Organotin accumulation in an estuarine food chain: comparing field measurements with model estimations

The bioaccumulation model OMEGA (optimal modelling for ecotoxicological applications) is used to explore accumulation of organotins in the Western Scheldt food chain, consisting of herbi-detritivores, primary and secondary carnivorous fish and a piscivorous bird. Organotins studied are tributyltin (TBT) and triphenyltin (TPT) and the respective di- and mono-organotin metabolites. Empirical elimination rate constants are compared to model predictions for organic substances and metals. It is found that field bioaccumulation ratios are higher than predicted based on elimination kinetics relevant for organic compounds. The results indicate that uptake of organotins mainly occurs via hydrophobic mechanisms, whereas elimination may occur via metal-like kinetics. This results in very low elimination rates, which are comparable to model predictions for metals.     

Computational issues and applications of line-elements to model subsurface flow governed by the modified Helmholtz equation

Two new approaches are presented for the accurate computation of the potential due to line elements that satisfy the modified Helmholtz equation with complex parameters. The first approach is based on fundamental solutions in elliptical coordinates and results in products of Mathieu functions. The second approach is based on the integration of modified Bessel functions. Both approaches allow evaluation of the potential at any distance from the element. The computational approaches are applied to model transient flow with the Laplace transform analytic element method. The Laplace domain solution is computed using a combination of point elements and the presented line elements. The time domain solution is obtained through a numerical inversion. Two applications are presented to transient flow fields, which could not be modeled with the Laplace transform analytic element method prior to this work. The first application concerns transient single-aquifer flow to wells near impermeable walls modeled with line-doublets. The second application concerns transient two-aquifer flow to a well near a stream modeled with line-sinks.     

Spawning origin of small,late-hatched Atlantic herring (Clupea harengus) larvae in a Maine estuary

Atlantic herring (Clupea harengus) larvae have been collected for resource monitoring purposes in the Sheepscot River in mid-coastal Maine during October–February, for the past 20 years. During this period, the larval population in the river has typically peaked in October-early November and has been composed of larvae derived from August–September spawning in eastern Maine and New Brunswick waters and from September-early October spawning along the central Maine coast. Larvae from eastern coastal spawning areas are transported to the river by the prevailing westerly coastal current. The appearance of small (≤15 mm SL) larvae in the river during December and January 1985–1989 suggested an additional time and area of origin. Aging procedures based on enumeration of daily otolith increments showed the majority of these small larvae were spawned from mid October to mid November when spawning usually occurs in western Maine coastal waters and in the vicinity of Jeffreys Ledge. Comparison of back-calculated hatching dates for small larvae collected in the river with wind direction and velocity data from mid October through November suggested that larvae were transported eastward against a weakened Gulf of Maine coastal current to the Sheepscot River by complex wind-driven surface currents that occur off the western Maine coast in the fall. *** DIRECT SUPPORT *** A01BY059 00003     

Urban land use/land cover changes in the Tema metropolitan area (1990–2010)

Land use and land cover changes are local and place specific, occurring incrementally in ways that often escape our attention. This study sought to detect changes in land cover in the Tema Metropolis of Ghana from 1990 to 2010. Multispectral Landsat Thematic Mapper data sets of 1990, 2000 and 2007 were acquired, pre-processed and enhanced. Unsupervised classification of the images was performed and six land cover classes (water, wetlands, closed vegetation, open vegetation, cropped lands, and built-up) were derived. The post-classification change detection technique was performed to derive the changes in land cover and their corresponding change matrices. Between 1990 and 2010, built-up areas expanded steadily to become the most prevalent land cover type in the metropolis, reducing vegetation cover dramatically. High population growth with its attendant rise in the demand for housing, and increasing commercial activities, were found to have influenced land cover changes over the period.     

Resting spores of the freshwater diatomsAcanthoceras andUrosolenia

Diatom resting spores are a widespread, but sometimes misconstrued component of siliceous microfossil assemblages. We illustrate and discuss resting spore morphology found in populations ofAcanthoceras andUrosolenia, two widely distributed freshwater genera. Taxonomic status of these genera and the potential paleolimnologic interpretation of resting spores are discussed.