Advances in lithium analysis in solids by means of laser-induced breakdown spectroscopy: an exploratory study

Lithium is an important geochemical tracer for fluids or solids. However, because the electron microprobe cannot detect Li, variations of Li abundance at the micrometric scale are most often estimated from bulk analyses. In this study, the Li intense emission line at 670.706 nm in optical emission spectroscopy was used to perfect the analysis of Li at the micrometric scale by means of laser-induced breakdown spectroscopy (LIBS). To estimate lithium content for different geological materials, LIBS calibration of the emission line at 670.706 nm was achieved by use of synthetic glasses and natural minerals. The detection limit for this method is ∼5 ppm Li. Three applications to geological materials show the potential of LIBS for lithium determination, namely for Li-bearing minerals, melt inclusions, quartz, and associated fluid inclusions.For spodumene and petalite from granite pegmatite dikes (Portugal), the Li₂O concentrations are 7.6 ± 1.6 wt% and 6.3 ± 1.3 wt%, respectively, by use of LIBS. These values agree with ion microprobe analyses, bulk analyses, or both. For eucryptite crystals, the Li concentrations are scattered because grain size is smaller than the LIBS spatial resolution (6 to 8 μm). Lithium concentrations of melt inclusions from the Streltsovka U deposit (Siberia) are in the range of 2 to 6.2 wt% (Li₂O) for Li-rich daughter minerals. Lithium estimations on silicate glasses display values between 90 and 400 ppm.Lithium was also analyzed as a trace element in quartz. Transverse profiles were performed in hydrothermal barren quartz veins from the Spanish Central System (Sierra de Guadarrama). The highest Li concentrations (250 to 370 ppm) were found in specific growth bands in conjunction with the observed variation in optical cathodoluminescence intensity. Considering the fluid inclusion analysis, the source of fluid responsible to the Li enrichment in quartz is probably high-salinity fluids derived from sedimentary basins.     

Monitoring of heat transmission from buildings into geological environment and evaluation of soil deformation consequences in foundation engineering

In engineering geology a number of factors affecting foundation conditions are taken into consideration during engineering-geological investigations. This article deals with the factor of heat sourced from a structure (brick kiln) as a restrictive factor in foundation engineering in clay soils and introduces a documentation of soil deformation observations as an impact of the heat transmission into the geological environment. It was carried out in Southern Moravia in the Czech Republic, where the dominant foundation soils are Neogeneous clays where differential settlements of a tunnel kiln structure occurred as a result of ignoring the boundary conditions of temperature changes in the soil environment. The brick kilns caused heterogeneous spatial changes in the subsoil temperatures. This consequently resulted in differential settlements due to temperature changes originating from the kilns. The differential settlements reached as much as 150 mm. The major objective of the article is to highlight the importance of the heat transmission from buildings into the geological environment as a factor which should be considered in engineering geology and its application in planning. A new procedure for reducing or elimination of ground movements sourced from underlying clayey soils depending on the heat changes was also suggested in this context.     

The Northwest Africa (NWA) 5790 meteorite: A mesostasis‐rich nakhlite with little or no Martian aqueous alteration

Northwest Africa (NWA) 5790 is the most recently discovered member of the nakhlite group. Its mineralogy differs from the other nakhlites with a high abundance mesostasis (38.1 ± 3.6 vol%) and scarcity of olivine (4.0 ± 2.2 vol%). Furthermore, zoning of augite phenocrysts, and other petrographic and chemical characteristics suggest that NWA 5790 samples the chilled margin of its parent lava flow/sill. NWA 5790 contains calcite and rare clay minerals that are evidence for its exposure to liquid water. The calcite forms a cement to coatings of dust on the outer surface of the find and extends into the interior of the meteorite within veins. The presence of microbial remains within the coating confirms that the dust and its carbonate cement are terrestrial in origin, consistent with the carbon and oxygen isotope composition of the calcite. The clay minerals are finely crystalline and comprise ~0.003 vol% of the meteorite. δD values of the clay minerals range from ?212 ± 109‰ to ?96 ± 132‰, and cannot be used to distinguish between a terrestrial or Martian origin. As petrographic results are also not definitive, we conclude that secondary minerals produced by Martian groundwaters are at best very rare within NWA 5790. The meteorite has therefore sampled a region of the lava flow/sill with little or no exposure to the aqueous solutions that altered other nakhlites. This isolation could relate to the scarcity of olivine in NWA 5790 because dissolution of olivine in other nakhlites by Martian groundwaters enhanced their porosity and permeability, and provided solutes for secondary minerals.     

Low-pressure differentiation of tholeiitic lavas as recorded in segregation veins from Reykjanes (Iceland), Lanzarote (Canary Islands) and Masaya (Nicaragua)

Segregation veins are common in lava sheets and result from internal differentiation during lava emplacement and degassing. They consist of evolved liquid, most likely replaced by gas-filter pressing from a ∼50% crystallised host lava. Pairs of samples, host lavas and associated segregation veins from the Reykjanes Peninsula (Iceland), Lanzarote (Canary Islands) and the Masaya volcano (Nicaragua) show extreme mineralogical and compositional variations (MgO in host lava, segregation veins and interstitial glass ranges from 8–10 wt%, 3–6 wt%, and to less than 0.01 wt%, respectively). These samples allow the assessment of the internal lava flow differentiation mechanism, since both the parental and derived liquid are known in addition to the last magma drops in the form of late interstitial glasses. The mineralogical variation, mass-balance calculated from major- and trace element composition, and transitional metal partition between crystals and melts are all consistent with fractional crystallisation as the dominant differentiation mechanism. The interstitial glasses are highly silicic (SiO₂ = 70–80 wt%) and represent a final product of high-degree (75–97%) fractional crystallisation of olivine tholeiite at a pressure close to one atmosphere. The tholeiitic liquid-line-of-decent and the composition of the residual melts are governed by the K₂O/Na₂O of the initial basaltic magma. The granitic minimum is reached if the initial liquid has a high K₂O/Na₂O whereas trondhjemitic composition is the final product of magma with low initial K₂O/Na₂O. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Orbital Elements of 2004 Perseid Meteoroids Perturbed by Jupiter

