Effect of hydrocarbon volatility and adsorption on source-rock pyrolysis

Petroleum source-rock evaluations by pyrolysis are based on the concept that free hydrocarbons in rock samples are volatilized below 300°C while hydrocarbons cracked from kerogen come off at higher temperatures. The pyrolysis of pure hydrocarbons with different mineral matrices shows that free hydrocarbons containing 16 or more carbon atoms may not be evolved eblow 300°C, but at varying higher temperatures. The extent to which this occurs depends on the hydrocarbon volatility, the mineral matrix and the pyrolysis instrument design. Source-rock parameters which use the P₁ (S₁) peak may be not be reproducible between instruments if the rock contains appreciable amounts of high molecular weight hydrocarbons.     

Assessing the effects of forest biomass reductions on forest health and streamflow

Forest biomass reductions in overgrown forests have the potential to provide hydrologic benefits in the form of improved forest health and increased streamflow production in water-limited systems. Biomass reductions may also alter evaporation. These changes are generated when water that previously would have been transpired or evaporated from the canopy of the removed vegetation is transferred to transpiration of the remaining vegetation, streamflow, and/or non-canopy evaporation. In this study, we combined a new vegetation-change water-balance approach with lumped hydrologic modelling outputs to examine the effects of forest biomass reductions on transpiration of the remaining vegetation and streamflow in California's Sierra Nevada. We found that on average, 102 mm and 263 mm (8.0% and 20.6% of mean annual precipitation [MAP]) of water were made available following 20% and 50% forest biomass-reduction scenarios, respectively. This water was then partitioned to both streamflow and transpiration of the remaining forest, but to varying degrees depending on post-biomass-reduction precipitation levels and forest biomass-reduction intensity. During dry periods, most of the water (approximately 200 mm [15.7% on MAP] for the 50% biomass-reduction scenario) was partitioned to transpiration of the remaining trees, while less than 50 mm (3.9% on MAP) was partitioned to streamflow. This increase in transpiration during dry periods would likely help trees maintain forest productivity and resistance to drought. During wet periods, the hydrologic benefits of forest biomass reductions shifted to streamflow (200 mm [15.7% on MAP]) and away from transpiration (less than 150 mm [11.8% on MAP]) as the remaining trees became less water stressed. We also found that streamflow benefits per unit of forest biomass reduction increased with biomass-reduction intensity, whereas transpiration benefits decreased. By accounting for changes in vegetation, the vegetation-change water balance developed in this study provided an improved assessment of watershed-scale forest health benefits associated with forest biomass reductions.     

Lutz Creek watershed,Barro Colorado Island,Republic of Panama

Lutz creek is a small (9.69 ha) catchment located on Barro Colorado Island (BCI), a 1500-ha island in Lake Gatún, the principal freshwater reservoir (425 ha, 26 m above sea level) of the Panama Canal watershed in central Panama. In 1972, a concrete V-notch weir was installed on the creek, located at 9°09′42.8358″N, 79°50′15.6699″W, and hydrological record keeping began. The island was first established as a research station in 1923 and precipitation data collection was initiated in 1925. A meteorological tower, installed in 1972 and located a few meters from the weir, is currently instrumented to collect air temperature, relative humidity, wind speed and direction, evapotranspiration and solar radiation. In addition, since 1972, gravimetric soil moisture has been measured at least biweekly at 10 sites located throughout the Lutz Catchment above the location of the weir. Data collection and the administration of BCI are the responsibility of the Smithsonian Tropical Research Institute (STRI; https://stri.si.edu ) which funds the data collection and storage. Data are in the public domain, entitled ‘Lutz Watershed And Meteorological Tower’ and are available at the STRI Physical monitoring website https://biogeodb.stri.si.edu/physical_monitoring/ .     

Vegetation water sources in California's Sierra Nevada (USA) are young and change over time,a multi-isotope (δ18O, δ2H, 3H) tracer approach.

