Variable sequence of events during the past seven terminations in two deep-sea cores from the Southern Ocean

The relationships among internally consistent records of summer sea-surface temperature (SSST), winter sea ice (WSI), and diatomaceous stable isotopes were studied across seven terminations over the last 660 ka in sedimentary cores from ODP sites 1093 and 1094. The sequence of events at both sites indicates that SSST and WSI changes led the carbon and nitrogen isotopic changes in three Terminations (TI, TII and TVI) and followed them in the other four Terminations (TIII, TIV, TV and TVII). In both TIII and TIV, the leads and lags between the proxies were related to weak glacial mode, while in TV and TVII they were due to the influence of the mid-Pleistocene transition. We show that the sequence of events is not unique and does not follow the same pattern across terminations, implying that the processes that initiated climate change in the Southern Ocean has varied through time.     

Walking algorithms for point location in TIN models

Finding which triangle in a planar or 2.5D triangle mesh contains a query point (so-called point location problem) is a frequent task in geosciences, especially when working with triangulated irregular network models. Usually, a large number of point locations has to be performed, and so there is a need for fast algorithms having minimal additional memory requirements and resistant to changes in the triangulation. So-called walking algorithms offer low complexity, easy implementation, and negligible additional memory requirements, which makes them suitable for such applications. In this article, we focus on these algorithms, summarize, and compare them with regard to their use in geosciences. Since such a summary has not been done yet, our article should serve those who are dealing with this problem in their application to decide which algorithm would be the best for their solution. Moreover, the influence of the triangulation type on the number of the visited triangles is discussed.     

Volcanic tsunami: a review of source mechanisms, past events and hazards in Southeast Asia (Indonesia, Philippines, Papua New Guinea)

Southeast Asia has had both volcanic tsunamis and possesses some of the most densely populated, economically important and rapidly developing coastlines in the world. This contribution provides a review of volcanic tsunami hazard in Southeast Asia. Source mechanisms of tsunami related to eruptive and gravitational processes are presented, together with a history of past events in the region. A review of available data shows that many volcanoes are potentially tsunamigenic and present often neglected hazard to the rapidly developing coasts of the region. We highlight crucial volcanic provinces in Indonesia, the Philippines and Papua New Guinea and propose strategies for facing future events.     

Ca2Mg(NO3)6×12H2O–structural investigations on a new compound retrieved from chimney deposits of a combined heat and power plant

Phase analysis of incrustations retrieved from chimney deposits of a combined heat and power plant in Malchow/Germany by X-ray powder diffraction gave evidence for the existence of a previously unknown hydrous calcium magnesium nitrate. Optical investigations of the sample showed the presence of colorless platy crystals with a maximum diameter of about 250 μm embedded in a partly polycrystalline and partly glassy matrix. Aided by EDX-analysis and Raman spectroscopy, a single-crystal diffraction study performed at ambient conditions demonstrated that the material represents a phase with composition Ca₂Mg(NO₃)₆×12H₂O. Basic crystallographic data are as follows: trigonal symmetry, space group type R \( \overline{3} \) , a?=?10.5583(5) Å, c?=?19.5351(10) Å, V?=?1885.97(16) ų, Z?=?3, (R(|F|) = 0.0248). The magnesium ions are coordinated by water molecules to form distorted Mg(H₂O)₆-octahedra. The calcium atoms are surrounded by nine ligands. The resulting CaO₉ tricapped trigonal prisms involve oxygen atoms from additional water moieties as well as from three different bidentate nitrate groups, respectively. Hydrogen bonds link one octahedron with two adjacent prisms into trimers. The trimers in turn are stacked in columns running parallel to [001]. Further hydrogen bonding between neighboring columns results in the formation of a three-dimensional network. To our best knowledge, Ca₂Mg(NO₃)₆×12H₂O represents a new structure type. However, column-like topologies with rods consisting of different types of polyhedra have been also observed in other trigonal hydrous nitrates. The structural relationships between these compounds are discussed. It is interesting to note that in previous phase equilibrium studies on the ternary system Ca(NO₃)₂-Mg(NO₃)₂-H₂O no other hydrous double salt has been described. Finally, the results of the structure analysis allowed a qualitative and quantitative phase analysis of the crystalline part of the chimney deposit by the Rietveld method.     

