Upper Silurian and Devonian pelagic deep-water radiolarian chert from the Khangai–Khentei belt of Central Mongolia: Evidence for Middle Paleozoic subduction–accretion activity in the Central Asian Orogenic Belt

Recent mapping projects undertaken in Central Mongolia have revealed the widespread occurrence of radiolarian chert within a Paleozoic accretionary complex. We present the results of the first detailed tectonostratigraphic and radiolarian biostratigraphic investigations of the Gorkhi Formation in the Khangai–Khentei belt of the Central Asian Orogenic Belt.The Gorkhi Formation consists of sandstone shale, alternating sandstone and shale of turbidite affinity and chert with small amounts of siliceous shale, basalt, limestone, and clast-bearing mudstone. Radiolarian chert that is completely devoid of terrigenous clastic material is commonly associated with underlying basalt (sedimentary contact) and with conformably overlying siliceous shale and turbidite deposits. The tectonic stacking of basalt–chert and chert–turbidite successions is the most remarkable structural feature of the formation.The recovery of moderately well-preserved radiolarians and conodonts from red chert led to the recognition of four radiolarian assemblages that have a combined age range from the latest Silurian (Pridolian) to the Late Devonian (Frasnian). No age control exists for the siliceous shale, shale, and sandstone, although they are considered to be latest Devonian or slightly younger on the basis of stratigraphic relationships with underlying chert.The Gorkhi Formation has previously been interpreted as a thick sedimentary basin deposit overlying an unexposed Archean–Neoproterozoic basement; however, the stratigraphy within individual tectonic slices clearly corresponds to that of an ocean plate stratigraphy of an accretionary complex generated by the trenchward movement of an oceanic plate. From the lowermost to uppermost units, the stratigraphy comprises ocean floor basalt, pelagic deep-water radiolarian chert, hemipelagic siliceous shale, and terrigenous turbidite deposits. The biostratigraphic data obtained in the present study provide corroborating evidence for the existence of an extensive deep-water ocean that enabled the continuous sedimentation of pelagic chert over a period of nearly 50 million years. These data, together with structural data characterized by tectonic repetition of the stratigraphy, indicate that these rocks formed as an accretionary wedge along an active continental margin, possibly that of the Angara Craton. The mid-oceanic chert was probably deposited in the Northern Hemisphere portion of the Paleo–Pacific Ocean that faced the Angara Craton and the North China–Tarim blocks. Thus, we propose that subduction–accretion processes along the Paleo–Pacific rim played an important role in the accretionary growth of the active continental margin of the Angara Craton, directly influencing the evolution of the Central Asian Orogenic Belt.     

Modeling of damage,permeability changes and pressure responses during excavation of the TSX tunnel in granitic rock at URL,Canada

This paper presents numerical modeling of excavation-induced damage, permeability changes, and fluid-pressure responses during excavation of a test tunnel associated with the tunnel sealing experiment (TSX) at the Underground Research Laboratory (URL) in Canada. Four different numerical models were applied using a wide range of approaches to model damage and permeability changes in the excavation disturbed zone (EDZ) around the tunnel. Using in situ calibration of model parameters, the modeling could reproduce observed spatial distribution of damage and permeability changes around the tunnel as a combination of disturbance induced by stress redistribution around the tunnel and by the drill-and-blast operation. The modeling showed that stress-induced permeability increase above the tunnel is a result of micro and macrofracturing under high deviatoric (shear) stress, whereas permeability increase alongside the tunnel is a result of opening of existing microfractures under decreased mean stress. The remaining observed fracturing and permeability changes around the periphery of the tunnel were attributed to damage from the drill-and-blast operation. Moreover, a reasonably good agreement was achieved between simulated and observed excavation-induced pressure responses around the TSX tunnel for 1 year following its excavation. The simulations showed that these pressure responses are caused by poroelastic effects as a result of increasing or decreasing mean stress, with corresponding contraction or expansion of the pore volume. The simulation results for pressure evolution were consistent with previous studies, indicating that the observed pressure responses could be captured in a Biot model using a relatively low Biot-Willis’ coefficient, α ≈ 0.2, a porosity of n ≈ 0.007, and a relatively low permeability of k ≈ 2 × 10⁻²² m², which is consistent with the very tight, unfractured granite at the site.     