Sierra Nevada forests transpire a significant amount of California's water resources, sparking interest in applying forest management to improve California's water supply. Determining the source water of evapotranspiration enables forest managers to make informed decisions. To this end, a significant interest in critical zone science is to develop new methods to work across time scales to predict subsurface water storage and use. In this study, forest vegetation accessed young water and switched sources depending on availability, suggesting that forest drought vulnerability may depend on the range of water sources available (rain, snowmelt and deeply stored water). This finding also suggests that changes in transpiration rates may have immediate effects on water sources in close proximity to vegetation, and delayed effects on storage and runoff. New δ¹⁸O, δ²H and ³H data were used to track precipitation, runoff, evapotranspiration and storage through the critical zone seasonally, including seasons where evapotranspiration and snowmelt were in phase (winter snowmelt) and out of phase (seasonally dry summer). The main source of this headwater catchment's runoff is derived from its meadow saturated zone water, which was dominated by snowmelt. Water that originated as snowmelt contributed to transpiration, unless other sources, such as recent rain, became available. In cases where xylem δ¹⁸O and δ²H signatures matched those of deeper saturated zone water, ³H data showed that xylem water was distinctly younger than the deep saturated zone water. During 2016, which experienced relatively normal snowpack in winter and seasonally dry summer conditions, mean summer saturated zone water and vegetation water were similar in δ¹⁸O, −12.4 ± 0.04 ‰ and − 12.5 ± 0.3 ‰, respectively, but were distinctly different in ³H, 5.5 ± 0.2 pCi/L and 13.7 ± 1.1 pCi/L, respectively. While δ¹⁸O shows that vegetation and meadow saturated zone water have similar origins, ³H shows they have dissimilar ages.     

Insights into plant water uptake from xylem‐water isotope measurements in two tropical catchments with contrasting moisture conditions

Water transpired by trees has long been assumed to be sourced from the same subsurface water stocks that contribute to groundwater recharge and streamflow. However, recent investigations using dual water stable isotopes have shown an apparent ecohydrological separation between tree‐transpired water and stream water. Here we present evidence for such ecohydrological separation in two tropical environments in Puerto Rico where precipitation seasonality is relatively low and where precipitation is positively correlated with primary productivity. We determined the stable isotope signature of xylem water of 30 mahogany (Swietenia spp.) trees sampled during two periods with contrasting moisture status. Our results suggest that the separation between transpiration water and groundwater recharge/streamflow water might be related less to the temporal phasing of hydrologic inputs and primary productivity, and more to the fundamental processes that drive evaporative isotopic enrichment of residual soil water within the soil matrix. The lack of an evaporative signature of both groundwater and streams in the study area suggests that these water balance components have a water source that is transported quickly to deeper subsurface storage compared to waters that trees use. A Bayesian mixing model used to partition source water proportions of xylem water showed that groundwater contribution was greater for valley‐bottom, riparian trees than for ridge‐top trees. Groundwater contribution was also greater at the xeric site than at the mesic–hydric site. These model results (1) underline the utility of a simple linear mixing model, implemented in a Bayesian inference framework, in quantifying source water contributions at sites with contrasting physiographic characteristics, and (2) highlight the informed judgement that should be made in interpreting mixing model results, of import particularly in surveying groundwater use patterns by vegetation from regional to global scales. Copyright © 2016 John Wiley & Sons, Ltd.     

Oblique surface wave propagation over a small undulation on the bottom of an ocean

The problem of oblique water wave diffraction by small undulation of the bottom of a laterally unbounded ocean is considered using linear water wave theory. A perturbation analysis is employed to obtain the velocity potential, the reflection and the transmission coefficients up to the first order in terms of integrals involving the shape functions c(x) representing the bottom undulation. Finite cosine transform is used to find the first order potential, and this potential is utilised in obtaining the first order reflection and transmission coefficients. Some particular forms of the shape function representing an exponentially damped undulation, a single hump and a patch of sinusoidal ripples are considered and the integrals for the reflection and transmission coefficients are evaluated. For the exponentially damped undulation, it is observed that the reflection ceases much before transmission while for the single hump, reflection and transmission go hand in hand up to a certain value of the wavenumber, after which they vanish. For the patch of sinusoidal ripples having the same wavenumber, the reflection coefficient up to the first order is found to be an oscillatory function in the quotient of twice the component of the wavenumber along x-axis and the ripple wavenumber. When this quotient becomes one, the theory predicts a resonant interaction between the bed and free surface, and the reflection coefficient becomes a multiple of the number of ripples. High reflection of the incident wave energy occurs if this number is large. Also, when a patch of ripples having different wavenumbers is considered the same result follows. Known results for the normal incidence are recovered as special cases for the patch of sinusoidal ripples. The theoretical observations are shown computationally.     

