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991.
Injection-extraction treatment well pairs: an alternative to permeable reactive barriers 总被引:2,自引:0,他引:2
Two of the biggest drawbacks of using permeable reactive barriers (PRBs) to treat contaminated ground water are the high capital cost of installation, particularly when the contaminated ground water is deep below ground surface, and the uncertainty of whether or not PRBs remain effective for the long time scales (e.g., decades) needed for many contaminant plumes. The use of an injection-extraction treatment well pair (IETWP) for capture and treatment of contaminated ground water can circumvent these difficulties, while still providing many of the same advantages offered by PRBs. In this paper, the hydraulics of IETWPs and PRBs are compared, focusing primarily on the width of the captured plume. It is demonstrated that IETWPs act as hydraulic barriers in a manner similar to PRBs, and that IETWPs provide excellent plume capture. A mathematical expression is presented for the plume capture width of an IETWP oriented perpendicular to the ground water flow direction in a homogeneous aquifer. Also discussed are other practical considerations that might determine whether an IETWP is better suited than a PRB for a particular contaminated site; these considerations include operating and maintenance costs, and the conditions under which an IETWP system can be used for in situ remediation. 相似文献
992.
In-situ Measurements of Tropospheric Hydroxyl Radicals by Folded Long-Path Laser Absorption During the Field Campaign POPCORN 总被引:1,自引:0,他引:1
Uwe Brandenburger Theo Brauers Hans-Peter Dorn Martin Hausmann Dieter H. Ehhalt 《Journal of Atmospheric Chemistry》1998,31(1-2):181-204
Absolutely calibrated in-situ measurements of tropospheric hydroxyl radicals, formaldehyde, sulfur dioxide, and naphthalene (C10H8) were performed by long-path laser absorption spectroscopy during the field campaign POPCORN. The absorption light path was folded into an open optical multiple reflection cell with a mirror separation of 38.5 m. Using a light path length of 1848 m and an integration time of 200 s, the average 1-detection limits of OH, HCHO, SO2 and C10H8 during POPCORN were 8.7 · 105 cm–3, 8.3 · 109 cm–3, 2.4 · 109 cm–3, 1.5 · 108 cm–3, respectively. In total, 392 identifications of OH in air spectra were made in a rural environment between August 5 and August 23, 1994. We present and discuss OH absorption spectra and diurnal OH concentration profiles of three days which are representative for measurements under different pollution conditions during POPCORN. The observed maximum and median OH radical concentrations are 1.3 · 107 OH/cm3 and 4.0 · 106 OH/cm3, respectively. The measured diurnal variation of the OH concentration shows a good correlation with the primary formation reaction of OH radicals which is the photolysis of ambient ozone. Deviations from this correlation in the morning and evening hours, when the OH concentration is higher than expected from the ozone photolysis, demonstrate the importance of other photochemical HOx production pathways during POPCORN. 相似文献
993.
Asgeir Sorteberg Øystein Hov Sverre Solberg Kjetil Tørseth Hans Areskoug Martin Ferm Kit Granby Heikki Lättilä Karin Persson David Simpson 《Journal of Atmospheric Chemistry》1998,30(2):241-271
Observations of the concentration of several nitrogen containing compounds at five rural Scandinavian sites during March–June 1993 are reported. Total nitrate (NO
3
-
+ HNO3) and total ammonium (NH
4
+
+ NH3) were measured by denuder and filter pack. In general the methods agree well. At all sites the particulate fraction dominated, with the largest fraction of NO
3
-
and the lowest of NH
4
+
at the sites which were closest to the emission sources. The fraction of NO
3
-
of total nitrate increased with increasing NO2 concentrations, indicating that the nighttime conversion of NO2 to NO
3
-
is an important route of formation for NO
3
-
. A positive correlation was found between HNO3 and O3 in June at all sites, while no correlation was found early in the spring. Model calculations were made with a lagrangian boundary layer photooxidant model for the whole period, and compared to the measured concentrations. The calculated ratio between mean observed and modelled daily maximum concentrations of ozone over the measurement period were within +/–10% at all sites. The models ability to describe the daily ozone maximum concentration was satisfactory with an average deviation of 19–22% from the observed concentrations. HNO3 was underestimated by over 50% at all sites except the one closest to the emission sources. The correlation between modelled and observed concentrations was generally best for the sites with shortest transport distance from the sources of emission. 相似文献
994.
