Geochemical and biological consequences of groundwater augmentation in lakes of west-central Florida (USA)

We studied sediment cores from four Florida (USA) lakes that have received groundwater hydrologic supplements (augmentation) for >30 years to maintain lake stage. Top samples (0–4 cm) from sediment cores taken in Lakes Charles, Saddleback, Little Hobbs, and Crystal had ²²⁶Ra activities of 44.9, 17.5, 7.6, and 8.5 dpm g⁻¹, respectively, about an order of magnitude greater than values in deeper, older deposits. The surface sample from Lake Charles yielded the highest ²²⁶Ra activity yet reported from a Florida lake core. Several lines of evidence suggest that groundwater augmentation is responsible for the high ²²⁶Ra activities in recent sediments: (1) ²²⁶Ra activity in cores increased recently, (2) the Charles, Crystal, and Saddleback cores display ²²⁶Ra/²¹⁰Pb disequilibrium at several shallow depths, suggesting ²²⁶Ra entered the lakes in dissolved form, (3) cores show recent increases in Ca, which, like ²²⁶Ra, is abundant in augmentation groundwater, and (4) greater Sr concentrations are associated with higher ²²⁶Ra activities in recent Charles and Saddleback sediments. Sr concentrations in Eocene limestones of the deep Floridan Aquifer are high relative to Sr concentrations in surficial quartz sands around the lakes. Historical water quality inferences for the lakes were based on diatom assemblages in sediments. Recent alkalization in Lakes Charles, Saddleback, Little Hobbs, and Crystal was inferred from weighted-averaging calibration (WACALIB). The lakes also show recent trophic state increases based on WACALIB-derived estimates for limnetic total P. Although residential and agricultural sources might contribute to increased P loading, P in augmentation waters probably has had significant influence on eutrophication. Dystrophic diatoms were abundant in the early history of Lakes Saddleback, Little Hobbs, and Crystal, which suggests that these lakes contained more tannic waters during the past than at present, perhaps as a consequence of greater inflows from surrounding wetlands. Ionic content of lake waters increased, as indicated by diatom autecological analysis. Recent geochemical and biological changes detected in cores from these lakes probably are a result of deliberate groundwater augmentation, although inputs of groundwater pumped for agricultural and residential development in the watersheds also might have contributed to limnological changes.     

A three-dimensional radially anisotropic model of shear velocity in the whole mantle

We present a 3-D radially anisotropic S velocity model of the whole mantle (SAW642AN), obtained using a large three component surface and body waveform data set and an iterative inversion for structure and source parameters based on Non-linear Asymptotic Coupling Theory (NACT). The model is parametrized in level 4 spherical splines, which have a spacing of ∼ 8°. The model shows a link between mantle flow and anisotropy in a variety of depth ranges. In the uppermost mantle, we confirm observations of regions with   V_SH > V_SV   starting at ∼80 km under oceanic regions and ∼200 km under stable continental lithosphere, suggesting horizontal flow beneath the lithosphere. We also observe a   V_SV > V_SH   signature at ∼150–300 km depth beneath major ridge systems with amplitude correlated with spreading rate for fast-spreading segments. In the transition zone (400–700 km depth), regions of subducted slab material are associated with   V_SV > V_SH   , while the ridge signal decreases. While the mid-mantle has lower amplitude anisotropy (<1 per cent), we also confirm the observation of radially symmetric   V_SH > V_SV   in the lowermost 300 km, which appears to be a robust conclusion, despite an error in our previous paper which has been corrected here. The 3-D deviations from this signature are associated with the large-scale low-velocity superplumes under the central Pacific and Africa, suggesting that   V_SH > V_SV   is generated in the predominant horizontal flow of a mechanical boundary layer, with a change in signature related to transition to upwelling at the superplumes.     

Whither Critical Inquiry?*

In his article, “Whither Geography?,” Jay R. Harman raised a number of important issues regarding the nature and direction of geographic scholarship. In this response I critically address some of those issues and offer an alternative perspective. In doing so, I support Harman's desire for the discipline to “help answer deep human questions” but argue that rather than reinforce the vitality and legitimacy of the discipline, a market‐based approach of the sort he advocates could instead potentially undermine such objectives and compromise disciplinary integrity by discouraging critical inquiry. While acknowledging the influence of “the market,” I defend a place for critical inquiry within the discipline.     

U–Pb SHRIMP zircon dating of Grenvillian metamorphism in Western Sierras Pampeanas (Argentina): Correlation with the Arequipa-Antofalla craton and constraints on the extent of the Precordillera Terrane

Metamorphism of Grenvillian age (ca. 1.2 Ga; U–Pb zircon dating) is recognized for the first time in the Western Sierras Pampeanas (Sierra de Maz). Conditions reached granulite facies (ca. 780 °C and ca. 780 MPa). Comparing geochronological and petrological characteristics with other outcrops of Mesoproterozoic basement, particularly in the northern and central Arequipa-Antofalla craton, we suggest that these regions were part of a single continental crustal block from Mesoproterozoic times, and thus autochthonous or parautochthonous to Gondwana.     

