A new magnetostratigraphic framework for the Lower Miocene (Burdigalian/Ottnangian, Karpatian) in the North Alpine Foreland Basin

Oligocene–Miocene chronostratigraphic correlations within the Paratethys domain are still highly controversial. This study focuses on the late Early Miocene of the Swiss and S-German Molasse Basin (Late Burdigalian, Ottnangian–Karpatian). Previous studies have published different chronologies for this time interval that is represented by the biostratigraphically well constrained Upper Marine Molasse (OMM, lower and middle Ottnangian), Upper Brackish Molasse (OBM, Grimmelfingen and Kirchberg Formations, middle and upper Ottnangian to lower Karpatian, MN 4a–MN 4b) and Upper Freshwater Molasse (OSM, Karpatian–Badenian, MN 5). Here, we suggest a new chronostratigraphic framework, based on integrated magneto-litho-biostratigraphic studies on four sections and three boreholes. Our data indicate that the OBM comprises chrons 5D.1r and 5Dn (Grimmelfingen Fm), chron 5Cr (lower Kirchberg Fm) and the oldest part of chron 5Cn.3n (upper Kirchberg Fm). The OSM begins during chron 5Cn.3n, continues through 5Cn, and includes a long reversed segment that can be correlated to chron 5Br. The OMM-OSM transition was completed at 16.0 Ma in the Swiss Molasse Basin, while the OBM-OSM changeover ended at 16.6 Ma in the S-German Molasse Basin. As the lower Kirchberg Fm represents a facies of the Ottnangian, our data suggest that the Ottnangian–Karpatian boundary in the Molasse Basin is approximately at 16.8 Ma, close to the 5Cr–5Cn.3n magnetic reversal, and thus 0.4 Myr younger than the inferred age of 17.2 Ma used in recent Paratethys time scales. Notably, this would not be problematic for the Paratethys stratigraphy, because chron 5Cr is mainly represented by a sedimentation gap in the Central Paratethys. We also realise, however, that additional data is still required to definitely solve the age debate concerning this intriguing time interval in the North Alpine Foreland Basin. We dedicate this work to our dear friend and colleague Jean-Pierre Berger (8 July 1956–18 January 2012).     

Alternative conceptual models and the robustness of groundwater management scenarios in the multi-aquifer system of the Central Veneto Basin, Italy

A three-dimensional (3D) groundwater flow model of the deep multi-aquifer Quaternary deposits of the Po plain sedimentary basin, within a 3,300-km² area (Veneto, Italy), is developed, tested and applied to aid sustainable large-scale water-resources management. Integrated mathematical modelling proves significantly successful, owing to an unusual wealth of available geological, geophysical, and hydrologic data and to state-of-the-art numerical tools. Of particular interest is the evaluation of the influence of alternative conceptual models; that is, of reconstructed representations of the 3D geological model of the structure of the aquifers. The reference conceptual model is set up by means of extended geological sections and stratigraphic records, and is used to create a large, unstructured 3D finite element grid. By analyzing the effects on piezometric surfaces and on the overall water budget of geometrical perturbations from the reference structure, alternative geo-structural models, obtained by systematically shifting the pinch-out of the aquitards, are compared. Interestingly, the impacts of aquitard pinch-out prove far from negligible. The results suggest the critical importance of reliable geological models even for large, complex 3D models. The good practice of iteratively testing numerically the impact of surprises on the conceptual model, as more field information is collected, is thus supported.     

Spatio-temporal microseismicity clustering in the Cretan region

Spatio-temporal clustering of microseismicity in the central forearc of the Hellenic Subduction Zone in the area of Crete is investigated. Data for this study were gathered by temporary short period networks which were installed on the islands of Crete and Gavdos between 1996 and 2004. The similarity of waveforms is quantified systematically to identify clusters of microseismicity. Waveform similarities are calculated using an adaptive time window containing both the P- and S-wave onsets. The cluster detection is performed by applying a single linkage approach. Clusters are found in the interplate seismicity as well as in the intraplate seismicity of the continental crust in the region of the transtensional Ptolemy structure. The majority of the clusters are off the southern coast of Crete, in a region of elevated intraplate microseismic activity within the Aegean plate. Clusters in the Gavdos region are located at depths compatible with the plate interface while cluster activity in the region of the Ptolemy trench is distributed along a nearly vertical structure throughout the crust extending down to the plate interface. Most clusters show swarm-like behaviour with seismic activity confined to only a few hours or days, without a dominant earthquake and with a power law distribution of the interevent times.For the largest cluster, precise relocations of the events using travel time differences of P- and S-waves derived from waveform cross correlations reveal migration of the hypocenters. This cluster is located in the region of the Ptolemy trench and migration occurs along the strike of the trench at  500 m/day.Relocated hypocenters as well as subtle differences in the waveforms suggest an offset between the hypocenters and thus the activation of distinct patches on the rupture surface. The observed microseismicity patterns may be related to fluids being transported along the plate interface and escaping towards the surface in zones of crustal weakness (Ptolemy structure), triggering swarm-like cluster activity along its way.     

