Analysis of the time profile of type III bursts at meter wavelengths

The time profile of two sets of isolated type III bursts, observed in the meter wavelength range at the Trieste Astronomical Observatory, was analyzed using a Fourier transform technique in order to accurately determine the decay constant of the exponential phase and to derive the exciter time profile. The decay constant () was found to be correlated with the exciter duration (D _e ), suggesting that the damping of plasma waves is not of collisional origin and confirming results obtained by previous authors at lower frequencies. In particular, two distributions can be identified in the ( – D _e ) plane and fitted by two nearly parallel lines, which could be the signature of different decay processes. Moreover, the damping constant observed at higher frequencies (327 and 408 MHz) has the same dependence on exciter duration as that at the lower frequency (237 MHz), also in disagreement with the collisional hypothesis.     

Co-use of existing scenario sets to extend and quantify the shared socioeconomic pathways

More often than not, assessments of future climate risks are based on future climatic conditions superimposed on current socioeconomic conditions only. The new IPCC-guided alternative global development trends, the shared socioeconomic pathways (SSPs), have the potential to enhance the integration of future socioeconomic conditions—in the form of socioeconomic scenarios—within assessments of future climate risks. Being global development pathways, the SSPs lack regional and sectoral details. To increase their suitability in sectoral and/or regional studies and their relevance for local stakeholders, the SSPs have to be extended. We propose here a new method to extend the SSPs that makes use of existing scenario studies, the (re)use of which has been underestimated so far. Our approach lies in a systematic matching of multiple scenario sets that facilitates enrichment of the global SSPs with regional and sectoral information, in terms of both storylines and quantitative projections. We apply this method to develop extended SSPs of human vulnerability in Europe and to quantify them for a number of key indicators at the sub-national level up to 2050, based on the co-use of the matched scenarios’ quantitative outputs. Results show that such a method leads to internally consistent extended SSPs with detailed and highly quantified narratives that are tightly linked to global contexts. This method also provides multiple entry points where the relevance of scenarios to local stakeholders can be tested and strengthened. The extended SSPs can be readily employed to explore future populations’ vulnerability to climate hazards under varying levels of socioeconomic development.     

Epistemic and ethical trade-offs in decision analytical modelling

Designing decision analytical models requires making choices that can involve a range of trade-offs and interactions between epistemic and ethical considerations. Such choices include determining the complexity of a model and deciding what types of risk will be assessed. Here, we demonstrate how model design choices can involve trade-offs between the epistemic benefits of representational completeness and simplicity, which interact with ethical considerations about fairness and human life. We illustrate this point by focusing on modeling studies that assess flood risks in New Orleans, Louisiana. Addressing the ethical and epistemic implications of model design choices can help clarify the scope of factors necessary to inform ethically sound and economically efficient decision-making.     

Characteristics of sub-daily precipitation extremes in observed data and regional climate model simulations

Theoretical and Applied Climatology - The study compares characteristics of observed sub-daily precipitation extremes in the Czech Republic with those simulated by Hadley Centre Regional Model...     

Climate change implications for irrigation and groundwater in the Republican River Basin,USA

This study investigates the influence of climate change on groundwater availability, and thereby, irrigation across political boundaries within the US High Plains aquifer. A regression model is developed to predict changes in irrigation according to predicted changes in precipitation and temperature from a downscaled dataset of 32 general circulation models (GCMs). Precipitation recharge changes are calculated with precipitation-recharge curves developed for prognostic representations of precipitation across the Nebraska-Colorado-Kansas area and within the Republican River Basin focal landscape. Irrigation-recharge changes are scaled with changes in irrigation. The groundwater responses to climate forcings are then simulated under new pumping and recharge rates using a MODFLOW groundwater flow model. Results show that groundwater pumping and recharge both will increase and that the effects of groundwater pumping will overshadow those from natural fluctuations. Groundwater levels will decline more in areas with irrigation-driven decreasing trends in the baseline. The methodologies and predictions of this study can inform long-term water planning and the design of management strategies that help avoid and resolve water-related conflicts, enabling irrigation sustainability.     

