Significance of ancient sulfide PGE and Re–Os signatures in the mantle beneath Calatrava,Central Spain

Spinel lherzolite and wehrlite xenoliths from the Cenozoic Calatrava volcanic field carry the geochemical imprint of metasomatic agents that have affected the subcontinental lithospheric mantle beneath Central Iberia. Some xenoliths (mainly wehrlites) were enriched in REE, Sr, P, and CO₂ by silicic-carbonate-rich metasomatic melts/fluids, while others record the effects of subduction-related hydrous silicate fluids that have precipitated amphibole and induced high Ti/Eu in primary clinopyroxene. The petrographic observations and geochemical data suggest that interstitial glass in the xenoliths represent the quenched products of Si-rich melts that infiltrated the mantle peridotite shortly before the entrainment of the xenoliths in the host magmas that erupted ca 2 million years ago. During their infiltration, the metasomatic melts reacted with peridotite, resulting in silica enrichment, while remobilizing grains of iron-rich monosulfide solid solution (Fe-rich Mss) initially enclosed in, or intergranular to, primary olivine and pyroxenes. In situ laser ablation inductively coupled plasma-mass spectrometry analysis of single sulfide grains reveals that the Fe-rich Mss in glass shows platinum-group element (PGE) patterns and ¹⁸⁷Os/¹⁸⁸Os compositions identical to the Fe-rich Mss occurring as inclusions in, or at grain boundaries of primary silicates. Moreover, independent of its microstructural position, Fe-rich Mss exhibits PGE and ¹⁸⁷Os/¹⁸⁸Os signatures typical of Mss either residual after partial melting or crystallized directly from sulfide melts. Our findings reveal that young metasomatic melt(s)/fluid(s) may carry remobilized sulfides with PGE and Os-isotopic signatures identical to those of texturally older sulfides in the peridotite xenolith. These sulfides thus still provide useful information about the timing and nature of older magmatic events in the subcontinental mantle.     

Sandstone alterations triggered by fire-related temperatures

The aim of the study was to identify and describe changes in two different sandstone types when undergoing different environmental and extreme temperature regimes to assess the possibility of finding insolation weathering and how these sandstones would behave during and after a fire. The first step was the simulation in the laboratory of temperature regimes up to 60 °C which would correspond to extreme events that could be found in insolation cycles even in Central Europe and the second one was the temperature above 200 °C simulating in laboratory conditions the thermal regime of a potential fire situation at temperatures up to 200, 400, 600 and 800 °C. Heating the samples above 400 °C led to gradual changes in mineral composition, colour, surface roughness and physical properties reaching, eventually, total rock breakdown through spalling and granular disaggregation. The different behaviour of sandstones exposed to high temperatures is mainly caused by their different mineral composition with various ratios of minerals that are more or less chemically stable at high temperatures as well as by the differences in the porosity.     

Mercury colonial footprint in Darién Gulf sediments,Colombia

The mercury (Hg) deposition history in the Darién Gulf is reconstructed from three sediment cores spanning up to 1,000 years. Knowledge on the contribution to global Hg budget from the Caribbean is limited. Patterns of water circulation, sediment deposition rates, cataclysmic atmospheric inputs, and post-depositional migration have been considered in Hg trapping in the seabed. The sediment delivery rates to the coastal zone over the Late Holocene have increased from 0.2 to 1 cm year^?1 owing to anthropogenic influence. This alteration took the form of geological effects, like coastal morphology change, that played a major role in Hg downcore signal preservation. Natural background Hg levels in Southern Caribbean sediments (77.0 μg kg^?1) are up to three times higher than preindustrial signals at other latitudes, because of volcanic contributions from the Pacific ring of fire. Enrichment factors rose from 0.9 to 1.5 (70.1–113.5 μg kg^?1) within profiles related to Hg usage since Spanish colonial times between the calendar years 1550 and 1811.     