Potential microbial bioinvasions via ships' ballast water, sediment, and biofilm

A prominent vector of aquatic invasive species to coastal regions is the discharge of water, sediments, and biofilm from ships' ballast-water tanks. During eight years of studying ships arriving to the lower Chesapeake Bay, we developed an understanding of the mechanisms by which invasive microorganisms might arrive to the region via ships. Within a given ship, habitats included ballast water, unpumpable water and sediment (collectively known as residuals), and biofilms formed on internal surfaces of ballast-water tanks. We sampled 69 vessels arriving from foreign and domestic ports, largely from Western Europe, the Mediterranean region, and the US East and Gulf coasts. All habitats contained bacteria and viruses. By extrapolating the measured concentration of a microbial metric to the estimated volume of ballast water, biofilm, or residual sediment and water within an average vessel, we calculated the potential total number of microorganisms contained by each habitat, thus creating a hierarchy of risk of delivery. The estimated concentration of microorganisms was greatest in ballast water>sediment and water residuals>biofilms. From these results, it is clear microorganisms may be transported within ships in a variety of ways. Using temperature tolerance as a measure of survivability and the temperature difference between ballast-water samples and the water into which the ballast water was discharged, we estimated 56% of microorganisms could survive in the lower Bay. Extrapolated delivery and survival of microorganisms to the Port of Hampton Roads in lower Chesapeake Bay shows on the order of 10(20) microorganisms (6.8 x 10(19) viruses and 3.9 x 10(18) bacteria cells) are discharged annually to the region.     

Firms and sustainability: Mapping the intellectual origins and structure of the corporate sustainability field

Business research has repeatedly been criticized for its lack of engagement with pressing issues such as climate change, despite a surge of publications on corporate sustainability topics in recent years. We are therefore interested in identifying the knowledge development and knowledge gaps in business scholarship on the relationship between firms, environment and society. This paper provides a systematic review of the corporate sustainability field in form of a bibliometric analysis based on citation data acquired from the Social Sciences Citation Index. The final dataset contained 3117 records published between 1953 and 2011. Our analysis shows that, over the last 50 years, the field of corporate sustainability has emerged from a few primary nodes of research and developed into four distinct conceptual genealogies: corporate social performance theory, stakeholder theory, a corporate social performance versus economic performance debate, and a greening of management debate. The results of our analysis suggest four key findings. First, the four genealogies only comprise a relatively narrowly focused research scope. Second, there is very little integration and citation of work in other disciplinary areas such as ecology or environmental science. Third, the existing literature has a strong focus on empirically examining the relationship between a firm's environmental and/or social performance and its financial performance. Finally, there is little consideration of managerial implications and consequences of climate change in the corporate sustainability literature to date. We suggest that while this may be a reflection of an insular field, it may also be a role played by the management literature turning away from problem based issues in favor of empirical results, theory building, and the identification of variables that influence firm profitability and can be subjected to direct managerial control. We conclude by outlining pathways for future research.     

Collisional velocities and rates in resonant planetesimal belts

We consider a belt of small bodies (planetesimals, asteroids, dust particles) around a star, captured in one of the external or 1:1 mean-motion resonances with a massive perturber (protoplanet, planet). The objects in the belt collide with each other. Combining methods of celestial mechanics and statistical physics, we calculate mean collisional velocities and mean collisional rates, averaged over the belt. The results are compared to collisional velocities and rates in a similar, but non-resonant belt, as predicted by the particle-in-a-box method. It is found that the effect of the resonant lock on the velocities is rather small, while on the rates more substantial. At low to moderate eccentricities and libration amplitudes of tens of degrees, which are typical of many astrophysical applications, the collisional rates between objects in an external resonance are by about a factor of two higher than those in a similar belt of objects not locked in a resonance. For Trojans under the same conditions, the collisional rates may be enhanced by up to an order of magnitude. The collisional rates increase with the decreasing libration amplitude of the resonant argument, depend on the eccentricity distribution of objects, and vary from one resonance to another. Our results imply, in particular, shorter collisional lifetimes of resonant Kuiper belt objects in the solar system and higher efficiency of dust production by resonant planetesimals in debris disks around other stars.     