Annual dynamics of pelagic primary production and respiration in a shallow coastal basin

The Wadden Sea (North Sea, Europe) is a shallow coastal sea with high benthic and pelagic primary production rates. To date, no studies have been carried out in the Wadden Sea that were specifically designed to study the relation between pelagic respiration and production by comparable methods. Because previous studies have suggested that the import of primary-produced pelagic organic matter is important for benthic Wadden Sea carbon budgets, we hypothesised that on an annual average the northern Wadden Sea water column is autotrophic. To test this hypothesis, we studied annual dynamics of primary production and respiration at a pelagic station in a shallow tidal basin (List Tidal Basin, northern Wadden Sea). Since water depth strongly influences production estimates, we calculated primary production rates per unit area in two ways: on the basis of the mean water depth (2.7 m) and on the basis of 1 m depth intervals and their respective spatial extent in the List Tidal Basin. The latter more precise estimate yielded an annual primary production of 146 g C m^− 2 y^− 1. Estimates based on the mean water depth resulted in a 40% higher annual rate of 204 g C m^− 2 y^− 1. The total annual pelagic respiration was 50 g C m^− 2 y^− 1. The P/R ratio varied between seasons: from February to October the water column was autotrophic, with the highest P/R ratio of 4–5 during the diatom spring bloom in April/May. In autumn and winter the water column was heterotrophic. On an annual average, the water column of the List Tidal Basin was autotrophic (P/R 3). We suggest that a large fraction of the pelagic produced organic matter was respired locally in the sediment.     

Late Pleistocene spread of (cool-)temperate forests in Northeast China and climate changes synchronous with the North Atlantic region

The results presented here from the annually laminated sedimentary sequence of Sihailongwan lake provide the first comprehensive palaeoecological record covering the Late Pleniglacial to the Early Holocene (16,700–10,600 cal yrs. BP) from Northeast China. High-resolution pollen analyses have enabled the vegetational and climatic changes of the last glacial-interglacial transition to be reconstructed in more detail than has been previously possible. Moreover, a reliable chronology has been provided by both varve counting and 40 calibrated AMS ¹⁴C age determinations.Palaeobotanical evidence indicates predominantly steppe and open taiga-like woodland communities, with abundant Betula, Larix, Alnus fruticosa, Artemisia, grasses and sedges, which are typical of cold and dry conditions between 16,700 and 14,450 cal yrs. BP. The beginning expansion of Ulmus and Fraxinus marks the onset of the Late-glacial climatic amelioration at 14,450 cal yrs. BP. Dense deciduous forests, predominantly consisting of thermophilous broadleaf taxa, become established and widespread during the Early Holocene.Two short-term climatic reversals to colder and/or dryer conditions are recorded in the proxy data between 13,900 and 13,800 cal yrs. BP and 13,100 and 12,900 cal yrs. BP, correlating with the Oldest Dryas/Greenland Interstadial (GI) 1d event and the Gerzensee/Killarney/GI-1b oscillation, respectively. The prominent reappearance of Picea and Larix, coupled with a marked decrease in broadleaved trees, prior to the start of the Holocene, implies a climatic reversal compatible with the Younger Dryas event in the circum-Atlantic region. The evident synchroneity of climate changes in the North Atlantic region and East Asia supports the theory of strong atmospheric coupling between both regions.     

Biological Impact of Elevated Ocean CO<Subscript>2</Subscript> Concentrations: Lessons from Animal Physiology and Earth History

CO₂ currently accumulating in the atmosphere permeates into ocean surface layers, where it may impact on marine animals in addition to effects caused by global warming. At the same time, several countries are developing scenarios for the disposal of anthropogenic CO₂ in the worlds' oceans, especially the deep sea. Elevated CO₂ partial pressures (hypercapnia) will affect the physiology of water breathing animals, a phenomenon also considered in recent discussions of a role for CO₂ in mass extinction events in earth history. Our current knowledge of CO₂ effects ranges from effects of hypercapnia on acid-base regulation, calcification and growth to influences on respiration, energy turnover and mode of metabolism. The present paper attempts to evaluate critical processes and the thresholds beyond which these effects may become detrimental. CO₂ elicits acidosis not only in the water, but also in tissues and body fluids. Despite compensatory accumulation of bicarbonate, acid-base parameters (pH, bicarbonate and CO₂ levels) and ion levels reach new steady-state values, with specific, long-term effects on metabolic functions. Even though such processes may not be detrimental, they are expected to affect long-term growth and reproduction and may thus be harmful at population and species levels. Sensitivity is maximal in ommastrephid squid, which are characterized by a high metabolic rate and extremely pH-sensitive blood oxygen transport. Acute sensitivity is interpreted to be less in fish with intracellular blood pigments and higher capacities to compensate for CO₂ induced acid-base disturbances than invertebrates. Virtually nothing is known about the degree to which deep-sea fishes are affected by short or long term hypercapnia. Sensitivity to CO₂ is hypothesized to be related to the organizational level of an animal, its energy requirements and mode of life. Long-term effects expected at population and species levels are in line with recent considerations of a detrimental role of CO₂ during mass extinctions in the earth's history. Future research is needed in this area to evaluate critical effects of the various CO₂ disposal scenarios. This revised version was published online in July 2006 with corrections to the Cover Date.     

