Long-term soil moisture dynamics derived from GNSS interferometric reflectometry: a case study for Sutherland,South Africa

Soil moisture is a geophysical key observable for predicting floods and droughts, modeling weather and climate and optimizing agricultural management. Currently available in situ observations are limited to small sampling volumes and restricted number of sites, whereas measurements from satellites lack spatial resolution. Global navigation satellite system (GNSS) receivers can be used to estimate soil moisture time series at an intermediate scale of about 1000 m². In this study, GNSS signal-to-noise ratio (SNR) data at the station Sutherland, South Africa, are used to estimate soil moisture variations during 2008–2014. The results capture the wetting and drying cycles in response to rainfall. The GNSS Volumetric Water Content (VWC) is highly correlated (r ² = 0.8) with in situ observations by time-domain reflectometry sensors and is accurate to 0.05 m³/m³. The soil moisture estimates derived from the SNR of the L1 and L2P signals compared to the L2C show small differences with a RMSE of 0.03 m³/m³. A reduction in the SNR sampling rate from 1 to 30 s has very little impact on the accuracy of the soil moisture estimates (RMSE of the VWC difference 1–30 s is 0.01 m³/m³). The results show that the existing data of the global tracking network with continuous observations of the L1 and L2P signals with a 30-s sampling rate over the last two decades can provide valuable complementary soil moisture observations worldwide.     

Is there a superior conceptual groundwater model structure for baseflow simulation?

Previous work has shown that streamflow response during baseflow conditions is a function of storage, but also that this functional relationship varies among seasons and catchments. Traditionally, hydrological models incorporate conceptual groundwater models consisting of linear or non‐linear storage–outflow functions. Identification of the right model structure and model parameterization however is challenging. The aim of this paper is to systematically test different model structures in a set of catchments where different aquifer types govern baseflow generation processes. Nine different two‐parameter conceptual groundwater models are applied with multi‐objective calibration to transform two different groundwater recharge series derived from a soil‐atmosphere‐vegetation transfer model into baseflow separated from streamflow data. The relative performance differences of the model structures allow to systematically improve the understanding of baseflow generation processes and to identify most appropriate model structures for different aquifer types. We found more versatile and more aquifer‐specific optimal model structures and elucidate the role of interflow, flow paths, recharge regimes and partially contributing storages. Aquifer‐specific recommendations of storage models were found for fractured and karstic aquifers, whereas large storage capacities blur the identification of superior model structures for complex and porous aquifers. A model performance matrix is presented, which highlights the joint effects of different recharge inputs, calibration criteria, model structures and aquifer types. The matrix is a guidance to improve groundwater model structures towards their representation of the dominant baseflow generation processes of specific aquifer types. Copyright © 2014 John Wiley & Sons, Ltd.     

Uncertainties of geochemical modeling during CO<Subscript>2</Subscript> sequestration applying batch equilibrium calculations

One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical models. The application of geochemical models contributes significantly to calculate the fate of the CO₂ after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as well as the option to calculate pressure dependent equilibrium constants influence the CO₂ trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model for a virtual CO₂ injection into a saline Keuper aquifer. The amount of CO₂ which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC. Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying the thermodynamic database caused a range of 61% in the amount of trapped CO₂ calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in the calculated amount of trapped CO₂. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped CO₂. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling.     

Incentives for field hydrology and data sharing: collaboration and compensation: reply to “A need for incentivizing field hydrology,especially in an era of open data”*

ABSTRACT

We thank Allen and Berghuijs for continuing the discussion on field hydrology and data sharing and discuss two incentives to promote data collection and sharing in hydrological sciences: a collaborative attitude and additional funding to make data publicly available.     

Decadal evolution of tidal flats and channels in the Outer Weser estuary,Germany

This study focuses on the medium scale morphodynamics of the tidal flat and channel system Fedderwarder Priel, located in the Outer Weser estuary (Wadden Sea, Germany). Tidal channels and adjacent flats are highly dynamic systems whose morphologic evolution are driven by tidal, wind, and wave forcings. These coastal environments are an important ecosystem and react to changes in hydrodynamic conditions in various spatial and temporal scales. Based on annual medium-resolution digital elevation models from 1998 to 2016, we describe changes in the surface area over depth with hypsometries and use vertical dynamic trends in order to analyze and visualize the morphologic evolution of the Fedderwarder Priel and adjacent tidal channels. It is shown that several intertidal flats rise in the order of 1.3 to 5.6 cm/year. The findings indicate that the Outer Weser estuary was not in an equilibrium state for the investigated period, and tidal flats accreted with a rate exceeding mean sea level rise.     