Historical problems of travel for women geologists

From unsuitable clothes to lack of chaperones, from harassment to lack of proper funding, throughout history women geologists have encountered difficulties travelling to their field locations or working in the field, whether these locations were close by or abroad. Most early female geologists were able to avoid many difficulties because they were protected through working locally, where their high social standing was known and respected, or because they worked in a team with husband, father or brother. However, the problem was to grow in the second half of the nineteenth century, when women started to appear as students and professionally trained geologists. This feature explores the difficulties of female geologists undertaking fieldwork from the late nineteenth to the mid-twentieth century.     

Consequences of anthropogenic activity for two remote alpine lakes in NW Slovenia as tracked by sediment geochemistry

Several geological and geochemical parameters were determined in the sediments of the 5th (5 J) and 6th (6 J) Triglav Lakes, Julian Alps (NW Slovenia), in order to study the impact of natural catchment characteristics and anthropogenic activity. Fish were introduced into both lakes in 1991 and a mountain hut lies on the shore of 5 J. Sedimentary grain size (GS) was distinctly coarser in 5 J than 6 J, with arithmetic means ranging between 46 and 60 and 23–36 μm, respectively. In contrast, the mineralogical composition of the two sediments was similar. Calcite predominated strongly, comprising more than 77 % of total minerals, while dolomite and quartz were rare. Organic carbon (OC) and total nitrogen (TN) concentrations were highest in surficial sediments, with levels of 14.4 and 1.8 %, and 19.3 and 2.4 % observed in 5 J and 6 J, respectively. C/N ratios (atomic) were lowest in the same surface sediments, with the two lakes characterized by similar values (9.6 vs. 9.4, respectively), suggesting a predominance of autochthonous organic matter (OM) in both lakes. Contemporary δ¹³C values were lower in 5 J (?21.0 ‰) than 6 J (?18.5 ‰) sediments. Considerable changes in these four parameters were observed in recently deposited material, reflecting a shift in the trophic status of both lakes that was likely induced by the introduction of fish. In addition, the smaller and shallower 6 J seemed to respond to changes faster than the larger and deeper 5 J, indicating the higher sensitivity of the former. δ¹⁵N values in surface sediments of 5 J and 6 J were ?2.9 and ?4.4 ‰, respectively, with levels increasing gradually with depth to approximately +1.0 ‰ in deeper sediments. The observed changes could most likely be attributed to the atmospheric deposition of reactive nitrogen. The mountain hut has seemingly not had a significant enough impact on the lakes to be recorded in their sediments.     

Assessment of Water Quality in the Elbe River at Flood Water Conditions Based on Cluster Analysis,Principle Components Analysis,and Source Apportionment

An assessment of water quality measurements during a spring flood in the Elbe River is presented. Daily samples were taken at a site in the middle Elbe, which is part of the network of the International Commission for the Protection of the Elbe River (IKSE/MKOL). Cluster analysis (CA), principal components analysis (PCA), and source apportionment (APCS apportioning) were used to assess the flood‐dependent matter transport. As a result, three main components could be extracted as important to the matter transport in the Elbe River basin during flood events: (i) re‐suspended contaminated sediments, which led to temporarily increased concentrations of suspended matter and of most of the investigated heavy metals; (ii) water discharge related concentrations of pedogenic dissolved organic matter (DOM) as well as preliminary diluted concentrations of uranium and chloride, parameters with stable pollution background in the river basin; and (iii) abandoned mines, i.e., their dewatering systems, with particular influence on nickel, manganese, and zinc concentrations.