Jupiter: New retrieved thermal profiles and ammonia distributions

New thermal profiles of Jupiter are retrieved from recent far infrared spectral measurements and for H₂ mixing ratios varying from 0.8 to 0.94. The effective temperature corresponding to the inferred thermal profile is 123.15 ± 0.35°K. Far-infrared brightness temperature spectra computed from these profiles are compared to experimental data including measurements made at high spectral resolution in the NH₃ν₂ band at 10 μm and in NH₃ pure rotational bands between 40 and 110 μm. It is found that a strong depletion of NH₃ does occur in the Jovian stratosphere and that ammonia seems to be undersaturated in the upper troposphere.     

Organic geochemistry of silicified wood,Petrified Forest National Park,Arizona

Lignin derivatives have been isolated for the first time from carbonaceous sections of the silicified (~90% SiO₂) conifer Araucarioxylon arizonicum. The products released by sequential high vacuum pyrolysis and identified by combined gas chromatography-mass spectrometry (GC-MS) include a wide variety of alkyl-substituted, phenolic and condensed aromatic compounds.Brauns spruce lignin was pyrolized and analyzed by GC-MS as a comparison for the fossil wood data. The primary pyrolyzates at the 300°C step were CO₂, H₂O, ethanol and propanol. The main product at 450°C was 4-methyl-2-methoxyphenol (methyl guaiacol), but at 600°C the pyrolyzates were similar both in product composition and in relative abundance to those from silicified wood. The results suggest that the fossil wood experienced a mild thermal event during which the ether bonds were ruptured and loss of oxygen occurred along with the rearrangement of the original wood into a highly stable polymer.     

Phytoliths as indicators of pedogenesis and paleoenvironmental changes in the Brazilian cerrado

This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed.     

A geochronological approach to understanding the role of solar activity on Holocene glacier length variability in the Swiss Alps

We present a radiocarbon data set of 71 samples of wood and peat material that melted out or sheared out from underneath eight presentday mid‐latitude glaciers in the Central Swiss Alps. Results indicated that in the past several glaciers have been repeatedly less extensive than they were in the 1990s. The periods when glaciers had a smaller volume and shorter length persisted between 320 and 2500 years. This data set provides greater insight into glacier variability than previously possible, especially for the early and middle Holocene. The radiocarbon‐dated periods defined with less extensive glaciers coincide with periods of reduced radio‐production, pointing to a connection between solar activity and glacier melting processes. Measured long‐term series of glacier length variations show significant correlation with the total solar irradiance. Incoming solar irradiance and changing albedo can account for a direct forcing of the glacier mass balances. Long‐term investigations of atmospheric processes that are in interaction with changing solar activity are needed in order to understand the feedback mechanisms with glacier mass balances.     

Characterization and migration of atmospheric REE in soils and surface waters

Rainwater and snow collected from three different sites in France (Vosges Mountains, French Alps and Strasbourg) show more or less similar shapes of their REE distribution patterns. Rainwater from Strasbourg is the most REE enriched sample, whereas precipitations from the two mountainous, less polluted catchments are less REE enriched and have concentrations close to seawater. They are all strongly LREE depleted.Different water samples from an Alpine watershed comprising snow, interstitial, puddle and streamwater show similar REE distributions with LREE enrichment (rainwater normalized) but MREE and HREE depletion. In this environment, where water transfer from the soil to the river is very quick due to the low thickness of the soils, it appears that REE in streamwater mainly originate from atmospheric inputs. Different is the behaviour of the REE in the spring- and streamwaters from the Vosges Mountains. These waters of long residence time in the deep soil horizons react with soil and bedrock REE carrying minerals and show especially significant negative Eu anomalies compared to atmospheric inputs. Their Sr and Nd isotopic data suggest that most of the Sr and Nd originate from apatite leaching or dissolution. Soil solutions and soil leachates from the upper soil horizons due to alteration processes strongly depleted in REE carrying minerals, have REE distribution patterns close to those of lichens and throughfall. Throughfall is slightly more enriched especially in light REE than filtered rainwater probably due to leaching of atmospheric particles deposited on the foliage and also to leaf excretion.Data suggest that Sr and Nd isotopes of the soil solutions in the upper soil horizons originate from two different sources: 1) An atmospheric source with fertilizer, dust and seawater components and 2) A source mainly determined by mineral dissolution in the soil. These two different sources are also recognizable in the Sr and Nd isotopic composition of the tree’s throughfall solution. The atmospheric contributions of Sr and Nd to throughfall and soil solution are of 20 to 70 and 20%, respectively. In springwater, however, the atmospheric Sr and REE contribution is not detectable.     

Tectonique transpressive en terre Adélie au Paléoprotérozoı̈que (Est Antarctique)Palaeoproterozoic transpression in Terre Adélie (East Antarctica)

The Palaeoproterozoic units of Terre Adélie show two types of structural domains associated with HT–LP metamorphic conditions: domes and NS–N340° striking vertical shear zones. Shear zones reflect dextral transpressive motions. Domes reflect sub-vertical shortening and principal stretching subparallel to shear zones. They could partly result from longitudinal flow coeval with transpression. Deformations are comparable to those described along the eastern and western boundaries of the Archean Gawler Craton (South-East Australia), which underlines the continuity between these two areas before opening of the Austral Ocean. To cite this article: A. Pelletier et al., C. R. Geoscience 334 (2002) 505–511.