A case study on the influence of THM coupling on the near field safety of a spent fuel repository in sparsely fractured granite

In order to demonstrate the feasibility of geological disposal of spent CANDU fuel in Canada, a safety assessment was performed for a hypothetical repository in the Canadian Shield. The assessment shows that the maximum long term radionuclide release from such repository would meet international criteria for dose rate; however, uncertainties in the assumed evolution of the repository were identified. Such uncertainties could be resolved by the consideration of coupled Thermal-Hydro-Mechanical-Chemical (THMC) processes. In Task A of the DECOVALEX-THMC project, THM models were developed within the framework of the theory of poroelasticity. Such model development was performed in an iterative manner, using experimental data from laboratory and field tests. The models were used to perform near-field simulations of the evolution of the repository in order to address the above-mentioned uncertainties. This paper presents the definition and rationale of task A and the results of the simulations. From a repository safety point of view, the simulations predict that the maximum temperature would be well below the design target of 100°C; however, the stress on the container can marginally exceed the design value of 15 MPa. However, the most important finding from the simulations is that a rock damage zone could form around the emplacement borehole. Such damage zone can extend a few metres from the walls of the emplacement holes, with permeability values that are orders of magnitude higher than the initial values. The damage zone has the potential to increase the radionuclide transport flux from the geosphere; the effect of such an increase should be taken into account in the safety assessment and mitigated if necessary by the provision of sealing systems. Prepared for publication in Environmental Geology. DECOVALEX-THMC Special Issue.     

On the interpretation of low-latitude hydrological proxy records based on Maunder Minimum AOGCM simulations

An increasing number of proxy records, which are related to changes in the hydrological cycle, have been collected for climate reconstructions of the last millennium. There has been, however, little attempt to test climate models with such proxy records or to interpret proxy records using climate model simulations. In the present study, we analyze the hydrological changes between three different types of experiments: a present-day control, a perpetual AD 1640, and an ensemble of six transient Maunder Minimum (AD 1640–1715) simulations. Atmospheric moisture transport is investigated in terms of contributions of specific humidity and circulation changes. The study points out the importance of the specific humidity contribution to changes in moisture transport reflected in hydrological proxy records. The moisture budget of the western tropical Pacific is also investigated to aid the interpretation of a proxy record in this specific region. The present-day freshening of the western tropical Pacific, compared to the Maunder Minimum, is explained by the increased zonal moisture transport via trade winds, mainly due to the increased amount of atmospheric water vapor content in the warming world. Due to the existence of several uncertainty factors, such as forcing reconstructions, the link between the model simulations and proxy records is, however, not definitive, but the thermal contribution to hydrological proxy records is important and not limited to the Maunder Minimum period.     

Seismicity gap near Oaxaca,southern Mexico as a probable precursor to a large earthquake

Summary An area of significant seismic quiescence is found near Oaxaca, southern Mexico. The anomalous area may be the site of a future large earthquake as many cases so far reported were. This conjecture is justified by study of past seismicity changes in the Oaxaca region. An interval of reduced seismicity, followed by a renewal of activity, preceded both the recent large events of 1965 and 1968. Those past earthquakes have ruptured the eastern and western portions of the present seismicity gap, respectively, so that the central part remaining is considered to be of the highest risk of the pending earthquake.The most probable estimates are: 7 1/2±1/4 for the magnitude and =16.5°±0.5°N, =96.5°±0.5W for the epicenter location. A firm prediction of the occurrence time is not attempted. However, a resumption of seismic activity in the Oaxaca region may precede a main shock.On leave from the Marine Science Institute, University of Texas, USA.     

Broad-band power-law spectra of well-log data in Japan

For the purpose of revealing the statistical characteristics of P -wave velocity, S -wave velocity and density in the uppermost part of the crust, we analysed well-log data obtained from five deep wells in different tectonic regions in Japan: three wells through the mainly sedimentary rocks in the Kanto plain and two wells in the Kuju volcano group in Kyushu Island. In the Kanto plain, the power spectral density of fractional fluctuation of P -wave velocity and that of density are proportional to a power of the spatial wavelength from a few metres to 100 m. where the power index (slope of the power spectral density at double logarithmic scale) is 1.1-1.3. At the Kuju volcano group, that of P - and S -wave velocity and density also obey a power law, with a power index of 1.3-1.6 for wavelengths from a few metres to few hundred metres. Correcting the effect of the moving box-car observation window which corresponds to the separation of two receivers of the logging tool, we find that the power-law characteristics hold for wavelengths down to a few tens of centimetres. The 1-D sections of the elastic inhomogeneities follow a kind of band-limited self-affine random process. Comparing the power spectral densities, we find smaller values of the power index in stable areas and larger values in tectonically active areas. The difference in the power index arises from long-wavelength components.     

