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101.
A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials 总被引:6,自引:1,他引:6
Jean Carignan Damien Cardinal Anton Eisenhauer Albert Galy Mark Rehkamper Frank Wombacher Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148
This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis. 相似文献
102.
Spatial Dimensions of Urban Commuting: A Review of Major Issues and Their Implications for Future Geographic Research* 总被引:3,自引:0,他引:3
Mark W. Horner 《The Professional geographer》2004,56(2):160-173
Modern urban transportation systems continuously challenge, and are challenged by, the changing nature of 21st‐century travel demand. Today, congestion is the norm in cities of the United States, and researchers and practitioners are seeking solutions to these problems. Urban commuting is identified as contributing to the suboptimal performance of transportation systems. This paper offers a review and critique of recent research on urban commuting, emphasizing geographical dimensions of this topic. Three broad areas of research related to urban commuting are discussed. These include (1) urban sustainability, (2) land use, and (3) geographic information systems (GIS). Major themes are examined in an effort to elicit thought on future geographic research. At the conclusion of the paper, summary remarks are provided and avenues for research are outlined. 相似文献
103.
Mark D. Bjelland 《The Professional geographer》2004,56(3):326-336
This study charts the presence of geography at liberal arts colleges and explores the relationship between the liberal arts and the study of geography. The results of this study reveal a paradox: geography embodies many of the ideals of a liberal arts education and yet this study indicates an absence of degree‐granting geography programs at 93% of institutions. Geography thrives, however, at a select group of liberal arts colleges, and these colleges are disproportionately important as the undergraduate origin for doctorate recipients in geography. 相似文献
104.
Alexander B Verchovsky and Mark A Sephton review the origins and significance of noble gases in meteorites, focusing on what this unique record reveals about the early solar system. 相似文献
105.
Michael Pearlman Carey Noll Peter Dunn Julie Horvath Van Husson Paul Stevens Mark Torrence Hoai Vo Scott Wetzel 《Journal of Geodynamics》2005,40(4-5):470
The International Laser Ranging Service (ILRS) was established in September 1998 as a service within the IAG to support programs in geodetic, geophysical, and lunar research activities and to provide data products to the International Earth Rotation Service (IERS) in support of its prime objectives. Now in operation for 5 years, the ILRS develops: (1) the standards and specifications necessary for product consistency and (2) the priorities and tracking strategies required to maximize network efficiency. The service collects, merges, analyzes, archives and distributes satellite and lunar laser ranging data to satisfy a variety of scientific, engineering, and operational needs and encourages the application of new technologies to enhance the quality, quantity, and cost effectiveness of its data products. The ILRS works with: (1) the global network to improve station performance; (2) new satellite missions in the design and building of retroreflector targets to maximize data quality and quantity and (3) science programs to optimize scientific data yield. The ILRS Central Bureau maintains a comprehensive web site as the primary vehicle for the distribution of information within the ILRS community. The site, which can be accessed at: http://ilrs.gsfc.nasa.gov is also available at mirrored sites at the Communications Research Laboratory (CRL) in Tokyo and the European Data Center (EDC) in Munich.During the last 2 years, the ILRS has addressed very important challenges: (1) data from the field stations are now submitted hourly and made available immediately through the data centers for access by the user community; (2) tracking on low satellites has been significantly improved through the sub-daily issue of predictions, drag functions, and the real-time exchange of time biases; (3) analysis products are now submitted in SINEX format for compatibility with the other space geodesy techniques; (4) the Analysis Working Group is heavily engaged in Pilot Projects as it works toward an ILRS “standard” global solution and (5) SLR has significantly increased its participation in the International Terrestrial Reference Frame (ITRF) activity, which is important to the success of IGGOS. 相似文献
106.
Stable isotope data on humid tropical hydrology are scarce and, at present, no such data exist for Borneo. Delta18O, δ2H and δ13C were analysed on 22 water samples from different parts of the Sungai (river) Niah basin (rain, cave drip, rainforest pool, tributary stream, river, estuary, sea) in north‐central Sarawak, Malaysian Borneo. This was done to improve understanding of the modern stable isotope systematics of the Sungai Niah basin, essential for the palaeoenvironmental interpretation of the Late Quaternary stable isotope proxies preserved in the Great Cave of Niah. The Niah hydrology data are put into a regional context using the meteoric water line for Southeast Asia, as derived from International Atomic Energy Agency/World Meteorological Organization isotopes in precipitation network data. Although the Niah hydrological data‐set is relatively small, spatial isotopic variability was found for the different subenvironments of the Sungai Niah basin. A progressive enrichment occurs towards the South China Sea (δ18O ?4·6‰; δ2H ?29·3‰; δ13C ?4·8‰) from the tributary stream (δ18O ?8·4‰; δ2H ?54·7‰; δ13C ?14·5‰) to up‐river (δ18O c. ?8‰; δ2H c. ?51‰; δ13C c. ?12‰) and down‐river values (δ18O c. ?7·5‰; δ2H c. ?45‰; δ13C c. ?11‰). This is thought to reflect differential evaporation and mixing of different components of the water cycle and a combination of depleted biogenic δ13C (plant respiration and decay) with enriched δ13C values (due to photosynthesis, atmospheric exchange, mixing with limestone and marine waters) downstream. Cave drip waters are relatively enriched in δ13C as compared to the surface waters. This may indicate rapid degassing of the cave drips as they enter the cave atmosphere. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
107.