Experimental testing, numerical modelling and seismic strengthening of traditional stone masonry: comprehensive study of a real Azorian pier

Stone masonry is one of the oldest building techniques used worldwide and it is known to exhibit poor behaviour under seismic excitations. In this context, this work aims at assessing the in-plane behaviour of an existing double-leaf stone masonry pier by experimental testing. Additionally, a detailed 3D finite element numerical analysis based on micro-modelling of the original pier is presented (fully describing the geometry and division of each individual elements, namely infill, blocks and joints) aiming at simulating the experimental test results. This numerical strategy can be seen as an alternative way of analysing this type of constructions, particularly useful for laboratory studies, and suitable for the calibration of simplified numerical models. As part of a wider research activity, this work is further complemented with the presentation of an effective retrofit/strengthening technique (reinforced connected plaster) to achieve a significant improvement of its in-plane cyclic response which is experimentally verified in the results presented herein.     

Performance of masonry enclosure walls: lessons learned from recent earthquakes

This paper discusses the issue of performance requirements and construction criteria for masonry enclosure and infill walls.Vertical building enclosures in European countries are very often constituted by non-load-bearing masonry walls, using horizontally perforated clay bricks.These walls are generally supported and confined by a reinforced concrete frame structure of columns and beams/slabs.Since these walls are commonly considered to be nonstructural elements and their influence on the structural response is ignored,their consideration in the design of structures as well as their connection to the adjacent structural elements is frequently negligent or insufficiently detailed.As a consequence,nonstructural elements,as for wall enclosures,are relatively sensitive to drift and acceleration demands when buildings are subjected to seismic actions. Many international standards and technical documents stress the need for design acceptability criteria for nonstructural elements,however they do not specifically indicate how to prevent collapse and severe cracking,and how to enhance the overall stability in the case of moderate to high seismic loading.Furthermore,a review of appropriate measures to improve enclosure wall performance and both in-plane and out-of-plane integrity under seismic actions is addressed.     

Assessment of the effects of a marine urban outfall discharge on caged mussels using chemical and biomarker analysis

To assess the presence of endocrine disruptors in treated marine outfall discharges and their possible effects, mussels (Mytilus galloprovincialis) were caged in the environmental mixing zone of the outfall of the Santander sanitation system and in one control area. After 30, 60 and 90 days, samples were collected to perform chemical analyses (metals, anionic surfactants, alkylphenols, bisphenol A, phthalates and estrogenic hormones), biomarkers of general stress (lysosomal membrane stability-LMS, histopathology) and biomarkers of endocrine disruption (vitellogenin-like proteins and gonad index). There were no significant differences between outfall and control sites on contaminant levels, except for 4-tert-octylphenol which was higher in the outfall site. Bacteriological counts were higher in the outfall area. No relevant differences in biomarkers were detected between treated and control mussels. A significant reduction in LMS occurred in both groups after 90 days caging, indicating a stress situation possibly related to caging or to post-spawning reproductive state.     

Benthic recovery after fish farming cessation: a "beyond-BACI" approach

The development of a benthic environment after fish-farming cessation was examined. To ascertain whether recovery occurred, several abiotic (granulometry, acid-volatile sulfides, total phosphorus and redox potential) and biotic (polychaete abundance) variables were monitored using a "beyond-BACI" approach. Before the cessation of farming, the geochemical conditions and polychaete assemblages differed among the impacted and control sites. After cessation, an improvement of the geochemical conditions was achieved. A significant tendency toward a recovery of the polychaete assemblage in the impacted area was observed, but significant differences still remained compared with the control sites. The acid-volatile sulfide level was responsible for these differences. The abundance of polychaete families associated with organically enriched sediments diminished at the impacted site after cessation, whereas the abundance of some sensitive and omnivorous families increased. The "beyond-BACI" approach provided a wider framework than other approaches, enabling us to differentiate the natural variability from those changes induced by the fish farm and farming cessation.     