High-field cantilever magnetometry as a tool for the determination of the magnetocrystalline anisotropy of single crystals

Cantilever torque magnetometry is utilized widely in physics and material science for the determination of magnetic properties of thin films and semiconductors. Here, we report on its first application in rock magnetism, namely the determination of K₁ and K₂ of single crystal octahedra of natural magnetite. The design of cantilever magnetometers allows optimization for the specific research question at hand. For the present study, a cantilever magnetometer was used that enables measurement of samples with a volume up to 64 mm³. It can be inserted into an electromagnet with a maximum field of 2 T. The cantilever spring is suitable for torque values ranging from 7.5 × 10^− 7 N·m to 5 × 10^− 6 N·m. The torque is detected capacitively; the measured capacitance is converted into torque by using a calibrated feedback coil. The magnetometer allows in-situ rotation of the sample in both directions and is, therefore, also suitable to analyze rotational hysteresis effects.The evaluation of the magnetite anisotropy constants involved Fourier analysis of the torque signal on the magnetite crystals' (001) and (110) planes. The absolute anisotropy constant has been computed using the extrapolation-to-infinite-field method. The value of K₁ at room temperature is determined at − 1.28 × 10⁴ [J m^− 3] (± 0.13, i.e. 10%) and that of K₂ at − 2.8 × 10³ [J m^− 3] (± 0.1, i.e. 2%). These values concur with earlier determinations that could not provide an instrumental error, in contrast with this work.The cantilever magnetometer performs four times faster than other torque magnetometers used for rock magnetic studies. This makes the instrument also suitable for magnetic fabric analysis.     

Scale relationships in hillslope runoff and erosion

Eight runoff plots, located within a small catchment within the Walnut Gulch Experimental Watershed, southern Arizona, were constructed to test the argument that sediment yield (kg m^?2) decreases as plot length increases. The plots ranged in length from 2 m to 27·78 m. Runoff and sediment loss from these plots were obtained for ten natural storm events. The pattern of sediment yield from these plots conforms to the case in which sediment yield first increases as plot length increases, but then subsequently decreases. Data from the present experiment indicate that maximum sediment yield would occur from a plot 7 m long. Analysis of both runoff and sediment yield from the plots indicates that the relationship of sediment yield to plot length derives both from the limited travel distance of individual entrained particles and from a decline in runoff coefficient as plot length increases. Particle‐size analysis of eroded sediment confirms the role of travel distance in controlling sediment yield. Whether in response to the finite travel distance of entrained particles or the relationship of runoff coefficient to plot length, the experiment clearly demonstrates that the erosion rates for hillslopes and catchments cannot be simply extrapolated from plot measurements, and that alternative methods for estimating large‐area erosion rates are required. Copyright © 2006 John Wiley & Sons, Ltd.     

Arctic climate change with a 2 ∘C global warming: Timing, climate patterns and vegetation change

The signatories to United Nations Framework Convention on Climate Change are charged with stabilizing the concentrations of greenhouse gases in the atmosphere at a level that prevents dangerous interference with the climate system. A number of nations, organizations and scientists have suggested that global mean temperature should not rise over 2 ^°C above preindustrial levels. However, even a relatively moderate target of 2 ^°C has serious implications for the Arctic, where temperatures are predicted to increase at least 1.5 to 2 times as fast as global temperatures. High latitude vegetation plays a significant role in the lives of humans and animals, and in the global energy balance and carbon budget. These ecosystems are expected to be among the most strongly impacted by climate change over the next century. To investigate the potential impact of stabilization of global temperature at 2 ^°C, we performed a study using data from six Global Climate Models (GCMs) forced by four greenhouse gas emissions scenarios, the BIOME4 biogeochemistry-biogeography model, and remote sensing data. GCM data were used to predict the timing and patterns of Arctic climate change under a global mean warming of 2 ^°C. A unified circumpolar classification recognizing five types of tundra and six forest biomes was used to develop a map of observed Arctic vegetation. BIOME4 was used to simulate the vegetation distributions over the Arctic at the present and for a range of 2 ^°C global warming scenarios. The GCMs simulations indicate that the earth will have warmed by 2 ^°C relative to preindustrial temperatures by between 2026 and 2060, by which stage the area-mean annual temperature over the Arctic (60–90^°N) will have increased by between 3.2 and 6.6 ^°C. Forest extent is predicted by BIOME4 to increase in the Arctic on the order of 3 × 10⁶ km² or 55% with a corresponding 42% reduction in tundra area. Tundra types generally also shift north with the largest reductions in the prostrate dwarf-shrub tundra, where nearly 60% of habitat is lost. Modeled shifts in the potential northern limit of trees reach up to 400 km from the present tree line, which may be limited by dispersion rates. Simulated physiological effects of the CO₂ increase (to ca. 475 ppm) at high latitudes were small compared with the effects of the change in climate. The increase in forest area of the Arctic could sequester 600 Pg of additional carbon, though this effect is unlikely to be realized over next century.     

Fire Danger Monitoring Using ERS-1 SAR Images in the Case of Northern Boreal Forests

Research was carried out to assess the potential of imaging radar systems formonitoring forest fire danger. In Canada, daily forest fire danger ratings are generated by the Canadian ForestFire Danger Rating System (CFFDRS), based on estimates of fire weather indices (FWI) and measured foliar moisturecontent (FMC). To evaluate the potential of imaging radar, an experiment was conducted using test sitesconsisting of jack pine, black spruce and white spruce stands located in the MacKenzie river basin, NorthwestTerritories, Canada. Radar image intensity values from ERS-1 SAR imagery collected over these stands in 1994 werecompared to FWI indices and FMC data. FWI indices were calculated using data from local weather stations.Seasonal trends in radar backscatter (⁰) were shown to correlate with temperature and precipitation. Significant relationships were found between ⁰ and FWI codes and indices, particularly in thecase of the black spruce stands, with slow-drying fuels, like duff moisture code (DMC), drought code (DC), and build-upindex (BUI). Rates of changes in ⁰were related to rates of changes in FMC, particularly in the case ofthe jack pine stands for old FMC and in the case of white spruce stands for composite FMC.