Quantifying Arctic contributions to climate predictability in a regional coupled ocean-ice-atmosphere model

The relative importance of regional processes inside the Arctic climate system and the large scale atmospheric circulation for Arctic interannual climate variability has been estimated with the help of a regional Arctic coupled ocean-ice-atmosphere model. The study focuses on sea ice and surface climate during the 1980s and 1990s. Simulations agree reasonably well with observations. Correlations between the winter North Atlantic Oscillation index and the summer Arctic sea ice thickness and summer sea ice extent are found. Spread of sea ice extent within an ensemble of model runs can be associated with a surface pressure gradient between the Nordic Seas and the Kara Sea. Trends in the sea ice thickness field are widely significant and can formally be attributed to large scale forcing outside the Arctic model domain. Concerning predictability, results indicate that the variability generated by the external forcing is more important in most regions than the internally generated variability. However, both are in the same order of magnitude. Local areas such as the Northern Greenland coast together with Fram Straits and parts of the Greenland Sea show a strong importance of internally generated variability, which is associated with wind direction variability due to interaction with atmospheric dynamics on the Greenland ice sheet. High predictability of sea ice extent is supported by north-easterly winds from the Arctic Ocean to Scandinavia.     

An ethnoarchaeological study of chemical residues in the floors and soils of Q'eqchi' Maya houses at Las Pozas,Guatemala

This ethnoarchaeological study at the Q'eqchi' Maya village of Las Pozas, Guatemala, aimed to refine the understanding of the relationship between soil chemical signatures and human activities for archaeological applications. The research involved phosphorus, exchangeable ion (calcium, potassium, magnesium, sodium), and trace element analysis of soils and earth floors extracted by Mehlich II, ammonium acetate, and DTPA chelate solutions, respectively. The results showed high levels of phosphorus, potassium, magnesium, and pH in food preparation areas, as well as high phosphorus concentrations and low pH in food consumption areas. The traffic areas exhibited low phosphorus and trace element contents, whereas refuse disposal areas were enriched. These results provide important information for the understanding of space use in ancient settlements. © 2002 Wiley Periodicals, Inc.     

Recharge response and kinematics of an unusual earthflow in Liechtenstein

Landslides - Understanding landslide behavior over medium and long timescales is crucial for predicting landslide hazard and constructing accurate landscape evolution models. The behavior of...     

Formation by silicate–fluoride + phosphate melt immiscibility of REE-rich globular segregations within aplite dikes

Aplite dikes intruding the Proterozoic 1.42(±?3) Ga Longs Peak-St. Vrain Silver Plume-type peraluminous granite near Jamestown, Colorado, contain F, P, and rare earth element (REE)-rich globular segregations, with 40–46% REE, 3.7–4.8 wt% P₂O₅, and 5–8 wt% F. A combination of textural features and geochemical data suggest that the aplite and REE-rich globular segregations co-existed as two co-genetic liquids prior to their crystallization, and we propose that they are formed by silicate–fluoride?+?phosphate (+?S?+?CO₂) melt immiscibility following ascent, cooling, and decompression of what was initially a single homogeneous magma that intruded the granite. The REE distribution coefficients between the silica-rich aplites and REE-rich segregations are in good agreement with experimentally determined distribution coefficients for immiscible silicate–fluoride?+?phosphate melts. Although monazite-(Ce) and uraninite U–Th–Pb microprobe ages for the segregations yield 1.420(±?25) and 1.442(±?8) Ga, respectively, thus suggesting a co-genetic relationship with their host granite, ε_Nd1.42Ga values for the granites and related granitic pegmatites range from ??3.3 to ??4.7 (average ??3.9), and differ from the values for both the aplites and REE-rich segregations, which range from ??1.0 to ??2.2 (average ??1.6). Furthermore, the granites and pegmatites have (La/Yb)_N <50 with significant negative Eu anomalies, which contrast with higher (La/Yb)_N >100 and absence of an Eu anomaly in both the aplites and segregations. These data are consistent with the aplite dikes and the REE-rich segregations they contain being co-genetic, but derived from a source different from that of the granite. The higher ε_Nd1.42Ga values for the aplites and REE-rich segregations suggest that the magma from which they separated had a more mafic and deeper, dryer and hotter source in the lower crust or upper mantle compared to the quartzo-feldspathic upper crustal source proposed for the Longs Peak-St. Vrain granite.