The 1998 eruption of Volcán Cerro Azul in the Galápagos Islands produced two intra-caldera vents and a flank vent that erupted more than 1.0×108 m3 of lava. Lava compositions changed notably during the 5-week eruption, and contemporaneous eruptions in the caldera and on the flank produced different compositions. Lavas erupted from the flank vent range from 6.3 to 14.1% MgO, nearly the entire range of MgO contents previously reported from the volcano. On-site monitoring of eruptive activity is linked with petrogenetic processes such that geochemical variations are evaluated in a temporal context. Lavas from the 1998 eruption record two petrogenetic stages characterized by progressively more mafic lavas as the eruption proceeded. Crystal compositions, whole rock major and trace element compositions, and isotope ratios indicate that early lavas are the product of mixing between 1998 magma and remnant magma of the 1979 eruption. Intra-caldera lavas and later lavas have no 1979 signature, but were produced by the 1998 magma incorporating olivine and clinopyroxene xenocrysts. Thus, early magma petrogenesis is characterized by mixing with the 1979 magma, followed by the magma progressively entraining wehrlite cumulate mush.Editorial Responsibility: M.R. Carroll 相似文献
108.
Mark Cleary 《Singapore journal of tropical geography》2005,26(3):359-374
The paper examines how land and forest management policies were elaborated in French Indochina circa 1900–40. It places their development in the context of a scientific and economic discourse about the value of land and forest resources, the most appropriate ways in which they might be exploited and the relationship between colonial science and indigenous knowledge. By focusing on debates and laws relating to the development of small‐scale and plantation farming systems (Land Code legislations) and forest management and exploitation (Forest Code legislations) the paper seeks to ground arguments about Western conceptions of the “tropics” within a discussion of national policy development and impacts. Focusing primarily on Cochinchina and Annam (southern and central Vietnam) and drawing on materials from French archives, the paper shows how changes in both attitudes and legislation have had lasting consequences on systems of property rights in forest management and on the place and status of indigenous peoples in Indochina. 相似文献
109.
Recent research has highlighted the value of employing the idea of networks to describe the interrelatedness of today's globalizing economy. Networks facilitate flows of knowledge, ideas, managerial techniques and capital between firms both within and across political borders. This paper argues that the reconstruction of social connections through which information is created, given value and exchanged is fundamental to an understanding of not only contemporary but also historical patterns of economic globalization. We focus on the networks of the capitalist elite running 12 major multinational enterprises, active across British imperial territories, between c .1900 and c .1930. An examination is made of the economic and spatial interlocks between firms created by board members who were multiple directors. Social underpinnings of multiple directorates are examined by exploring the common, overlapping social spheres within which individuals engaged. A clearer grasp of the ways in which corporate activity operated in the early 1900s can provide a better understanding of the social context of global economic operations. 相似文献
110.
Kelly Addy Arthur Gold Barbara Nowicki James McKenna Mark Stolt Peter Groffman 《Estuaries and Coasts》2005,28(6):896-908
Coastal waters are severely threatened by nitrogen (N) loading from direct groundwater discharge. The subterranean estuary,
the mixing zone of fresh groundwater and sea water in a coastal aquifer, has a high potential to remove substantial N. A network
of piezometers was used to characterize the denitrification capacity and groundwater flow paths in the subterranean estuary
below a Rhode Island fringing salt marsh.15N-enriched nitrate was injected into the subterranean estuary (in situ push-pull method) to evaluate the denitrification capacity
of the saturated zone at multiple depths (125–300 cm) below different zones (upland-marsh transition zone, high marsh, and
low marsh). From the upland to low marsh, the water table became shallower, groundwater dissolved oxygen decreased, and groundwater
pH, soil organic carbon, and total root biomass increased. As groundwater approached the high and low marsh, the hydraulic
gradient increased and deep groundwater upwelled. In the warm season (groundwater temperature >12 °C), elevated groundwater
denitrification capacity within each zone was observed. The warm season low marsh groundwater denitrification capacity was
significantly higher than all other zones and depths. In the cool season (groundwater temperature <10.5 °C), elevated groundwater
denitrification capacity was only found in the low marsh. Additions of dissolved organic carbon did not alter groundwater
denitrification capacity suggesting that an alternative electron donor, possibly transported by tidal inundation from the
root zone, may be limiting. Combining flow paths with denitrification capacity and saturated porewater residence time, we
estimated that as much as 29–60 mg N could be removed from 11 of water flowing through the subterranean estuary below the
low marsh, arguing for the significance of subterranean estuaries in annual watershed scale N budgets. 相似文献