Rare earth element evidence concerning the origin of voluminous mid-Tertiary rhyolitic ignimbrites and related volcanic rocks,Sierra Madre Occidental,Chihuahua, Mexico

The mid-Tertiary volcanic sequence of the central Sierra Madre Occidental in Chihuahua, Mexico, is about one kilometer thick and is composed predominantly of rhyolitic ignimbrites. Basaltic andesite to dacitic lavas are interbedded with the rhyolites, but they are of minor volumetric importance. Rare earth element (REE) data are used to constrain a crustal anatexis model for the origin of the voluminous ignimbrites and to test a fractional crystallization model. The REE patterns indicate that if the rhyolites were formed by direct crustal anatexis, the residue from partial melting could contain no more than a few percent garnet or about 20% hornblende. This eliminates residues with the mineralogy of amphibolite, eclogite, or garnet granulite, but melting of a garnet-free granulite source is permitted. The crustal anatexis model is difficult to evaluate critically because of a lack of knowledge concerning the mid-Tertiary geothermal gradient and the composition of the crust beneath the Sierra Madre Occidental.In contrast, the fractional crystallization model can be tested rigorously. Rayleigh fractionation calculations are used to closely model REE patterns in the basaltic andesite to rhyolite series. The minerals involved are those occurring as phenocryst phases, and the mineral proportions were generated by leastsquares major element calculations. The results of the calculations are consistent with the hypothesis that the voluminous rhyolites originated by plagioclase-dominated crystal fractionation.     

The petrology of greek brown coals

Results are given in the petrography of Greek coals collected from most of the major coal-bearing basins in Greece.Rank was determined by measuring reflectances on the maceral varieties eu-ulminite A and eu-ulminite B and on the maceral textinite. Reflectances obtained from these components indicate a coalification stage of brown coal for all samples. Within this group of samples there is, however, a fairly wide scatter of reflectance values indicating for some of them the transition zone from peat to brown coal and for others a coalification stage close to the transition into bituminous coals. Reflectances obtained from eu-ulminite A and eu-ulminite B were found to correlate well with chemical rank parameters such as volatile matter and calorific value.Composition was determined by maceral analysis. The coals are in general characterized by low amounts of macerals of the inertinite group, low to intermediate amounts of macerals of the liptinite group and high amounts of macerals of the huminite group. Within the latter group densinite, attrinite, eu-ulminite and textinite make up the bulk of the samples.Typical macerals observed in the coals are illustrated by two black and white and three colour plates.Cluster analysis based on maceral distribution, mineral matter and reflectance indicates that the samples studied can be divided into three major groups. The first one is dominated by eu-ulminite and densinite with relatively high reflectances. The second is dominated by attrinite, textinite and texto-ulminite with somewhat lower reflectances. The third is represented by a single sample in which textinite and resinite are the most abundant macerals. This sample also has the lowest reflectance.     

Petrology of fine-grained rock fragments and petrologic implications of single crystals from the Luna 20 soil

Only fine-grained rocks are present in the Luna 20 samples, and coarser grained rocks are represented by fragments of single crystals. A petrologic study has been made of 47 fine-grained crystalline rocks, microbreccias, and glassy aggregates. In addition, a total of 33 single crystals of pyroxene, plagioclase, olivine and spinel, in the size range 125 to 500 μ, have been examined using electron microprobe and single crystal X-ray diffraction techniques.The most abundant fine-grained crystalline rocks in the samples we have examined are recrystallized anorthositic norite and anorthositic troctolite. Gabbroic rocks, anorthosite, and KREEP basalt are present but not common. Most of the single crystals of pyroxene and plagioclase could have been derived from coarser grained noritic, troctolitic and anorthositic rocks. However, three of the 14 pyroxene crystals, and 2 of the 5 olivine crystals have $\text{Fe}\text{(Fe + Mg)}$ contents greater than 0.45 and are believed to have been derived from mare basalts or related rocks. Two relatively sodic crystals of plagioclase were found. One is a crystal zoned at least over the range An₈₅ to An₆₃, and the second is a homogeneous crystal of albite (~An₃).     