Speleothem stable isotope records interpreted within a multi-proxy framework and implications for New Zealand palaeoclimate reconstruction

A primary step in the interpretation of speleothem stable isotope records (¹⁸O/¹⁶O and ¹³C/¹²C) is to conduct a comparison with other local palaeoclimate proxies. Here, two new master speleothem δ¹⁸O and δ¹³C records (one from eastern North Island, and the other from western/southern South Island, New Zealand) are evaluated against independent precipitation and temperature proxy information to assess their palaeoclimate reconstruction potential. This comparison also resulted in a serendipitous opportunity to reconstruct past circulation using climate regime classification [Lorrey, A.M., Fowler, A.M., Salinger, J., 2007a. Regional climate regime classification as a qualitative tool for interpreting multi-proxy palaeoclimate data spatial patterns: a New Zealand case study. Palaeo-3, in press], specifically because these two regional climate districts are hyper-sensitive to westerly circulation changes, and in many cases, exhibit contrasting climate character in response to circulation anomalies.For both the western South Island and the eastern North Island master speleothem δ¹³C records, variations tracked changes in relative regional precipitation. The δ¹⁸O master speleothem record for both regions varied with temperature change. Both records contain strong regional climate signals that suggest they have good value for palaeoclimate reconstruction. The ensuing attempt at a multi-proxy reconstruction of regional climate regimes from the compiled proxies indicates past circulation in the New Zealand sector has varied considerably during the past four millennia. Centennial-scale circulation changes for the past 4000 years are evident, and are analogous to modern Blocking, Zonal and Trough regime types [Kidson J. W., 2000. An analysis of New Zealand synoptic types and their use in defining weather regimes. International Journal of Climatology 20, 299–316] that characterise changes in present-day (prevailing) westerly circulation. This palaeoclimate reconstruction indicates modern regional climate regime classification can be extended at least as far back as the temporal coverage of the records presented here, and it can likely be improved on with better dating control and the addition of new records with higher resolution. It is also anticipated that future work will expand to include more proxy data from across New Zealand to improve the clarity of past climate regime occurrence for the Late Holocene.     

Interaction of Freshly Precipitated Silica Gel with Aqueous Silicic Acid Solutions under Ambient and Near Neutral pH-conditions: A Detailed Analysis of Linear Rate Law

Interaction of freshly precipitated silica gel with aqueous solutions was studied at laboratory batch experiments under ambient and near neutral pH-conditions. The overall process showed excellent reversibility: gel growth could be considered as an opposite process to dissolution and a linear rate law could be applied to experimental data. Depending on the used rate law form, the resulting rate constants were sensitive to errors in parameters/variables such as gel surface area, equilibrium constants, Si-fluxes, and reaction quotients. The application of an Integrated Exponential Model appeared to be the best approach for dissolution data evaluation. It yielded the rate constants k _dissol ∼ (4.50 ± 0.68) × 10⁻¹² and k _growth ∼ (2.58 ± 0.39) × 10⁻⁹ mol m⁻² s⁻¹ for zero ionic strength. In contrast, a Differential Model gave best results for growth data modeling. It yielded the rate constants k _dissol ∼ (1.14 ± 0.44) × 10⁻¹¹ and k _growth ∼ (6.08 ± 2.37) × 10⁻⁹ mol m⁻² s⁻¹ for higher ionic strength (I ∼ 0.04 to 0.11 mol L⁻¹). The found silica gel solubility at zero ionic strength was somewhat lower than the generally accepted value. Based on the and standard Gibbs free energy of silica gel formation was calculated as and −850,318 ± 20 J mol⁻¹, respectively. Activation energies for silica gel dissolution and growth were determined as and respectively. An universal value for growth of any silica polymorph, is not consistent with the value for silica gel growth, which questions the hypothesis about one unique activated complex controlling the silica polymorph growth.     

Abiotic ammonium formation in the presence of Ni-Fe metals and alloys and its implications for the Hadean nitrogen cycle

Experiments with dinitrogen-, nitrite-, nitrate-containing solutions were conducted without headspace in Ti reactors (200°C), borosilicate septum bottles (70°C) and HDPE tubes (22°C) in the presence of Fe and Ni metal, awaruite (Ni₈₀Fe₂₀) and tetrataenite (Ni₅₀Fe₅₀). In general, metals used in this investigation were more reactive than alloys toward all investigated nitrogen species. Nitrite and nitrate were converted to ammonium more rapidly than dinitrogen, and the reduction process had a strong temperature dependence. We concluded from our experimental observations that Hadean submarine hydrothermal systems could have supplied significant quantities of ammonium for reactions that are generally associated with prebiotic synthesis, especially in localized environments. Several natural meteorites (octahedrites) were found to contain up to 22 ppm N_tot. While the oxidation state of N in the octahedrites was not determined, XPS analysis of metals and alloys used in the study shows that N is likely present as nitride (N^3-). This observation may have implications toward the Hadean environment, since, terrestrial (e.g., oceanic) ammonium production may have been supplemented by reduced nitrogen delivered by metal-rich meteorites. This notion is based on the fact that nitrogen dissolves into metallic melts.