Edward S. Grew Nikolai N. Pertsev Stanislav Vrána Martin G. Yates Charles K. Shearer Michael Wiedenbeck 《Contributions to Mineralogy and Petrology》1998,131(1):22-38
Kornerupine, (□,Fe,Mg)(Mg,Fe,Al)9(Si,Al,B)5 (O,OH,F)22, has been reported with talc in rocks from six localities worldwide, but only at Chilapila Hill in the Lufilian Arc, Zambia
do textural relationships imply that kornerupine (Krn) equilibrated with talc (Tlc) during a prograde metamorphic event at
T≈ 640 °C, P≈ 13 kbar; a prograde Krn + Tlc assemblage has also been reported from Mautia Hill, Tanzania (P ≤ 13 kbar). In order to estimate possible constraints on the stability range for the kornerupine + talc paragenesis in nature,
we constructed a P-T diagram in the model system MgO-Al2O3-SiO2-H2O (MASH) for seven phases quartz (Qtz), B-free kornerupine sensu stricto, anthophyllite (Ath), chlorite (Chl), cordierite
(Crd), kyanite (Ky), and talc. The minimum pressure for Krn + Tlc + Ky stability in MASH is close to that for Ky + Tlc stability,
i.e., 6–8 kbar, at T≤ 780 °C. However, in the natural system, B2O3 and Na2O are major constituents in Krn and orthoamphibole (Oam), respectively, and dravitic tourmaline (Tur) is widespread. The critical
assemblage alternative to Krn + Tlc in nature is Tur + Oam. The upper pressure limit of Tur + Ath is determined by the upper
pressure for anthophyllite: 7.7–10.5 kbar at 682–794 °C in the MgO-SiO2-H2O system (Chernosky et al. 1985, Am Mineral 70:223–236), and is undoubtedly higher in the presence of Na2O, CaO, and Al2O3. At three of the six localities, talc is a retrograde phase; nonetheless, it possibly equilibrated with kornerupine on the
retrograde path or during a later metamorphic event at P-T conditions appropriate for Ky + Tlc. At the sixth locality (Mulvoj, southwestern Pamir Mountains, Tajikistan), Krn is found
in the same thin section as talc and kyanite and all three minerals formed during a prograde metamorphic event at T≥ 650 °C, P near 7 kbar. However, Krn is restricted to a lens 4 to 6 mm thick of phlogopite + anthophyllite + Tur and it does not touch
either talc or kyanite. A reaction relating the Mulvoj and Chilapila Hill (Krn + Tlc + Ky + Qtz + Tur) parageneses is calculated
from compositions in the Mulvoj rock to be 0.40Tur + 2.55Ath + 1.33H2O + 0.27F = Krn + 2.16Tlc + 0.36B2O3 + 0.02Rutile + 0.19Na2O + 0.17CaO. Given the difference in metamorphic pressures estimated for Mulvoj and Chilapila Hill, Krn + Tlc is inferred
to be favored by increasing pressure as well as by low Na2O and CaO contents. Some FeO, F, Fe2O3, and BeO are present in measurable amounts in at least one of the phases in the Mulvoj and Chilapila Hill whiteschists (e.g.,
Krn contains 0.24–0.67 wt% BeO), but the effect of these constituents is subordinate to that of Na2O, CaO and B2O3. The Krn + Tlc could be a more important assemblage in B-bearing whiteschists than has been reported to date, particularly
at pressures where orthoamphibole is no longer stable.
Received: 21 April 1997 / Accepted: 13 October 1997 相似文献
995.
Open system alkaline magmatism in northern Kenya: evidence from U-series disequilibria and radiogenic isotopes 总被引:4,自引:0,他引:4
Stuart Black Ray Macdonald Barbara A. Barreiro Peter N. Dunkley Martin Smith 《Contributions to Mineralogy and Petrology》1998,131(4):364-378
U-series activity ratios, Sr-Nd-Pb isotopic ratios and major and trace element compositions have been determined on young
basalts (<10 ka) and trachytes from the volcano Emuruangogolak in the Kenya Rift Valley. The basalts are mildly alkaline and
are associated with small volumes of hawaiite. The mafic rocks are characterised by high (230Th/232Th) (≥1.06) with low (238U/230Th) ratios (≤0.72). They have variable incompatible trace element ratios (e.g. Zr/Nb, Ba/Zr), indicating that they represent
a number of magmatic lineages. The trachytes, which comprise both comenditic and pantelleritic varieties, have significantly
lower (230Th/232Th) ratios than the basalts, with clear differences between pantelleritic and comenditic types. The (238U/230Th) ratios in the pantellerites range from less, to greater, than 1. The variations in composition and isotopic diversity
must represent different sources for the trachytes. Internal isochrons for the trachytes give U-Th ages of 14 to 40 ka, similar
to single crystal laser fusion 40Ar/39Ar ages from sanidine phenocrysts (16–38 ka) for the same rocks. Post-crystallisation residence times of the trachytes were
very short, implying relatively rapid movement of trachyte from magma chamber to the surface. Variations in the initial (230Th/232Th)0 ratios (0.69–1.14) of both basalts and trachytes indicate that Emuruangogolak has erupted a large range of isotopically diverse
magmas over a very short period of time (38 ka), from conduits closely spaced around the summit of the volcano.
Received: 29 May 1996 / Accepted: 24 November 1997 相似文献
996.
