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Mark L. Kram Stephen H. Lieberman Jerry Fee Arturo A. Keller 《Ground Water Monitoring & Remediation》2001,21(1):67-76
The site characterization and analysis cone penetrometer system (SCAPS), equipped with realtime fluorophore detection capabilities, was used to delineate subsurface contaminant releases in an area where plating shop waste was temporarily stored. Records indicated that various nonaqueous phase liquids (NAPLs) were released at the site. The investigators advanced the SCAPS laser-induced fluorescence (LIF) sensor to depths beneath the water table of the principal water-bearing zone. The water table was located approximately 6 feet (1.8 m) below ground surface (bgs) across the site. Fluorescence, attributed to fuel compounds commingled with chlorinated solvents, was observed at depths ranging from 4.0 to 11.5 feet (1.2 to 3.5 m) bgs. Fluorescence, attributed to naturally occurring organic materials (by process of elimination and spectral characteristics) commingled with chlorinated solvent constituents, was observed at depths ranging from approximately 13 to 40 feet (4.0 to 12.2 m) bgs. Fluorescence responses from compounds confirmed to be commingled with chlorinated solvents indicates that the SCAPS fluorophore detection system is capable of indirectly delineating vadose zone and subaqueous chlorinated solvents and other dense nonaqueous phase liquids (DNAPLs) at contaminant release sites. This confirmation effort represents the first documented account of the successful application of LIF to identify a mixed DNAPL/LNAPL source zone. 相似文献
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Pebble clusters are common small‐scale morphological features in gravel‐bed rivers, occupying as much as 10 per cent of the bed surface. Important links exist between the presence of pebble clusters and the development of flow structures. These links are poorly understood at the three‐dimensional level. Particularly neglected has been the effect of clusters on the lateral flow characteristics. A laboratory study was conducted using a hydraulic flume, within which simulated pebble clusters were superimposed onto a plane bed of gravel material. High‐resolution three‐dimensional flow data were collected above the bed at two different flow depths using an acoustic Doppler velocimeter. The results present evidence of the importance of lateral flow in the development of turbulent flow structure. Narrow regions of high lateral and downstream turbulence intensity exist to both sides of clusters and in a three‐dimensional separation zone in their lee. This may indicate the presence of horseshoe‐type vortical structures analogous to those identified in less hydraulically rough environments. However, it is likely that these structures are more complicated given the mutual interference of the surrounding medium. The lateral flow was also identified as a key component in the upwelling identified by other authors in the lee of pebble clusters. The results of the vertical flow analysis confirm the hypothesis that six regions with distinct vertical flow characteristics exist above clusters: flow acceleration up the stoss‐side of the cluster; recirculation behind the cluster in the wake region; vortex shedding from the pebble crest and shear layer; flow reattachment downstream of the cluster; upwelling of flow downstream of the point of reattachment; and recovery of flow. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
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While it is intuitively attractive to link health status and the quality of housing, it is methodologically complex to identify the relative importance of housing because individual characteristics and environmental variables act as confounders. A secondary issue is that the data sets which contain detailed data on health status and environmental variables often contain only limited data on housing. Similarly, housing surveys rarely contain detailed data on health and environmental variables. Respondents from Montreal, Toronto and Vancouver in the public use micro-data files of the 1996/97 cycle of the National Population Health Survey make up the data sets for a series of logistic regression models where health status, allergies, asthma, arthritis, migraines and bronchitis/emphysema act as the dependent variables. Sets of variables which measure housing, the environment (smoking and alcohol consumption) and the socio-economic status of individuals are used as independent variables. The issues of confounders and the limitations of the data are illustrated by the results of the analysis. If we are to go beyond local area surveys and carry out broader analyses of the links between health status and the quality of housing, researchers and data collection agencies will need to re-think the artificial divisions between these two critical aspects of peoples' lives. 相似文献
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Karen A. Hudson-Edwards Mark G. Macklin Jerry R. Miller Paul J. Lechler 《Journal of Geochemical Exploration》2001,72(3)
The Río Pilcomayo rises on the Cerro Rico de Potosí precious metal-polymetallic tin deposits of Bolivia, and flows in a southeasterly direction for ca. 600 km to Bolivia's southern border with Argentina. Mining of the Potosí deposits has occurred continuously since 1545, generating large quantities of waste materials in the headwater of the basin. In addition, a tailings dam breach at the Porco mine in 1996 released an estimated 235 000 m3 of tailings and fluid into the upper reaches of the Río Pilaya, the largest tributary to the Pilcomayo.Concentrations of As, Sb, Cd, Cu, Pb, Hg, Ag, Tl and Zn in contemporary channel sediments upstream of the Pilaya confluence are significantly elevated above background values. Elevated levels appear to be associated with pyrite- and other sulphide mineral-bearing tailings materials transported more than 200 km downstream of the Potosí mines. Significant downstream declines in elemental concentrations occur within 15 km, and again between 150 and 200 km, from the mines. The initial decrease in concentrations is due to the rapid dilution of nearly pure tailings effluent released to the river from milling facilities near Potosí. The latter decrease results from a combination of geomorphic processes including the storage of sediment-borne metals within the channel bed and the influx of ‘clean’ sediment from several large tributaries. Downstream of the Pilaya confluence, concentrations of Cu, Pb, Hg and Zn are only slightly elevated above background values, and Ag, Cd, Sb and Tl cannot be distinguished from background levels. These data suggest that while the Porco tailings spill may have had a significant short-term impact on sediment and water quality along the lower reaches of the Río Pilcomayo, its longer-term impacts were limited. Metals stored and eroded from alluvial deposits of historical age in upstream reaches appear to be an important source of metals to the river today. An additional, and perhaps more significant source, is the release of tailings effluent to the river from modern milling operations. The transport of these contaminants downstream of Icla (203 km from Potosí) appears to be restricted by aggradational processes occurring in the vicinity of Puente Sucre. In addition, downstream of the confluence of the Río Pilaya, inputs of large amounts of ‘clean’ sediment have caused dilution of the metal contaminants. Data from other studies where similar geomorphic processes have occurred suggest that the metals in the upper Pilcomayo may eventually be moved downvalley as the aggradational processes are reversed and channel stabilisation occurs. Thus, the most significant impacts of metal contamination may not be realised in downstream areas for decades. 相似文献
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