Reconstruction of Recent Sedimentary Processes in a Carbonate Platform (Gulf of Batabano,Cuba) Using Environmental Radiotracers

Recent (past 100 years) sedimentary processes in the highly dynamic Gulf of Batabano (Cuba, Caribbean Sea) were investigated through the analyses of environmental radionuclides (e.g., ²¹⁰Pb, ²²⁶Ra, ¹³⁷Cs, ^239,240Pu, and ¹⁴C) in nine sediment cores. We evaluated the mean mass accumulation rates (MARs) and the surface mixed layers (SMLs) in each sediment core. Based on these results, three sedimentary environments were identified in the study region. In the central zone, the sediments were mainly composed of carbonate transported from the southern area and showed elevated mass accumulation rates (MAR, 0.11–0.23 g cm^?2 year^?1) and relatively deep surface mixed layers (SML, 14–16 cm). The southwestern zone was characterized by lower MAR (0.05–0.08 g cm^?2 year^?1) and thinner SML (7–8 cm). In both areas, the long sediment mixing times in the SMLs (of 45–61 years) smoothed out the sedimentary records. The coastline sedimentary environments were characterized by higher MAR (0.30–0.57 g cm^?2 year^?1) and the sedimentary records displayed clear signatures of extreme climatic events such as the intensive rains in 1999 reported for La Coloma and the hurricanes Lili and Isodore in 2002. Our study shows that the application of the ²¹⁰Pb sediment dating method in dynamic costal zones is a challenging task but still may provide important information regarding sedimentation and mixing processes in the ecosystem.     

Treatment of water-repellent petroleum-contaminated soil from Bemidji,Minnesota, by alkaline desorption

A pipeline right-of-way contaminated with light crude in 1979 and subsequently burned shows severe hydrophobicity, poor infiltration rates, and loss of vegetative cover. To evaluate alkaline desorption as a treatment method, surface soil samples were collected and analyzed pre- and post-treatment. Samples had total petroleum hydrocarbon concentrations of 2800–63,100 mg/kg, severe water repellency, critical moisture 2–5 times above the in situ moisture content, but no acute toxicity. Thus, water repellency, rather than toxicity, is causing the loss of vegetation. Samples were treated with 0.1 N NaOH in two doses (1:3; soil/solution), with complete drainage between doses. Finally, each soil sample was washed with an equal volume or water and allowed to drain completely. For more hydrophobic samples, repeated treatments, without rinsing between each treatment, were made. Post-treatment, the samples were re-analyzed for water repellency and critical moisture content. In samples with initial water repellency values in the range of 5.0–6.7 M, the repellency was reduced 94–100 % and below critical levels to avoid soil hydrophobicity in field conditions. The other samples with initial water repellency values in the range of 10–13 M could not be recovered with single treatment, but sequential treatments reduced the hydrocarbon content up to 87 % and reduced the hydrophobicity to levels low enough or nearly low enough to avoid severe water repellency in the field. Currently, field studies are being carried out to evaluate this treatment method at the site, as a stand-alone method and in combination with organic amendment.     

Geochemical mobility of arsenic in the surficial waters from Argentina

The presence of arsenic (As) in surface water constitutes an important environmental risk, where mobility and adsorption processes are responsible for its behavior in the sediment–water interface. Therefore, the assessment of adsorption, mobility and water availability of arsenic in freshwater sediments, with agricultural, livestock and urban soil uses was performed. Arsenic concentrations in sediments ranged from 5.4 to 15.9 mg kg^?1 (total) and 2.8 to 6.5 mg kg^?1 (labile), and those of iron and manganese were 11,563–23,500 and 140.6–662.1 mg kg^?1, respectively. The As levels in water were significantly lower than those of sediments. Results would suggest that As co-precipitation and adsorption on Fe oxides are probably the major route of immobilization, determining its low lability. Manganese did not present an outstanding contribution to the retention, and cation-exchange capacity, pH and organic matter of sediments did not show an influence on the mobility of As.     

Evidence of episodic long-lived eruptions in the Yuma,Ginsburg, Jesús Baraza and Tasyo mud volcanoes,Gulf of Cádiz

High-resolution single channel and multichannel seismic reflection profiles and multibeam bathymetric and backscatter data collected during several cruises over the period 1999 to 2007 have enabled characterising not only the seabed morphology but also the subsurface structural elements of the Yuma, Ginsburg, Jesús Baraza and Tasyo mud volcanoes (MVs) in the Gulf of Cádiz at 1,050–1,250 m water depth. These MVs vary strongly in morphology and size. The data reveal elongated cone-shaped edifices, rimmed depressions, and scarps interpreted as flank failures developed by collapse, faulting, compaction and gravitational processes. MV architecture is characterised by both extrusive and intrusive complexes, comprising stacked edifices (including seabed cones and up to four buried bicones) underlain by chaotic vertical zones and downward-tapering cones suggesting feeder systems. These intrusive structures represent the upper layer of the feeder system linking the fluid mud sources with the constructional edifices. The overall architecture is interpreted to be the result of successive events of mud extrusion and outbuilding alternating with periods of dormancy. Each mud extrusion phase is connected with the development of an edifice, represented by a seabed cone or a buried bicone. In all four MVs, the stacked edifices and the intrusive complexes penetrate Late Miocene–Quaternary units and are rooted in the Gulf of Cádiz wedge emplaced during the late Tortonian. Major phases of mud extrusion and outbuilding took place since the Late Pliocene, even though in the Yuma and Jesús Baraza MVs mud volcanism started in the Late Miocene shortly after the emplacement of the Gulf of Cádiz wedge. This study shows that fluid venting in the eastern sector of the Gulf of Cádiz promoted the outbuilding of large long-lived mud volcanoes active since the Late Miocene, and which have been reactivated repeatedly until recent times.