A search for the Hα emission in spectroscopic binaries of the spectral types B0–B9

The H emission is searched for 67 spectroscopic binaries of the spectral types B0–B9 and of the orbital period 1–1000 days. Among them the H emission is detected in 13 stars with various intensity. The results of this inspection are presented. When combined with the previous data, our results show that the Be-star frequency in spectroscopic binaries along the orbital periods exhibits a sharp maximum in the period range 100–300 days, and that the stars of strong H emission concentrate in the same period range.     

Distribution of Trace Bioelements in the Subarctic North Pacific Ocean and the Bering Sea (the R/V Hakuho Maru Cruise KH-97-2)

A column concentration-high resolution inductively coupled plasma mass spectrometry (ICP-MS) determination was applied to measure the total dissolved concentrations of Fe, Co, Ni, Cu and Zn in seawater collected from the subarctic North Pacific (~45°N) and the Bering Sea in July–September 1997. Total adsorbable Mn was determined on board by column electrolysis preconcentration and chemiluminescence detection. The vertical profiles for Fe, Ni and Zn were nutrient-like. The deep water concentration of Fe was ~0.5 nM in the northeast Pacific (18°-140°W) and increased to ~1 nM in the northwest Pacific (161°E) and ~2 nM in the Bering Sea (57°N, 180°E). The deep water concentrations for Ni and Zn in the Bering Sea were also 1.3–2 times higher than in the North Pacific. The profiles for Co and Cu were examined in the subarctic North Pacific, and results obtained were consistent with previous reports. There was a significant correlation between the concentrations of Co and Mn except for surface mixed layer. The profiles for total adsorbable Mn were similar to the reported profiles for total dissolvable Mn. The deep water concentration of Mn in the Bering Sea was also 4 times higher than in the North Pacific. Iron and zinc were depleted in surface water of the subarctic North Pacific. The relationship between these trace elements and nutrients suggests that these elements could be a limiting factor of phytoplankton productivity. In the Bering Sea, surface water contained ~0.3 nM of Fe. The Zn concentration, which was less than the detection limit in surface water, increased at shallower depths (~30 m) compared with the subarctic North Pacific. These results imply a higher flux of Fe and Zn to surface water in the Bering Sea. This in turn may cause the ecosystem in the Bering Sea characterized by a dominance of diatoms and high regenerated production.     

Quantitative micro‐X‐ray fluorescence scanning spectroscopy of wet sediment based on the X‐ray absorption and emission theories: Its application to freshwater lake sedimentary sequences

Micro‐X‐ray fluorescence scanning spectroscopy of marine and lake sedimentary sequences can provide detailed palaeoenvironmental records through element intensity proxy data. However, problems with the effects of interstitial pore water on the micro‐X‐ray fluorescence intensities have been pointed out. This is because the X‐ray fluorescence intensities are measured directly at the surfaces of split wet sediment core samples. This study developed a new method for correcting X‐ray fluorescence data to compensate for the effects of pore water using a scanning X‐ray analytical microscope. This involved simultaneous use of micro‐X‐ray fluorescence scanning spectroscopy and an X‐ray transmission detector. To evaluate the interstitial pore water content from the X‐ray transmission intensities, a fine‐grained sediment core retrieved from Lake Baikal (VER99‐G12) was used to prepare resin‐embedded samples with smooth surfaces and uniform thickness. Simple linear regression between the linear absorption coefficients of the samples and their porosity, based on the Lambert–Beer law, enabled calculation of the interstitial pore spaces and their resin content with high reproducibility. The X‐ray fluorescence intensities of resin‐embedded samples were reduced compared with those of dry sediment samples because of: (i) the X‐ray fluorescence absorption of resin within sediment; and (ii) the sediment dilution effects by resin. An improved micro‐X‐ray fluorescence correction equation based on X‐ray fluorescence emission theory considers the instrument's sensitivity to each element, which provides a reasonable explanation of these two effects. The resin‐corrected X‐ray fluorescence intensity was then successfully converted to elemental concentrations using simple linear regression between the data from micro‐X‐ray fluorescence scanning spectroscopy and from the conventional analyzer. In particular, the calculated concentration of SiO₂ over the depth of the core, reflecting diatom/biogenic silica concentration, was significantly changed by the calibrations, from a progressively decreasing trend to an increasing trend towards the top of the core.