Analysis of incorporating groundwater exchanges in hydrological models

In many catchments, the geographical demarcation does not coincide with the limits of the aquifers, so groundwater may be exchanged beyond their topographic boundaries. By studying groundwater exchanges, the natural resources of a catchment can be better assessed, and the divergences between hydrological models and measurements can be explained. The aim of this work is to reveal the importance of including groundwater exchanges in the hydrological modelling of some catchments, using a water balance model. For this purpose, a simple example is conducted. The so‐called parent model scheme is modified to only allow groundwater exchanges, and it is applied to the headwater of the Segura River Basin District, located in the southeast of Spain. This area is selected because groundwater plays an important role in surface hydrology. The results reveal that groundwater exchanges cannot be neglected in some catchments when assessing water resources because their integration in the hydrological model corrects errors in the water balance. Moreover, this paper proves that water balance models are a useful tool for estimating groundwater exchanges between catchments, which can be contrasted with more complex distributed models or isotopic tracers if there is enough information available. Copyright © 2015 John Wiley & Sons, Ltd.     

Contraction,fragmentation and expansion dynamics determine nutrient availability in a Mediterranean forest stream

Temporary streams are a dominant surface water type in the Mediterranean region. As a consequence of their hydrologic regime, these ecosystems contract and fragment as they dry, and expand after rewetting. Global change leads to a rapid increase in the extent of temporary streams, and more and more permanent streams are turning temporary. Consequently, there is an urgent need to better understand the effects of flow intermittency on the biogeochemistry and ecology of stream ecosystems. Our aim was to investigate how stream nutrient availability varied in relation to ecosystem contraction, fragmentation and expansion due to hydrologic drying and rewetting. We quantified the temporal and spatial changes in dissolved nitrogen (N) and phosphorus (P) concentrations along a reach of a temporary Mediterranean forest stream during an entire contraction–fragmentation–expansion hydrologic cycle. We observed marked temporal changes in N and P concentrations, in the proportion of organic and inorganic forms as well as in stoichiometric ratios, reflecting shifts in the relative importance of in-stream nutrient processing and external nutrient sources. In addition, the spatial heterogeneity of N and P concentrations and their ratios increased substantially with ecosystem fragmentation, reflecting the high relevance of in-stream processes when advective transport was lost. Overall, changes were more pronounced for N than for P. This study emphasizes the significance of flow intermittency in regulating stream nutrient availability and its implications for temporary stream management. Moreover, our results point to potential biogeochemical responses of these ecosystems in more temperate regions under future water scarcity scenarios.     

Validation of Arenicola marina in field toxicity bioassays using benthic cages: biomarkers as tools for assessing sediment quality

Sediment toxicity assessments using caged organisms present advantages over using laboratory and native community studies. The use of caged Arenicola marina in sediment toxicity assessments was evaluated. Lugworms were exposed in situ to sediments from coastal and port areas in Spain for seven days, and the activities of the biotransformation enzymes ethoxyresorufin O-deethylase, dibenzylfluorescein dealkylase and glutathione S-transferase, the activities of the antioxidant enzymes glutathione reductase and glutathione peroxidase and lipid peroxidation were then analyzed as biomarkers. Biomarker results and sediment physicochemical data were integrated. Cádiz Bay (SW Spain) sediments presented metal contamination that was not linked to a biochemical response. In LPGC Port (SW Spain), Pb contamination exhibited a moderate toxic potential, while PAHs, and presumably pharmaceuticals, provoked biochemical responses that efficiently prevented lipid peroxidation. In Santander Bay (N Spain), exposure to PAHs and, presumably, pharmaceuticals induced biomarker responses, but lipid peroxidation occurred nevertheless. These results indicated that caged A. marina were effective for the assessment of sediment quality and that the selected biomarkers were sufficiently sensitive to identify chemical exposure and toxicity.     

Modelling regional impacts of climate change on water resources: the Júcar basin,Spain

Abstract

In this paper we analyse all currently available simulated climate scenarios, proposed by the Spanish Agency of Meteorology (AEMET), for the period 2010–2040 on the geographical area covered by the Júcar River basin, located in eastern Spain. This is done through the validation of these scenarios using historical records, and by assessing the impact on water resources for the next 30 years by means of a hydrological model. By taking the period 1960–1990 as the control period, a careful comparison of its historical records against AEMET scenarios is performed. Although temperature records are modelled properly, precipitation data are widely underestimated in a range from 8% to 29%. This wide variability observed in the control period is also found in the precipitation scenarios for the period 2010–2040. The impact on water resources shows a great degree of dispersion, ranging from –13.45% to 18.1% with a mean value of –2.13%.