Heather Clegg Brian Horsfield Heinz Wilkes Jaap Sinninghe Damst Martin P. Koopmans 《Organic Geochemistry》1998,29(8):1953-1960
Hydrous pyrolysis experiments were performed on the Ghareb Formation (Upper Cretaceous, Jordan), a carbonate- and organic-rich (TOC 19.6%) source rock, using a temperature range of 200 to 360°C (72 h). The original sediment contains only low amounts of carbazoles, (maximum 2.2 μg/g bitumen for 1-methylcarbazole). With increasing thermal maturation, intense generation begins at temperatures only in excess of 300°C, reaching a maximum at 360°C. Likewise, during natural maturation, generation occurs at later stages of maturity (e.g. for Tithonian source rocks at >0.81% Rr and for Posidonia Shale at >0.88% Rr). Some isomeric changes during hydrous pyrolysis do not resemble those in nature whereas others do. The relative abundances of selected C1- and C2-alkylcarbazoles on ternary diagrams reveal differences, whereas the benzo[a]carbazole/benzo[a]carbazole+benzo[c]carbazole ratio is closely similar. The latter result supports the contention that maturation plays a key role in controlling carbazole distributions in source rocks. However, the results for alkylcarbazoles, especially the C2-carbazoles, are not easy to interpret. 相似文献
997.
Anke Putschew Christine Schaeffer-Reiss Philippe Schaeffer Martin P Koopmans Jan W de Leeuw Michael D Lewan Jaap S Sinninghe Damsté James R Maxwell 《Organic Geochemistry》1998,29(8):1875-1890
An immature sulfur-rich marl from the Gessosso-solfifera Formation of the Vena del Gesso Basin (Messinian, Italy) has been subjected to hydrous pyrolysis (160 to 330°C) to simulate maturation under natural conditions. The kerogen of the unheated and heated samples was isolated and the hydrocarbons released by selective chemical degradation (Li/EtNH2 and HI/LiAlH4) were analysed to allow a study of the fate of sulfur- and oxygen-bound species with increasing temperature. The residues from the chemical treatments were also subjected to pyrolysis–GC to follow structural changes in the kerogens. In general, with increasing hydrous pyrolysis temperature, the amounts of sulfide- and ether-bound components in the kerogen decreased significantly. At the temperature at which the generation of expelled oil began (260°C), almost all of the bound components initially present in the unheated sample were released from the kerogen. Comparison with an earlier study of the extractable organic matter using a similar approach and the same samples provides molecular evidence that, with increasing maturation, solvent-soluble macromolecular material was initially released from the kerogen, notably as a result of thermal cleavage of weak carbon–heteroatom bonds (sulfide, ester, ether) even at temperatures as low as 220°C. This solvent-soluble macromolecular material then underwent thermal cleavage to generate hydrocarbons at higher temperatures. This early generation of bitumen may explain the presence of unusually high amounts of extractable organic matter of macromolecular nature in very immature S-rich sediments. 相似文献
998.
The main driving force behind Al/Si ordering in tetrahedral framework aluminosilicates is nearest-neighbour Al/Al avoidance.
Computer simulation is used to explore the direct consequences of such Al/Al avoidance. The main result is that the order-disorder
transition temperature T
c
falls dramatically as the concentration x of Al in the structure is reduced, and if the only interactions are those associated with nearest-neighbour Al/Al avoidance,
T
c
becomes zero for x less than some critical value x
c
, where x
c
=0.31 for the feldspar framework and x
c
=0.34 for cordierite. Also a large degree of short range order is found above T
c
. Both results differ radically from the standard Bragg-Williams model. Plots of entropy and enthalpy of ordering are given
as functions of x and T, which may be used to interpret experimental data or for extrapolation into ranges of x and T inaccessible to experiment.
Received: 14 May 1997 / Revised, accepted: 2 June 1997 相似文献
999.
Martin Beech 《Monthly notices of the Royal Astronomical Society》1998,294(2):259-264
This study is motivated by the possibility of determining the large-body meteoroid flux at the orbit of Venus. Towards this end, we attempt to estimate the times at which enhanced meteoric activity might be observed in the planet's atmosphere. While a number of meteoroid streams are identified as satisfying common Earth and Venus intercept conditions, it is not clear from the Earth-observed data if these streams contain large-body meteoroids. A subset of the Taurid Complex objects may produce fireball-rich meteor showers on Venus. A total of 11 short-period, periodic comets and 46 near-Earth asteroids approach the orbit of Venus to within 0.1 au, and these objects may have associated meteoroid streams. Comets 27P/Crommelin and 7P/Pons–Winnecke are identified as candidate parents to possible periodic meteor showers at the orbit of Venus. 相似文献
1000.
D'Amico Stappers Bailes Martin Bell Lyne & Manchester 《Monthly notices of the Royal Astronomical Society》1998,297(1):28-40
The Parkes survey of the entire southern sky for millisecond and other low-luminosity pulsars has now been completed. The survey system and initial results were described by Manchester et al. and the final results and population studies are described by Lyne et al. A total of 298 pulsars were detected, including 101 new discoveries of which 17 were millisecond pulsars. Here we report on timing observations at Parkes and Jodrell Bank of the 84 long-period (non-millisecond) pulsars discovered in the survey, including timing solutions for 78 of them. Pulse profiles and arrival times were obtained at several different frequencies over intervals of more than a year, yielding a position, period, period derivative and dispersion measure for each pulsar. Pulse profiles at frequencies near 400 MHz and 600 or 1400 MHz are presented for most of the observed pulsars. Significant timing noise was detected for five pulsars and a glitch was observed in the period of PSR J1123–6259. 相似文献