Jupiter and Saturn produce important gravitational impulses on meteoroids released by comet 109P/Swift-Tuttle. The meteoroids from this comet once released follow retrograde orbits that during their periodic approaches to these planets (within 1.6 and 0.9 A.U., respectively) are impulsed gaining orbital energy. This perturbation effect is translated into a net inward shift in the node of the perturbed meteoroids. Such geometry with Jupiter occurred in 2004 over a meteoroid trail ejected by this comet during the 1862 A.D. return of the comet to perihelion. In order to study the predicted outburst produced by one-revolution meteoroids, the Spanish Photographic Meteor Network (SPMN) performed an extensive campaign. As a part of this observational effort here are presented 10 accurate meteoroid orbits. We discuss their origin by comparing them with the theoretical orbital elements of the dust trails intercepting the Earth during the 2004 Perseid return.     

ARGO upper salinity measurements: perspectives for L-band radiometers calibration and retrieved sea surface salinity validation

With the view of preparing the strategy for the calibration/validation of future L-band satellite radiometers, we examine the salinity variability recorded by Array for Real-Time Geostrophic Oceanography (ARGO) floats in the upper 10-m layer of the surface ocean. Using one year of ARGO measurements,we show that the surface salinity variability at ten days and 200-km scales is above /spl plusmn/0.1 psu for 30% of the drifters and that this variability is larger than 0.2 psu in tropical regions affected by strong river discharges and by precipitations, and in frontal areas characterized by strong mesoscale activity. Vertical gradient observed between 5-10-m depth is much lower than the horizontal variability but leads to systematic biases in the tropics. The South Pacific Ocean appears to be the less variable both vertically and horizontally.     

Statistical modeling of extreme value behavior in North American tree-ring density series

Many analyses of the paleoclimate record include conclusions about extremes, with a focus on the unprecedented nature of recent climate events. While the use of extreme value theory is becoming common in the analysis of the instrumental climate record, applications of this framework to the spatio-temporal analysis of paleoclimate records remain limited. This article develops a Bayesian hierarchical model to investigate spatially varying trends and dependencies in the parameters characterizing the distribution of extremes of a proxy data set, and applies it to the site-wise decadal maxima and minima of a gridded network of temperature sensitive tree ring density time series over northern North America. The statistical analysis reveals significant spatial associations in the temporal trends of the location parameters of the generalized extreme value distributions: maxima are increasing as a function of time, with stronger increases in the north and east of North America; minima are significantly increasing in the west, possibly decreasing in the east, and exhibit no changes in the center of the region. Results indicate that the distribution varies as a function of both space and time, with tree ring density maxima becoming more extreme as a function of time and minima having diverging temporal trends, by spatial location. Results of this proxy-only analysis are a first step towards directly reconstructing extremal climate behavior, as opposed to mean climate behavior, by linking extremes in the proxy record to extremes in the instrumental record.     

Development of Specimen Curing Procedures that Account for the Influence of Effective Stress During Curing on the Strength of Cemented Mine Backfill

Paste backfill used to provide ground support in underground mining is generated from full-stream tailings and is almost always placed underground with cement. For the backfill, both the rate of strength development and the final strength are important considerations for design, particularly when the backfill is subsequently exposed in the stope-mining sequence. There is strong evidence that strengths measured on specimens obtained from coring the in situ cemented backfill are much greater than laboratory-cured specimens with the same cement content. The paper reviews some of the experimental evidence showing that one of the major reasons for the different strength is the difference in effective stress acting on the backfill during curing. Laboratory specimens are (almost) always cured under zero total stress, so no effective stress develops. In contrast, backfill in a stope may cure under high effective stress, which develops due to either “conventional” consolidation in free-draining backfills, or to the so-called “self-desiccation” mechanism in fine-grained fills. Evidence is presented showing how the final strength is affected by applying stress to specimens at different stages of curing and at different rates. It is shown that a fully-coupled analysis of the filling behaviour is required to determine the appropriate effective stress regime to apply in curing laboratory specimens, where “fully-coupled” in this context means taking account of the interaction of consolidation/drainage rate, filling rate and cement hydration rate. Curing protocols for laboratory specimens are proposed, which would ensure that the strengths obtained are representative of in situ conditions.     

利用大地电磁资料对玄武岩成像的可行性

The magnetotelluric （MT） method has been among the favorite supporting tools for seismic imaging of sub-salt and sub-basalt targets. In this paper we present an example from Kachchh, India （where basaltic rocks overlie Mesozoic sedimentary rocks）, and discuss the feasibility of using MT method as an exploration tool in this geological setting. Our results highlight the difference in magnetotelluric response caused by the thin intrabasalt layering. The key issue addressed in this paper is what MT can and cannot provide in such geological settings. First, we compute apparent resistivity and phase response curves using representative resistivity-depth models and borehole data from the study area. Later, we compare these results to assess the plausibility of using MT to image the sub-volcanic sediments at Kachchh. Finally, we substantiate our discussion through one-dimensional inversion of the field observed MT data from this region that exhibits poor sensitivity of MT for thin basalt layers.