Age, geology, geophysics, and geochemistry of Mahukona Volcano, Hawai`i

The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (～6,000?km³) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ～270?m below sea level but probably did not form an island. New ⁴⁰Ar–³⁹Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high ³He/⁴He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized.     

Esterase activities in the bivalve mollusc Adamussium colbecki as a biomarker for pollution monitoring in the Antarctic marine environment

Marine environments are continuously being threatened by a large number of xenobiotics from anthropogenic sources. Even in sparsely populated and relatively pristine areas, such as Antarctica, hazardous chemicals can pose a serious environmental problem. The main aims of the present study were to (1) validate and optimize an analytical technique utilizing a microtitre-plate photometer to ascertain background levels of esterase activities in the Antarctic bivalve Adamussium colbecki, (2) carry out in situ monitoring of esterase activities to assess any potential environmental impacts of the Italian Scientific Antarctic Base "Terra Nova Bay" on the surrounding marine area. Results showed the presence of organophosphorous-sensitive cholinesterase (ChE) and carboxylesterase (CbE) activities in the gills of A. colbecki and optimal assay conditions were comparable with those found for bivalve species from temperate areas. A higher sensitivity of ChE versus acetylthiocholine activity in A. colbecki to chlorpyrifos compared to species from temperate areas may also be inferred. The in situ study indicated no differences in the environmental quality of the three study sites located around the Italian Base.     

Spatial assessment of fishing effort around European marine reserves: implications for successful fisheries management

We examined the spatial dynamic of artisanal fishing fleets around five European marine protected areas (MPAs) to derive general implications for the evaluation of MPAs as fisheries management tools. The coastal MPAs studied were located off France, Malta and Spain and presented a variety of spatial designs and processes of establishment. We developed a standardized methodology to define factors influencing effort allocation and to produce fishing effort maps by merging GIS with geostatistical modelling techniques. Results revealed that in most cases the factors “distance to the no-take”, “water depth”, and “distance to the port” had a significant influence on effort allocation by the fishing fleets. Overall, we found local concentration of fishing effort around the MPA borders. Thus, neglecting the pattern of fishing effort distribution in evaluating MPA benefits, such as spillover of biomass, could hamper sound interpretation of MPAs as fisheries management tools.     

Suspended sediment fluxes at an intertidal flat: The shifting influence of wave,wind, tidal,and freshwater forcing

Using in situ, continuous, high frequency (8–16 Hz) measurements of velocity, suspended sediment concentration (SSC), and salinity, we investigate the factors affecting near-bed sediment flux during and after a meteorological event (cold front) on an intertidal flat in central San Francisco Bay. Hydrodynamic forcing occurs over many frequency bands including wind wave, ocean swell, seiching (500–1000 s), tidal, and infra-tidal frequencies, and varies greatly over the time scale of hours and days. Sediment fluxes occur primarily due to variations in flow and SSC at three different scales: residual (tidally averaged), tidal, and seiching. During the meteorological event, sediment fluxes are dominated by increases in tidally averaged SSC and flow. Runoff and wind-induced circulation contribute to an order of magnitude increase in tidally averaged offshore flow, while waves and seiching motions from wind forcing cause an order of magnitude increase in tidally averaged SSC. Sediment fluxes during calm periods are dominated by asymmetries in SSC over a tidal cycle. Freshwater forcing produces sharp salinity fronts which trap sediment and sweep by the sensors over short (∼30 min) time scales, and occur primarily during the flood. The resulting flood dominance in SSC is magnified or reversed by variations in wind forcing between the flood and ebb. Long-term records show that more than half of wind events (sustained speeds of greater than 5 m/s) occur for 3 h or less, suggesting that asymmetric wind forcing over a tidal cycle commonly occurs. Seiching associated with wind and its variation produces onshore sediment transport. Overall, the changing hydrodynamic and meteorological forcing influence sediment flux at both short (minutes) and long (days) time scales.     

