helps with efforts to improve the intraseasonal prediction of WNP TCG.     

Model analysis of radar echo split observed in an artificial cloud seeding experiment

An artificial cloud seeding experiment was performed over the Japan Sea in winter to show how massive seeding could be effective to mitigate heavy snowfall damage. The results showed that 20 min after cloud seeding, a portion of the radar echo beneath the seeding track was weakened to divide the radar echo into two parts. In order to analyze the results, a numerical simulation was conducted by using the Weather Research and Forecasting model verion 3.5.1. In this simulation, the seeding effects were represented as phenomena capable of changing rain particles by accreting cloud ice and snow to form graupel particles and by changing cloud liquid water to snow particles. The graupel particles fell rapidly, thus temporarily intensifying the rainfall, which subsequently decreased. Therefore, the weakened radar echo in the field experiment is deemed to have been caused by the increase in rapidly falling graupel particles.     

Polar cap absorption on vlf emissions

It is shown that VLF emissions are greatly affected by the polar cap absorption caused by the bombardment of solar protons. Characteristics of the PCA effect on VLF emissions are examined and they are in agreement with those obtained by other studies, such as the polar blackout and the cosmic radio absorption. Therefore, the earlier conclusion that the occurrence frequency of VLF emissions decreases in high latitudes during magnetic storms is likely to be due to the PCA effect.

Taking this PCA effect into account, it is established that an enhancement of occurrence of VLF emissions occurs at geomagnetic latitudes lower than 67° during the magnetic storm. This suggests that enhanced VLF emissions during geomagnetic storms are generated in the co-rotating region of the magnetosphere or in the outer radiation belt, but not in the tail region.     

Characterization of vertical mixing at a tidal-front on Georges Bank

Studies of mixing were done at the northern flank of Georges Bank in the summer and autumn of 1988. Two time-series of the evolution and intensity of microstructure were examined over a tidal period in the context of tidal forcing and the evolution of the density and velocity field at the site. From the CTD, ADCP and microstructure observations (EPSONDE) on Georges Bank, several interesting features of the mixing processes were found. High dissipation and diffusivity regions appear near the bottom of the Bank. Turbulence near the bottom is highest in intensity and reaches farthest from the bottom at peak tidal flow and diminishes in intensity and vertical extent as the flow decreases. The thickness of the bottom turbulent layer has its maximum value when the flow is strongest and the stratification is weakest. Characterization of the dissipation rate and turbulent diffusivities in respect to buoyancy frequency N, current shear S, Richardson Number R_i and ε/νN² was done. Dissipation and χ_T showed little dependence on shear or N² but decreased at larger R_i. χ_t was found to be higher in regions of higher N² and increased as ε/νN² increased. K_T, K and K_ν, were all highest near the bottom in excess of 10⁻²m²s⁻¹ and decreased towards the surface. There was little suggestion of a dependence of mixing efficiency on S², R_i or ε/νN², but some indication that Γ decreases with decreasing N².     

Water and flow variations in Sagami Bay under the influence of the Kuroshio path

Variations of water and flow in Sagami Bay in relation to the Kuroshio path variations are examined by using 100m-depth temperature and salinity data from 25 stations as well as sea level data from five stations (Minami-Izu, ItÔ, Ôshima, Aburatsubo, Mera). In regard to temperature, anomalies from the mean seasonal variations are used. Results show that water properties are clearly different between the three typical paths of the Kuroshio. The difference is more remarkable in temperature than in salinity; temperature is higher during the typical large-eander (LM) path, and lower during the offshore non-large-meander (NLM) path, compared with the nearshore NLM path. Temperature anomaly and salinity distributions, as well as the Ôshima minus Minami-Izu and Ôshima minus Mera sea-level differences strongly suggest that the flows during the typical LM path are distributed as hitherto described in past studies, that is, water in the mouth region of the bay flows clockwise around Ôshima from the west channel to the east channel, and a counterclockwise eddy exists in the interior. On the other hand, flows during the nearshore and offshore NLM paths seem to be quite different from those during the typical LM path; velocities are very weak, and the directions of circulation is frequently reversed. This tendency also can be seen during parts of LM period in which the Kuroshio takes a non-typical LM path.Water properties in Sagami Bay are most characteristic during transitions between nearshore and offshore NLM paths. During transitions from nearshore to offshore NLM paths, temperatures are extremely high as a whole in the bay, while during reverse transitions, both temperatures and salinities are very low in the entire region.     

On wave-free floating-body forms in heaving oscillation

Some wave-free heaving forms are obtained in a manner similar to Bessho's earlier work by using a source and vertical dipole combination to generate bulbous-shaped two and three-dimensional bodies which have zero radiation damping. Then the combinations of higher singularities, such as triple-pole and quadra-pole, are considered. Using the thin-ship approximation, where the boundary condition is satisfied on the centreline, a simple procedure for generating any arbitrary shape that has the same property is established. The existence of wave-free frequencies of such bodies are verified numerically, in two dimensions by a standard singularity-distribution method based on the actual body-contour and in three-dimensions by using vortex-ring distribution for an axisymmetric body. Experiments are carried out for the models obtained theoretically and the results support the theoretical predictions fairly well. Finally, some suggestions are made to apply such a wave-free body to a moored buoy to suppress its heaving oscillation.     

Dynamics of elastically moored floating objects

The two-dimensional problem of wave transformation by, and motions of, moored floating objects is solved numerically as a boundary value problem by direct use of Green's identity formula for a potential function. The cross-sectional shape of the floating object, the bottom configuration and the mooring arrangements may be all arbitrary. For a given incident wave, the three modes of body motion, the wave system and mooring forces are all solved at the same time. A laboratory experiment is conducted to verify the theory. Generally good agreements between the theory and experiments are obtained as long as the viscous damping due to flow separation is small. A numerical experiment indicates that a conventional sluck mooring is to worsen the wave attenuation by a floating breakwater and that a properly arranged elastic mooring can considerably improve the wave attenuation by a floating breakwater.