Reintroduction of gold, other chalcophile elements and LILE during retrogression of depleted granulite, Tromøy, Norway

Several metamorphic and magmatic events were associated with the Sveconorwegian orogeny ( 1.1 Ga) that affected the Bamble shear belt, south Norway. Among the most important were (1) granuliteto amphibolite-facies metamorphism of the entire belt; (2) intrusion of mafic dykes (“hyperites”), followed by their localized metamorphism to amphibolite; (3) intrusion of granitic sheets, which in granulite terrane caused rehydration and retrogression. Previous studies have shown that rocks from across the belt metamorphosed to amphibolite and granulite grade during event (1) are strongly depleted in Au, Sb and As; while some granulites are also depleted in Rb, Cu and S. Gold and chalcophile elements were also lost during (2) amphibolization of hyperites. This paper is concerned with event (3), at which time the granulites had been uplifted and cooled. H₂O---CO₂ fluids, at least in part derived from the granitic magma, caused localized rehydration and retrogression of granulite. This was accompanied by the variable reintroduction of the same elements (Au, As, Sb, Cu, S and Rb) that had earlier been depleted. The nature of the reintroduction of Au and other elements has relevance to the origin of mesothermal gold deposits.     

Composition of groundwaters associated with porphyry-Cu deposits, Atacama Desert, Chile: Elemental and isotopic constraints on water sources and water-rock reactions

Groundwaters were collected around the Spence porphyry copper deposit, Atacama Desert, northern Chile, to study water-porphyry copper ore bodies interaction and test hypotheses regarding transport of metals through thick overburden leading to the formation of soil geochemical anomalies. The deposit contains 400 Mt of 1% Cu and is completely buried by piedmont gravels of Miocene age. Groundwaters were recovered from the eastern up hydraulic gradient (upflow) margin of the Spence deposit, from within the deposit, and for two kilometers down flow from the deposit. Water table depths decrease from 90 m at the upflow margin to 30 m 1.5 km down flow. Groundwaters at the Spence deposit are compositionally variable with those upflow of the deposit characterized by relatively low salinities (900-7000 mg/L) and Na⁺-SO₄²⁻-type compositions. These waters have compositions and stable isotope values similar to regional groundwaters recovered elsewhere in the Atacama Desert of Northern Chile. In contrast, groundwaters recovered within and down flow of the deposit range in salinity from 10,000 to 55,000 mg/L (one groundwater at 145,000 mg/L) and are dominantly Na⁺-Cl⁻-type waters. Dissolved sulfate values are, however, elevated compared to upflow waters, and δ³⁴S_CDT decreases into the deposit (from >4‰ to 2‰), consistent with increasing influence of sulfur derived from oxidation of sulfide minerals within the deposit. The increase in salinity and conservative tracers (Cl⁻, Br⁻, Li⁺, and Na⁺) and the relationship between oxygen and hydrogen isotopes suggests that in addition to water-rock reactions within the deposit, most of the compositional variation can be explained by groundwater mixing (with perhaps a minor role for evaporation). A groundwater-mixing scenario implies a deeper, more saline groundwater source mixing with the less saline regional groundwater-flow system. Flow of deeper, more saline groundwater along pre-existing structures has important implications for geochemical exploration and metal-transport models.     

Early Ipswichian (last interglacial) sea level rise in the channel region: Stone Point Site of Special Scientific Interest,Hampshire, England

Constraining the speed of sea level rise at the start of an interglacial is important to understanding the size of the ‘window of opportunity’ available for hominin migration. This is particularly important during the last interglacial when there is no evidence for significant hominin occupation anywhere in Britain. There are very few finer grained fossiliferous sequences in the Channel region that can be used to constrain sea level rise and they are preserved only to the north of the Channel, in England. Of these, the sequence at Stone Point SSSI is by far the most complete. Data from this sequence has been previously reported, and discussed at a Quaternary Research Association Field Meeting, where a number of further questions were raised that necessitated further data generation. In this paper, we report new data from this sequence – thin section analysis, isotopic determinations on ostracod shells, new Optical Stimulated Luminescence ages and Amino Acid Recem analyses. These show early sea level rise in this sequence, starting during the pre-temperate vegetation zone IpI, but no early warming. The implications of this almost certainly last interglacial sequence for the human colonisation of Britain and our understanding of the stratigraphic relationship of interglacial estuarine deposits with their related fluvial terrace sequences is explored.     

Role of melt during deformation in the deep crust

Deformation in the deep crust is strongly influenced by the presence of melt. Injected melt (or magma) weakens the crust because strain will tend to localize where melt is present. The amount of strain a pluton may accommodate is dependent on the length of time it takes for a pluton to crystallize and the strain rate. For plutons that intrude into rocks which are near the solidus temperature of the melt, crystallization times can be quite long (> 1Myr).
Partial melting of deep crustal rocks can lead to melt-enhanced embrittlement. This occurs because the volume change for most melting reactions is positive. Therefore, when the rate of melt production outpaces the rate at which melt can leave the system, the melt pressure increases. Eventually, the melt pressure may become sufficiently high that the melting rocks behave in a brittle fashion and fracture.
Conjugate sets of dilatant shear fractures filled with melt occur in migmatite from the Central Gneiss belt (Canada); this suggests that melt-enhanced embrittlement occurred in these rocks. An expression which relates the magnitude of differential stress to the angle between conjugate dilatant shear fractures is derived. Assuming that migmatite has a small tensile strength, differential stresses are ≤ 20 MPa in migmatitic rocks at the time melt-enhanced embrittlement occurs. The occurrence of melt-enhanced embrittlement shows that a switch in deformation mechanism from plastic flow to cataclasis is possible in the deep crust during melting. Furthermore, repeated episodes of melt-enhanced embrittlement in migmatitic rocks may be an efficient mechanism for extracting melt from partially melted terrains.     