First evidence for episodic flooding events in the arid interior of central Saudi Arabia over the last 60 ka

Although evidence for Quaternary environmental changes in the Arabian Peninsula is now growing, research has mostly been conducted in the United Arab Emirates (UAE) and in the Sultanate of Oman. There have been virtually no recent studies in Saudi Arabia, especially in the central region such as around Al‐Quwaiayh. In this area there are a series of outwash plains developed along the eastern edge of the Arabian Shield that formed in the late Quaternary. Four sedimentary sections, which are representative of the deposits that have accumulated, have been studied and five luminescence ages obtained. These are the first luminescence ages acquired from Quaternary sediments in central Saudi Arabia. The preserved fluvial deposits in the study area have formed during humid events at ca. 54 ka, ca. 39 ka and ca. 0.8 ka. In more recent times aeolian sands have been encroaching on to the distal parts of the outwash plains. Copyright © 2008 John Wiley & Sons, Ltd.     

Amino acid geochemistry of fossil bones from the Rancho La Brea asphalt deposit,California

Low aspartic acid d:l ratios and modern collagenlike concentration values indicate that amino acids in bones from the Rancho La Brea asphalt deposit, Los Angeles, California are better preserved than amino acids in bones of equivalent age that have not been preserved in asphalt. Amino acids were recovered from 10 Rancho La Brea bone samples which range in age from less than 200 to greater than 36,000 yr. The calibrated rates of aspartic acid racemization range from 2.1 to 5.0 × 10^?6yr^?1. Although this wide range of rate constants decreases the level of confidence for age estimates, use of the larger rate constant of 5.0 × 10^?6yr^?1 provides minimum age estimates which fit the known stratigraphic and chronologic records of the Rancho La Brea deposits.     

A transport‐distance approach to scaling erosion rates: 3. Evaluating scaling characteristics of Mahleran

In the two previous papers of this series, we demonstrated how a novel approach to erosion modelling (Mahleran – Model for Assessing Hillslope‐Landscape Erosion, Runoff And Nutrients) provided distinct advantages in terms of process representation and explicit scaling characteristics when compared with existing models. A first evaluation furthermore demonstrated the ability of the model to reproduce spatial and temporal patterns of erosion and their particle‐size characteristics on a large rainfall‐simulation plot. In this paper, we carry out a more detailed evaluation of the model using monitored erosion events on plots of different size. The evaluation uses four plots of 21·01, 115·94, 56·84 and 302·19 m², with lengths of 4·12, 14·48, 18·95 and 27·78 m, respectively, on similar soils to the rainfall‐simulation plot, for which runoff and erosion were monitored under natural rainfall. Although the model produces the correct ranking of the magnitude of erosion events, it performs less well in reproducing the absolute values and particle‐size distributions of the eroded sediment. The implications of these results are evaluated in terms of requirements for process understanding and data for parameterization of improved soil‐erosion models. We suggest that there are major weaknesses in the current understanding and data underpinning existing models. Consequently, a more holistic re‐evaluation is required that produces functional relationships for different processes that are mutually consistent, and that have appropriate parameterization data to support their use in a wide range of environmental conditions. Copyright © 2008 John Wiley & Sons, Ltd.     

Hydrogeologic Controls on Induced Seismicity in Crystalline Basement Rocks Due to Fluid Injection into Basal Reservoirs

A series of M_b 3.8–5.5 induced seismic events in the midcontinent region, United States, resulted from injection of fluid either into a basal sedimentary reservoir with no underlying confining unit or directly into the underlying crystalline basement complex. The earthquakes probably occurred along faults that were likely critically stressed within the crystalline basement. These faults were located at a considerable distance (up to 10 km) from the injection wells and head increases at the hypocenters were likely relatively small (～70–150 m). We present a suite of simulations that use a simple hydrogeologic‐geomechanical model to assess what hydrogeologic conditions promote or deter induced seismic events within the crystalline basement across the midcontinent. The presence of a confining unit beneath the injection reservoir horizon had the single largest effect in preventing induced seismicity within the underlying crystalline basement. For a crystalline basement having a permeability of 2 × 10^?17 m² and specific storage coefficient of 10^?7/m, injection at a rate of 5455 m³/d into the basal aquifer with no underlying basal seal over 10 years resulted in probable brittle failure to depths of about 0.6 km below the injection reservoir. Including a permeable (k_z = 10^?13 m²) Precambrian normal fault, located 20 m from the injection well, increased the depth of the failure region below the reservoir to 3 km. For a large permeability contrast between a Precambrian thrust fault (10^?12 m²) and the surrounding crystalline basement (10^?18 m²), the failure region can extend laterally 10 km away from the injection well.