The data‐driven approach as an operational real‐time flood forecasting model

Accurate water level forecasts are essential for flood warning. This study adopts a data‐driven approach based on the adaptive network–based fuzzy inference system (ANFIS) to forecast the daily water levels of the Lower Mekong River at Pakse, Lao People's Democratic Republic. ANFIS is a hybrid system combining fuzzy inference system and artificial neural networks. Five ANFIS models were developed to provide water level forecasts from 1 to 5 days ahead, respectively. The results show that although ANFIS forecasts of water levels up to three lead days satisfied the benchmark, four‐ and five‐lead‐day forecasts were only slightly better in performance compared with the currently adopted operational model. This limitation is imposed by the auto‐ and cross‐correlations of the water level time series. Output updating procedures based on the autoregressive (AR) and recursive AR (RAR) models were used to enhance ANFIS model outputs. The RAR model performed better than the AR model. In addition, a partial recursive procedure that reduced the number of recursive steps when applying the AR or the RAR model for multi‐step‐ahead error prediction was superior to the fully recursive procedure. The RAR‐based partial recursive updating procedure significantly improved three‐, four‐ and five‐lead‐day forecasts. Our study further shows that for long lead times, ANFIS model errors are dominated by lag time errors. Although the ANFIS model with the RAR‐based partial recursive updating procedure provided the best results, this method was able to reduce the lag time errors significantly for the falling limbs only. Improvements for the rising limbs were modest. Copyright © 2011 John Wiley & Sons, Ltd.     

Passive microwave remote sensing of the historic February 2010 snowstorms in the Middle Atlantic region of the USA

The snowfall in the Baltimore/Washington metropolitan area during the winter of 2009/2010 was unprecedented and caused serious snow‐related disruptions. In February 2010, snowfall totals approached 2 m, and because maximum temperatures were consistently below normal, snow remained on the ground the entire month. One of the biggest contributing factors to the unusually severe winter weather in 2009/2010, throughout much of the middle latitudes, was the Arctic Oscillation. Unusually high pressure at high latitudes and low pressure at middle latitudes forced a persistent exchange of mass from north to south. In this investigation, a concerted effort was made to link remotely sensed falling snow observations to remotely sensed snow cover and snowpack observations in the Baltimore/Washington area. Specifically, the Advanced Microwave Scanning Radiometer onboard the Aqua satellite was used to assess snow water equivalent, and the Advanced Microwave Sounding Unit‐B and Microwave Humidity Sounder were employed to detect falling snow. Advanced Microwave Scanning Radiometer passive microwave signatures in this study are related to both snow on the ground and surface ice layers. In regard to falling snow, signatures indicative of snowfall can be observed in high frequency brightness temperatures of Advanced Microwave Sounding Unit‐B and Microwave Humidity Sounder. Indeed, retrievals show an increase in snow water equivalent after the detection of falling snow. Yet, this work also shows that falling snow intensity and/or the presence of liquid water clouds impacts the ability to reliably detect snow water equivalent. Moreover, changes in the condition of the snowpack, especially in the surface features, negatively affect retrieval performance. Copyright © 2011. This article is a U.S. Government work and is in the public domain in the USA.     

Effect of connecting rain barrels on the storage size reduction

In this article, the possibility of sharing rain barrels and the potential benefit of reducing storage size through physical and non‐physical connections of rain barrels in a community are investigated. Using the concepts of homogeneous/heterogeneous users in rainwater harvesting systems (RWHS), two simple cases of a community composed of four prospective users are examined. The first is performed with the users who have the same mean and variance in water demands (homogeneous users), and the second is with the users with different means and variances (heterogeneous users). To take account for the rainfall characteristics in different places, historical records from six cities in the USA are used for storage–reliability–yield analysis. The result indicates that required total storage can be reduced by connecting multiple rain barrels. In addition, a significant difference is found between homogeneous and heterogeneous user groups. Homogeneous users do not achieve a substantial benefit from connecting their rain barrels; these users may even be disadvantaged by sharing. In contrast, heterogeneous users receive benefit by reducing the total required storage. Most benefit is expected between users with maximum difference in mean water demands. The reduction in storage size was as considerable as 37% in this study. The quantity of storage reduction depends on locations and target reliabilities. Knowledge of the benefits and limitations of rain barrel connections can improve RWHS performance through ability to customize a network plan for individual users. Copyright © 2011 John Wiley & Sons, Ltd.