Estimated energy balance in the jovian upper atmosphere during an auroral heating event

We present an analysis of a series of observations of the auroral/polar regions of Jupiter, carried out between September 8 and 11, 1998, making use of the high-resolution spectrometer, CSHELL, on the NASA InfraRed Telescope Facility (IRTF), Mauna Kea, Hawaii; these observations spanned an “auroral heating event.” This analysis combines the measured line intensities and ion velocities with a one-dimensional model vertical profile of the jovian thermosphere/ionosphere. We compute the model line intensities both assuming local thermodynamic equilibrium (LTE) and, relaxing this condition (non-LTE), through detailed balance calculations, in order to compare with the observations. Taking the model parameters derived, we calculate the changes in heating rate required to account for the modelled temperature profiles that are consistent with the measured line intensities. We compute the electron precipitation rates required to give the modelled ion densities that are consistent with the measured line intensities, and derive the corresponding Pedersen conductivities. We compute the changes in heating due to Joule heating and ion drag derived from the measured ion velocities, and modelled conductivities, making use of ion-neutral coupling coefficients derived from a 3-D global circulation model. Finally, we compute the cooling due to the downward conduction of heat and the radiation-to-space from the molecular ion and hydrocarbons. Comparison of the various heating and cooling terms enables us to investigate the balance of energy inputs into the auroral/polar atmosphere. Increases in Joule heating and ion drag are sufficient to explain the observed heating of the atmosphere; increased particle precipitation makes only a minor heating contribution. But local cooling effects—predominantly radiation-to-space—are shown to be too inefficient to allow the atmosphere to relax back to pre-event thermal conditions. Thus we conclude that this event provides observational, i.e. empirical, evidence that heat must be transported away from the auroral/polar regions by thermally or mechanically driven winds.     

Using hyperspectral plant signatures for CO<Subscript>2</Subscript> leak detection during the 2008 ZERT CO<Subscript>2</Subscript> sequestration field experiment in Bozeman,Montana

Hyperspectral plant signatures can be used as a short-term, as well as long-term (100-year timescale) monitoring technique to verify that CO₂ sequestration fields have not been compromised. An influx of CO₂ gas into the soil can stress vegetation, which causes changes in the visible to near-infrared reflectance spectral signature of the vegetation. For 29 days, beginning on July 9, 2008, pure carbon dioxide gas was released through a 100-m long horizontal injection well, at a flow rate of 300 kg day⁻¹. Spectral signatures were recorded almost daily from an unmown patch of plants over the injection with a “FieldSpec Pro” spectrometer by Analytical Spectral Devices, Inc. Measurements were taken both inside and outside of the CO₂ leak zone to normalize observations for other environmental factors affecting the plants. Four to five days after the injection began, stress was observed in the spectral signatures of plants within 1 m of the well. After approximately 10 days, moderate to high amounts of stress were measured out to 2.5 m from the well. This spatial distribution corresponded to areas of high CO₂ flux from the injection. Airborne hyperspectral imagery, acquired by Resonon, Inc. of Bozeman, MT using their hyperspectral camera, also showed the same pattern of plant stress. Spectral signatures of the plants were also compared to the CO₂ concentrations in the soil, which indicated that the lower limit of soil CO₂ needed to stress vegetation is between 4 and 8% by volume.     

Numerical simulations of spiral‐shaped inclusion trails: can 3D geometry distinguish between end‐member models of spiral formation?

Numerical 3D simulations of the development of spiral inclusion trails in porphyroblasts were conducted in order to test the proposals that (a) 3D spiral geometry differs between the rotation and nonrotation end‐member models of spiral formation proposed in the literature, and (b) 3D spiral geometry can be used as a criterion to distinguish between the two end‐member models in rocks. Four principal differences are identified between the two sets of simulations: smoothness of spiral curvature; spacing of foliation planes; alignment of individual foliation planes either side of the sphere representing the porphyroblast; and spiral asymmetry with respect to matrix shear sense. Of these differences, only spiral asymmetry and possibly the alignment of individual foliation planes are diagnostic criteria for distinguishing between the end‐member models. In the absence of a readily applied test to distinguish the end‐member models, interpretation of spiral inclusion trails is problematic. It is necessary to determine complementary evidence to distinguish porphyroblast rotation or nonrotation during spiral formation.