A Pool-Based Model of the Spatial Distribution of Undiscovered Petroleum Resoufrces

An approach is proposed to predict the spatial distributions of undiscovered petroleum resources. Each pool is parameterized as a marked-point. The independence chain of the Hastings algorithm is used to generate an appropriate structure for pool combinations in a play. Petroleum-bearing favorability estimated from geological observations is used to represent the sampling probabilities of pool locations. An objective function measuring the distance between characteristics of the realization and constraints is constructed from both the pool size distribution and entropy maximum criterion, in which the entropy criterion places all undiscovered pools in the most favorable positions. The geometrical convergence property of the proposed Hastings algorithm is presented. The method is illustrated by a case study from the Western Canada Sedimentary Basin.     

Boninite primary magmas: Evidence from the Cape Vogel Peninsula,PNG

Boninites from Cape Vogel, PNG, are dominantly pyroxene-glass rocks, but many contain olivine, sometimes as refractory as Fo₉₄. We derive a parental magma for this suite (in equilibrium with Fo₉₄) which contains 20 wt.% MgO and is quartz-normative. This liquid is hydrous, and from petrographie evidence and whole rock H₂O⁺ values, we estimate it to contain 2–3 wt.% H₂O. These data suggest olivine fractionation and primary magmatic water are important in boninite genesis, but both are often obscured by later alteration. The derived parental magma has probably formed at 1,250–1,300° C and low pressures (< ?10kB) and is similar to those which gave rise to olivine-clinoenstatite phyric boninites from New Caledonia and from Howqua, Australia, and possibly to a proposed parental magma for the Bushveld Complex.     

Nonstoichiometry in sillimanite: Mullite compositions with sillimanite-type superstructures

Complete solid solution between sillimanite and mullite is shown to occur when Fe³⁺, in the virtual absence of Ti, replaces Al^VI. All members of the series adopt the sillimanite (Al, Si)^IV ordering scheme in preference to the modulated structure typical of synthetic and titaniferous natural mullites.     

Olivine-matrix reactions in thermally metamorphosed Apollo 14 breccias

Olivine clasts, which have mantles formed by reaction of the olivine with the breccia matrix, are present in the high-grade thermally metamorphosed Apollo 14 breccias. The mantled olivine clasts are most abundant in 14311, but they are also present in 14304 and 14319. Typically the mantles consist of two zones: an inner corona containing pyroxene, ilmenite and commonly plagioclase, and an outer light-colored halo where the matrix is depleted in ilmenite. The growth of the coronas involved matrix-to-corona diffusion of TiO₂ and corona-to-matrix diffusion of MgO and FeO. These diffusive fluxes can be attributed to chemical potential gradients developed between mineral assemblages in local equilibrium at the olivine-corona boundary and the matrix.     

Future heat vulnerability in California, Part II: projecting future heat-related mortality

Through the 21^st century, a significant increase in heat events is likely across California (USA). Beyond any climate change, the state will become more vulnerable through demographic changes resulting in a rapidly aging population. To assess these impacts, future heat-related mortality estimates are derived for nine metropolitan areas in the state for the remainder of the century. Heat-related mortality is first assessed by initially determining historical weather-type mortality relationships for each metropolitan area. These are then projected into the future based on predicted weather types created in Part I. Estimates account for several levels of uncertainty: for each metropolitan area, mortality values are produced for five different climate model-scenarios, three different population projections (along with a constant-population model), and with and without partial acclimatization. Major urban centers could have a greater than tenfold increase in short-term increases in heat-related mortality in the over 65 age group by the 2090s.     

On the response of yielding seismically isolated structures

This paper investigates the seismic response of yielding isolated structures. To establish a general understanding of the nonlinear response of seismically isolated structures, this study first investigates the nonlinear response of isolated structures subjected to steady‐state harmonic motion and nonlinear transient ground excitation. The response of both viscously damped and hysteretically damped isolation systems is investigated in three phases. Initially, basic insights are gained through simple nonlinear two degrees of freedom (2‐DOF) models subjected to harmonic motion of varying frequencies. Next, the transient response analysis of the nonlinear 2‐DOF model is investigated for a wide range of isolation system and superstructure properties. The results obtained from both approaches indicate that the yielding behavior of a structure on an isolation system is significantly different from that of the comparable fixed‐base structure. Finally, the response of the nonlinear 2‐DOF system model is compared with that of a 15‐story, three‐dimensional model. Based on the results of these analytical investigations, some important considerations for the design of seismically isolated structures are presented. Copyright © 2007 John Wiley & Sons, Ltd.