Occurrence of phthalate diesters in rivers of the Paris district (France)

The occurrence and fate of six phthalate esters were investigated in the River Seine and two tributaries in the Paris area, at six sites from upstream to downstream, throughout different seasons, with special attention given to a flood episode. At all sites, except the River Marne, whatever the period, diethylhexyl phthalate (DEHP) displayed the highest concentration (0·323–0·779 µg l^?1 as mean values), followed by di‐n‐butyl phthalate (DnBP; 0·211–0·526 µg l^?1 as mean values), which is consistent with the production pattern. High phthalate concentrations appeared to be related to population density and industrial distribution. The strongest values were located downstream from wastewater treatment plant effluent inputs. Seasonal variations were closely related to river flow and air and water temperature. The annual evolution of phthalates was linked to the hydrological conditions. During the flood episode at Paris, the DEHP concentration displayed a sharp increase (260 to 1123 ng l^?1) occurring 9 days before the flood peak. The simultaneous fluctuations of NH₄, typical of domestic origin, and of DEHP suggests a similar origin from combined sewer overflows for both compounds. Other elevated values corresponded to the highest precipitation amounts, and demonstrated the contribution of non‐point‐source runoff and wastewater overflow to DEHP inputs. The DEHP concentration relationship with river flow displayed a clockwise hysteresis loop, corresponding to a ‘first‐flush’ effect in which the finite supplies are swept along in the early stage of the flood. Annual fluxes for 2004 at Paris were 2257 kg of DEHP and 1613 kg of DnBP. The flood period seemed to have a minor impact on annual phthalate transport (29·5% and 41% of the total for DEHP and for DnBP, respectively), which is contrary to annual suspended solids transport (69%). Copyright © 2007 John Wiley & Sons, Ltd.     

High to low velocity succession in the upper crust related to tectonic emplacement: Tras os Montes-Galicia (Iberia), Brittany and Limousin (France)

Summary. Seismic probing of the upper crust in a catazonal massif in Tras os Montes, Hercynian Iberia, demonstrates the absence of a root towards the lower crust and favours a mechanism of thrust and nappe emplacement. Similar high to low velocity successions in the upper crust are evidenced in particular segments of the Hercynian domain of France. All these occurrences are related to a type region to which a particular meaning has been given in a recent plate tectonics interpretation of the Hercynian orogenesis. This model, implying large-scale nappe displacement and intracrustal thrusts furnishes in turn a general mechanism for the tectonic formation of upper crustal high and low velocity layers of limited extent in orogenic cycles.     

Desalination of a sedimentary rock aquifer system invaded by Pleistocene Champlain Sea water and processes controlling groundwater geochemistry

The objective of this study was to identify geochemical processes and Quaternary geological events responsible for the variations in groundwater geochemistry observed in a sedimentary rock aquifer system, including brackish to saline groundwater. Inorganic constituents and environmental isotopes were analyzed for 146 groundwater samples. Dissolution of carbonates dominates in recharge areas, resulting in Ca-, Mg-HCO₃ groundwater. Further along flow paths, under confined conditions, Ca²⁺–Na⁺ ion exchange causes groundwater evolution to Na-HCO₃ type. Na-Cl groundwater is also found and it falls on a seawater mixing line. Using conservative tracers, Cl⁻ and Br⁻, the original Champlain Sea water is shown to have been, in the region, a mixture of about 34% seawater and 66% freshwater, a composition still retained by some groundwater. Na-Cl groundwater thus results from mixing with former Champlain Sea water and also from solute diffusion from overlying marine clay. The system is thus found to be at different stages of desalinization, from the original Champlain Sea water still present in hydraulically stagnant areas of the aquifer to fully flushed conditions in parts, where more flow occurs, especially in recharge zones. The geochemical processes are integrated within the hydrogeological context to produce a conceptual geochemical evolution model for groundwater of the aquifer system.     