Al Huwaysah 010: The most reduced brachinite,so far

Al Huwaysah 010 is an ungrouped achondrite meteorite, recently referred to as a brachinite-like meteorite. This meteorite, showing a fine-grained assemblage of low-Ca pyroxene and opaque phases, is strongly reduced in comparison to other reduced brachinites. The occurrence of some tiny plates of graphite and oldhamite in this meteorite suggests that a partial melt residue has experienced a further reduction process. Olivine, the most abundant phase, is compositionally homogeneous (Fo_83.3) as well as the clinopyroxene (En_45.5Fs_10.8Wo_43.7) and the plagioclase (Ab_69.5). Orthopyroxene (En_85.4Fs_13.9Wo_0.7) also occurs but only in a fine intergrowth. Other accessory phases are Fe metal grains (Ni-free or Cr-bearing Fe-Ni alloy), troilite, chlorapatite, pentlandite (as inclusions in chromite). The sample shows two different closure temperatures: the highest (≈900°C) is determined via the olivine–chromite intercrystalline geothermometer and the lowest temperature (≈520°C) is determined via the pyroxene-based intracrystalline geothermometer. These temperatures may represent, respectively, the closure temperature associated with the formation and a subsequent impact event excavating the sample from the parental body. The visible to near-infrared (VNIR) reflectance spectra of Al Huwaysah 010 exhibit low reflectance, consistent with the presence of darkening components, and weak absorptions indicative of olivine and pyroxene. Comparing the spectral parameters of Al Huwaysah 010 to potential parent bodies characterized by olivine–pyroxene mineralogy, we find that it falls within the field previously attributed to the SIII type asteroids. These results lead us to classify the Al Huwaysah 010 meteorite as the most reduced brachinite, whose VNIR spectral features show strong affinities with those of SIII asteroids.     

Opening a new window to other worlds with spectropolarimetry

A high level of diversity has already been observed among the planets of our own Solar System. As such, one expects extrasolar planets to present a wide range of distinctive features, therefore the characterisation of Earth- and super Earth-like planets is becoming of key importance in scientific research. The Search (Spectropolarimetric Exoplanet AtmospheRe CHaracerisation) mission proposal of this paper represents one possible approach to realising these objectives. The mission goals of Search include the detailed characterisation of a wide variety of exoplanets, ranging from terrestrial planets to gas giants. More specifically, Search will determine atmospheric properties such as cloud coverage, surface pressure and atmospheric composition, and may also be capable of identifying basic surface features. To resolve a planet with a semi major axis of down to 1.4 AU and 30 pc distant Search will have a mirror system consisting of two segments, with elliptical rim, cut out of a parabolic mirror. This will yield an effective diameter of 9 m along one axis. A phase mask coronagraph along with an integral spectrograph will be used to overcome the contrast ratio of star to planet light. Such a mission would provide invaluable data on the diversity present in extrasolar planetary systems and much more could be learned from the similarities and differences compared to our own Solar System. This would allow our theories of planetary formation, atmospheric accretion and evolution to be tested, and our understanding of regions such as the outer limit of the Habitable Zone to be further improved.     

Geochemical and organic petrological characterization of the organic matter of lacustrine Eocene oil shales (Prinz von Hessen,Germany): reconstruction of the depositional environment

Optical and geochemical techniques were applied to sedimentary organic matter from the profundal area of the Eocene Lake Prinz von Hessen, which formed in a pull-apart basin on the Sprendlinger Horst, near Darmstadt, Germany. Variations in total sulphur content (S tot) and total organic carbon content (TOC), hydrogen index (HI), oxygen index (OI) and ¹³C values of the organic matter were used to reconstruct the lakes filling history. Following an initial rapid deepening phase, open lake conditions developed with HI reaching more than 500 mg HC/g TOC and TOC values up to 40%. The productivity of the lake was probably high and organic matter preservation was enhanced by a stratified water column. As the lake began to fill with sediment and became shallower, TOC and HI values declined, as the lake water was better oxygenated and preservation conditions declined. ¹³C values between –31 and –27 are controlled by the mixing of aquatic (algae and microbial mats) and terrigenous organic matter (wood, spores, pollen and cuticles). Following a rapid drop in lake level, shallow lake conditions alternated with swamp deposits (lignites) in the basin center. The organic matter preserved during this stage is strictly terrigenous in nature and experienced oxic degradation (HI 100 mg HC/g TOC). ¹³C values between –26 and –24 are typical for Eocene terrigenous matter. The inferred lake level fluctuations are interpreted to have been controlled by tectonic as well as climatic processes.