Atacamite formation by deep saline waters in copper deposits from the Atacama Desert,Chile: evidence from fluid inclusions,groundwater geochemistry,TEM, and <Superscript>36</Superscript>Cl data

The presence of large amounts of atacamite in oxide zones from ore deposits in the Atacama Desert of northern Chile requires saline solutions for its formation and hyperarid climate conditions for its preservation. We investigated the nature and origin of atacamite-forming solutions by means of coupling groundwater geochemical analyses with fluid inclusion data, high-resolution mineralogical observations, and chlorine-36 (³⁶Cl) data in atacamite from the Mantos Blancos and Spence Cu deposits. In both deposits, the salinities of fluid inclusions in atacamite are comparable to those measured in saline groundwaters sampled from drill holes. The average salinity of fluid inclusions in atacamite for the Mantos Blancos and Spence deposits (~7–9 and 2–3 wt.% NaCl_eq, respectively) are strongly correlated to the salinities at which gypsum supersaturates from groundwaters in both deposits (total dissolved solids ~5–9 and 1–3 wt.% NaCl_eq, respectively). This correlation is confirmed by transmission electron microscopy observations of atacamite-bearing samples, revealing an intimate association between atacamite and gypsum that can be traced down to the nanometer scale. ³⁶Cl data in atacamite provide new lines of evidence concerning the origin and age of the saline waters that formed atacamite in various stratabound and porphyry Cu deposits from the Atacama Desert. All atacamite samples show very low ³⁶Cl-to-Cl ratios (11 × 10⁻¹⁵ to 28 × 10⁻¹⁵ at at⁻¹), comparable to previously reported ³⁶Cl-to-Cl ratios of deep formation waters and old groundwaters. In addition, ³⁶Cl-to-Cl ratios in atacamite correlate with U and Th concentration in the host rocks but are independent from distance to the ocean. This trend supports an interpretation of the low ³⁶Cl-to-Cl ratios in atacamite as representing subsurface production of fissiogenic ³⁶Cl in secular equilibrium with the solutions involved in atacamite formation. Therefore, ³⁶Cl in atacamite strongly suggest that the chlorine in saline waters related to atacamite formation is old (>1.5 Ma) but that atacamite formation occurred more recently (<1.5 Ma) than suggested in previous interpretations. Our data provide new constraints on the origin of atacamite in Cu deposits from the Atacama Desert and support the recent notion that the formation of atacamite in hyperarid climates such as the Atacama Desert is an ongoing process that has occurred intermittently since the onset of hyperaridity.     

Impact of diagenesis on reservoir quality in a sedimentary geothermal play: a case study in the Cooper Basin,South Australia

Geothermal resources hosted within sedimentary basins with high natural permeability have been targeted for the production of energy in Australia. The Hutton Sandstone (Cooper‐Eromanga Basin) – a prolific oil and gas producer known to have good reservoir quality and high reservoir volume – was recently tested for its geothermal potential in the Cooper Region. However, recent exploratory drilling did not produce the anticipated flow rates, raising the question of the impact of diagenesis on the reservoir quality of this sedimentary formation. The combined characterization of the petrology, diagenesis and petrophysical properties of the Hutton Sandstone at Celsius‐1 and other surrounding wells indicates variable reservoir properties in the Cooper Region. This integrated study demonstrates that low formation permeability occurs at geothermal target depth and explains the negligible flow rates obtained at Celsius‐1. These low permeabilities are the results of the preservation of widespread detrital clayey matrix and the extensive occurrence of authigenic kaolinite, illite and silica cements at the top and base of the Hutton Sandstone. This aspect is confirmed by NMR T₂ transversal relaxation time becoming shorter at similar depths. Petrography analysis also reveals that sandstones are affected by diagenetic processes of the eogenetic and mesogenetic phases. However, the Hutton Sandstone at Celsius‐1 is presently at pressure‐temperature conditions that are below the mesogenetic conditions, which suggests a late episode of uplift and cooling from maximum palaeotemperatures.     