Hydrogeochemistry and groundwater origin of the Basses-Laurentides sedimentary rock aquifer system, St. Lawrence Lowlands, Québec, Canada

A comprehensive hydrogeochemical study was carried out in the Paleozoic Basses-Laurentides sedimentary rock aquifer system in Québec over a 1500 km² study area. Groundwater samples were collected at 153 sites, characterizing all geological and hydrogeological units to a maximum depth of 140 m. Groundwater was analyzed for major, minor and trace inorganic constituents, stable isotopes δ ²H, δ ¹⁸O, and δ ¹³C of dissolved inorganic carbon (DIC), and some samples were analyzed for ³H, and ¹⁴C of DIC. The regional distribution of groundwater types shows that the hydrogeological conditions exert a dominant control on the major ions chemistry of groundwater. Preferential recharge areas are characterized by tritiated Ca-Mg-HCO₃ groundwater, and confined conditions by submodern Na-HCO₃ and Na-Cl groundwater types. Two groundwater end-members are identified in the aquifer system, modern meteoric water and Pleistocene Champlain Sea water. The region displays significant variations of groundwater geochemistry and quality controlled by glaciation, Champlain Sea invasion, lithological rock diversity, and flow system scales. This situation leads to varied groundwater types and origins within a restricted area.     

Caractérisation de zones sources de DNAPL à l'aide de traceurs bisolubles : mise en évidence d'une cinétique de partage

Pollution source characterization by the Partitioning Interwell Tracer Test method requires the assessment of the partitioning coefficient of the tracers with the pollutant. Experiments conducted on batch tests (static) and laboratory columns (dynamic) indicated a partitioning kinetics between the reactive tracer (4-methyl 2-pentanol) and the organic phase (trichlorethene); the partitioning coefficient decreases when the flow velocity through the porous medium increases. This partitioning kinetics has been confirmed by the interpretation of the tracer breakthrough curves with a first-order kinetic transfer model. To cite this article: M. Bohy et al., C. R. Geoscience 336 (2004).     

The mafic–ultramafic complex of Sikhoran (central Iran): a polygenetic ophiolite complexLe massif basique-ultrabasique de Sikhoran (Iran central) : un complexe ophiolitique polygénétique

The mafic–ultramafic complex of Sikhoran presents a long geological history, marked out by various magmatic, metamorphic and tectonic events. This history is much more complex than a simple ophiolite obduction over a continental margin. As early as the Upper Permian, following a mantle uprise in a Tethysian supra-subduction zone, the opening of a (back-arc?) basin in extensional/transtensional conditions provoked the intrusion of multiple gabbroic dykes, veins and plutons charged with fluids, through a mafic/ultramafic complex and its metamorphic cover. Several basins, characterised by abundant submarine basaltic volcanism developed during Jurassic, whose feeding dykes may be represented by the diabase dyke swarms intruding the whole Sikhoran complex and its metamorphic cover. To cite this article: H. Ghasemi et al., C. R. Geoscience 334 (2002) 431–438.     

New data on the kinetics of the dissolution of alkali feldspars at 200°C in CO2 charged water

The kinetics of the dissolution of a (Na. K) sanidine in CO₂-charged water, were studied experimentally at 200°C as a function of the surface area s and of the time t. The molalities of Na⁺ and K⁺ have been plotted against the product st. As for albite and adularia (Lagache, Bull. Soc. Fr. Minéral. Cristallogr. 88, 223–253, 1965), the rates of dissolution of Na² and K⁺ are smooth continuous functions of st, which implies that they are controlled by the composition of the solution.The comparison between the dissolution of pure sodic or potassic feldspars and that of an intermediate feldspar shows that the sanidine dissolves as if it were composed of albite and K-feldspar grains in the proportions corresponding to its composition.Theoretical considerations presented by Helgeson (Geochim. Cosmochim. Acta35, 421–169, 1971; The Feldspars, pp. 184–217, 1972) and Pa?es (Geochim. Cosmochim. Acta37, 2641–2663, 1973) are reviewed: both had suggested, arguing from my first experimental results, that the dissolution could be described by a process of diffusional mass transfer through a surface layer of reaction products.The present experiments do not agree with such an interpretation of the mechanism of dissolution.