Editor Z.W. Kundzewicz; Associate editor F. Hattermann     

Occurrence of priority pollutants in WWTP effluents and Mediterranean coastal waters of Spain

A comprehensive study aimed at evaluating the occurrence, significance of concentrations and spatial distribution of priority pollutants (PPs) along the Comunidad Valenciana coastal waters (Spain) was carried out in order to fulfil the European Water Framework Directive (WFD). Additionally, PP concentrations were also analysed in the effluent of 28 WWTPs distributed along the studied area. In coastal waters 36 organic pollutants of the 71 analysed, including 26 PPs were detected although many of them with low frequency of occurrence. Only 13 compounds, which belong to four different classes (VOCs, organochlorinated pesticides, phthalates and tributyltin compounds (TBT)) showed a frequency of occurrence above 20% in coastal waters. In the results obtained until now, octylphenol, pentachlorobenzene, DEHP and TBT exceeded the annual average concentration (EQS-AAC), and only TBT surpassed the maximum allowable concentration (EQS-MAC). The most frequent contaminants determined in coastal waters were also present in WWTP effluents.     

Morphological characteristics and medium-term evolution of the beaches between Ceuta and Cabo Negro (Morocco)

This work presents the results of a combined study on the beach morphology and the evolution at short- and medium-term of the littoral between Ceuta and Cabo Negro (Morocco). It is an interesting sector showing a great increase of human occupation and coastal structures. The monitoring program allowed for the reconstruction of the beach morphological behavior and the seasonal changes. The studied beaches presented reflective profiles recording little seasonality, with the most notable morphological changes being strictly related to storms. Surf Similarity and Surf Scaling parameters highlighted the existence of intermediate and reflective beach states, characterized by plunging breakers. Aerial photographs and a satellite image have been geo-referenced and elaborated with GIS tools to reconstruct the short- and medium-term evolution of the littoral and the sediment transport pathways. The littoral showed important erosion at short- and medium-term related to a negative sedimentary budget because of offshore transport. Sand accumulation was recorded close to the main ports, i.e., Marina Smir and Marina Kabila. These port structures constituted impermeable, fixed limits, which divided the studied area into littoral cells. Other free, transit limits were also observed.     

Contrasting environmental effects of astronomically driven climate change on three Eocene hemipelagic successions from the Basque–Cantabrian Basin

Several processes can contribute to the formation of hemipelagic limestone–marl alternations as a consequence of astronomically driven climate change. The aim of this study was to decipher which environmental factors governed the formation of three Eocene hemipelagic successions of the Basque–Cantabrian Basin using a comprehensive set of physical and bulk carbonate geochemical data (bed thickness, mineralogy, %CaCO₃, δ¹³C and δ¹⁸O). The results show that the significance of several environmental processes varied depending on the palaeogeographic setting and eccentricity‐modulated precessional seasonality. In the Sopelana starved deep‐sea basin, limestones were formed as a consequence of high pelagic carbonate productivity during periods of warm seawater and sluggish circulation, which corresponded with periods of low seasonality (summers at aphelion); conversely, marls accumulated when pelagic carbonate productivity decreased during periods with cooler waters and more vigorous circulation, which occurred when seasonality was higher (summers at perihelion). In the Gorrondatxe submarine fan fringe, marls accumulated when high seasonality produced significant continental rainfall and run‐off, causing the dilution of pelagic carbonate sedimentation with terrigenous supplies. In the Oyambre upper slope, marls also accumulated when seasonality was high, as pelagic carbonate productivity decreased due to both the expansion of low‐salinity waters on the ocean surface and the increase in continentally derived nutrients, which caused detrimental seawater conditions for calcareous plankton. Both in Gorrondatxe and Oyambre, limestones accumulated when boreal summer at aphelion caused low seasonality, which allowed relatively stable conditions to prevail. At minimum eccentricity, when precession‐driven seasonality contrast diminished, changes in pelagic carbonate productivity were significant in the three sections. On the contrary, at maximum eccentricity, when seasonality peaked due to summers occurring at perihelion, the effects of other environmental processes, such as continental and oceanic currents, became influential. However, the influence of these processes minimized when summertime coincided with aphelion at maximum eccentricity and seasonality was weakest.     

Comparative analysis of continuous radon sensors in underground environments

Four different continuous radon (²²²Rn)-detection systems have been compared in underground environments, namely three subhorizontal tunnels excavated for groundwater exploitation. Within observational uncertainties, all sensors detected the same concentrations of radon in the air of the tunnels, regardless of the methodology used to measure this radioactive gas. In this sense, the choice of continuous long-term radon monitoring sensors in underground tunnels is constrained by factors such as robustness of the instrumentation, power supply and cost, rather than the sensitivity of the detection methodology. This is particularly important for the monitoring of radon in the context of seismo-volcanic surveillance, where the harsh environmental conditions of the monitoring sites and the absence of electrical power supply are key factors to take into account.