Size matters: experimental partitioning of the strength of fish herbivory on a fringing coral reef in Moorea,French Polynesia

While the importance of top‐down control by grazers in maintaining tropical reef community structure is well known, the effect of ‘fishing down the food web’, which simultaneously changes the abundance and size of herbivorous fishes, has received less attention. As many fishing practices target the biggest fish and regulations often set minimum size limits, understanding size‐dependency of this controlling force is important. We evaluated the hypothesis that reduction in the abundance and size of fish, regardless of species identity, reduces the role of herbivory in controlling algal abundance on reefs and assessed variation in efficacy of this top‐down control on different types of common macroalgae. We quantified herbivory rates within cages of differing opening sizes on assemblages of four common algal species (Padina boryana, Dictyota bartayresiana, Halimeda opuntia and Galaxaura fasciculata) on two fringing reefs in Moorea, French Polynesia. Small acanthurids (<15 cm length) were the dominant herbivorous fish while other herbivorous fish were rare. For the two most palatable algae, the majority of herbivory occurred in open plots, with herbivory reduced by >50% in the largest opening cages (6 × 6 cm) where the maximum size fish entering was 12 cm in length (mean = 7.6, SE = 0.4). Fish entering medium (4.5 × 4.5 cm openings, maximum fish length = 8 cm, mean = 6.3, SE = 0.4) and small (3 × 3 cm openings, no fish observed entering) cages had herbivory rates approximately equal to the control treatment (1 × 1 cm openings). Consumption varied among algal species, with minimal consumption of physically and chemically defended algae and no pattern across treatments. Our results demonstrate a need for management plans to not only maintain the overall abundance of herbivorous fish but to protect the largest sizes for effective top‐down control of algal communities.     

Surface inhomogeneities and line variability on DF Tau

We have mapped surface inhomogeneities on the classical T Tauri star DF Tau, using the Li  i doublet at 670.8 nm, the Ca  i lines at 612.2 nm and 643.9 nm and a calcium and iron blend at 646.3 nm. We find compelling evidence that there are hotspots with temperatures of more than 5000 K. Two of the hotspots produce line-profile deformations that can be traced as they move through the cross-correlated profiles. When one of the hotspots crosses the stellar disc, redshifted absorption components appear in the Na D lines. As these redshifted absorption features are usually tracers for mass-infall we interpret this hotspot as an accretion shock close to the stellar surface.   Parts of the surface of DF Tau are covered with a hot chromosphere that is visible in the Ca  ii infrared triplet lines and the narrow component of He  i . We find no correlation between the veiling and the lines that originate from the hot chromosphere, suggesting that the veiling and the chromospheric emission are produced in physically distinct regions.     

Latitude distributions and lifetimes of star-spots on G dwarfs in the α Persei cluster

We present a set of maximum-entropy reconstructions of the star-spot distributions on two rapidly rotating G dwarfs in the α Persei cluster, from spectra taken at the William Herschel Telescope on three nights in 1996 October and November. Since these stars are too faint for conventional Doppler imaging, which makes use of only one or a few lines, we take the large number of photospheric metal lines available in an echelle spectrum, and deconvolve them into a single, high signal-to-noise ratio profile. We show that this technique results in a typical multiplex gain of 22.5 in signal-to-noise ratio for a given spectrum, the equivalent of using a single line obtained on a 63-m telescope. The image reconstructions demonstrate that both these stars have cool high-latitude regions or polar crowns, and low-latitude features, in contradiction to the suggestion that only high-latitude spots should be present. Cross-correlation between image reconstructions of He 699, 31 days apart, reveals a lack of correlation between detailed small-scale structures. This places an upper limit for the lifetime of the observed features at less than one month. The Hα profiles are also found to exhibit absorption features indicating the presence of prominence clouds, at or below the corotation radius.