Detailed <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of geologic events associated with the Mantos Blancos copper deposit,northern Chile

The ⁴⁰Ar/³⁹Ar geochronological method was applied to date magmatic and hydrothermal alteration events in the Mantos Blancos mining district in the Coastal Cordillera of northern Chile, allowing the distinction of two separate mineralization events. The Late Jurassic Mantos Blancos orebody, hosted in Jurassic volcanic rocks, is a magmatic-hydrothermal breccia-style Cu deposit. Two superimposed mineralization events have been recently proposed. The first event is accompanied by a phyllic hydrothermal alteration affecting a rhyolitic dome. The second mineralization event is related to the intrusion of bimodal stocks and sills inside the deposit. Because of the superposition of several magmatic and hydrothermal events, the obtained ⁴⁰Ar/³⁹Ar age data are complex; however, with a careful interpretation of the age spectra, it is possible to detect complex histories of successive emplacement, alteration, mineralization, and thermal resetting. The extrusion of Jurassic basic to intermediate volcanic rocks of the La Negra Formation is dated at 156.3 ± 1.4 Ma (2σ) using plagioclase from an andesitic lava flow. The first mineralization event and associated phyllic alteration affecting the rhyolitic dome occurred around 155–156 Ma. A younger bimodal intrusive event, supposed to be equivalent to the bimodal stock and sill system inside the deposit, is probably responsible for the second mineralization event dated at ca. 142 Ma. Other low-temperature alteration events have been dated on sericitized plagioclase at ca. 145–146, 125, and 101 Ma. This is the first time that two distinct mineralization events have been documented from radiometric data for a copper deposit in the metallogenic belt of the Coastal Cordillera of northern Chile. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Sedimentary evolution of a Late Pleistocene temperate red algal reef (Coralligène) on Rhodes,Greece: correlation with global sea‐level fluctuations

Autochthonous red algal structures known as coralligène de plateau occur in the modern warm‐temperate Mediterranean Sea at water depths from 20 to 120 m, but fossil counterparts are not so well‐known. This study describes, from an uplifted coastal section at Plimiri on the island of Rhodes, a 450 m long by 10 m thick Late Pleistocene red algal reef (Coralligène Facies), interpreted as being a coralligène de plateau, and its associated deposits. The Coralligène Facies, constructed mainly by Lithophyllum and Titanoderma, sits unconformably upon the Plio‐Pleistocene Rhodes Formation and is overlain by a Maerl Facies (2 m), a Mixed Siliciclastic‐Carbonate Facies (0·2 m) and an Aeolian Sand Facies (2·5 m). The three calcareous facies, of Heterozoan character, are correlated with established members in the Lindos Acropolis Formation in the north of the island, while the aeolian facies is assigned to the new Plimiri Aeolianite Formation. The palaeoenvironmental and genetic‐stratigraphic interpretations of these mixed siliciclastic‐carbonate temperate water deposits involved consideration of certain characteristics associated with siliciclastic shelf and tropical carbonate shelf models, such as vertical grain‐size trends and the stratigraphic position of zooxanthellate coral growths. Integration of these results with electron spin resonance dates of bivalve shells indicates that the Coralligène Facies was deposited during Marine Isotope Stage 6 to 5e transgressive event (ca 135 to 120 ka), in water depths of 20 to 50 m, and the overlying Maerl Facies was deposited during regression from Marine Isotope Stage 5e to 5d (ca 120 to 110 ka), at water depths of 25 to 40 m. The capping Aeolian Sand Facies, involving dual terrestrial subunits, is interpreted as having formed during each of the glacial intervals Marine Isotope Stages 4 (71 to 59 ka) and 2 (24 to 12 ka), with soil formation during the subsequent interglacial periods of Marine Isotope Stages 3 and 1, respectively. Accumulation rates of about 0·7 mm year^?1 are estimated for the Coralligène Facies and minimum accumulation rates of 0·2 mm year^?1 are estimated for the Maerl Facies. The existence of older red algal reefs in the Plimiri region during at least Marine Isotope Stages 7 (245 to 186 ka) and 9 (339 to 303 ka) is inferred from the occurrence of reworked coralligène‐type lithoclasts in the basal part of the section and from the electron spin resonance ages of transported bivalve shells.     

Cenozoic Eucla Basin and associated palaeovalleys,southern Australia — Climatic and tectonic influences on landscape evolution,sedimentation and heavy mineral accumulation

The Eucla Basin including the vast Nullarbor Plain lies on the margins of the Yilgarn, Musgrave and Gawler cratons in southern Australia and owes its distinctive landscape to a unique set of interactions between eustatic, climatic and tectonic processes over the last ~ 50 Ma. Understanding of the history of the basin and the palaeovalleys that drained from the surrounding cratons are important because they contain major mineral deposits, and the sediments derived from them contain remobilised gold, uranium, and heavy minerals. In particular, a remarkably preserved palaeoshoreline sequence along the north-eastern margin of the Eucla Basin is highly prospective for heavy mineral placer deposits. The record of marine, marginal marine, estuarine, fluvial and lacustrine environments, as constrained mainly by an extensive borehole dataset, reflects major depositional events during the Palaeocene–Early Eocene, Middle–Late Eocene, Oligocene–Early Miocene, Middle Miocene–Early Pliocene and Pliocene–Quaternary. These events reflect the key role of eustatic sea-level variation which, during highstands, inundated the craton margins, flooding palaeovalleys to up to 400 km inboard of the present coastline. However, a systematic eastward migration of the depocentre across the Eucla Basin during the Neogene, together with apparent flow reversals in a number of palaeovalley systems draining the Gawler Craton, suggest that the Eucla Basin has also been subject to differential vertical movements, expressed as a west-side up, east-side down tilting of ~ 100–200 m. This differential movement forms part of a broader north-down–southwest-up dynamic topographic tilting of the Australian continent associated with relatively fast (6–7 cm/yr) northward plate motion since fast spreading commenced in the Southern Ocean at ~ 43 Ma. We suggest that the evolving dynamic topography field has played a key role in facilitating development of placer deposits, largely through multistage, eastward reworking of near-shore sequences during highstand transgressive cycles on a progressively tilting platform under the influence of persistent westerly weather systems.     

A Pliocene mega-tsunami deposit and associated features in the Ranquil Formation,southern Chile

An exceptionally large tsunami affected the coastline of southern Chile during the Pliocene. Its backflow eroded coarse beach and coastal dune sediments and redistributed them over the continental shelf and slope. Sandstone dykes and sills injected from the base of the resulting hyperconcentrated flow into underlying cohesive muds, assisted in plucking up large blocks of the latter and incorporating them into the flow. Locally, the rip-up intraclasts were fragmented further by smaller-scale injections to form a distinct breccia of angular to rounded mudstone clasts within a medium to coarse sandstone matrix. Sandstone sills in places mimic normal sedimentary beds, complete with structures resembling inverse gradation, planar laminae, as well as ripple and trough cross-lamination. These were probably formed by internal sediment flow and shear stress as the semi-liquefied sand was forcefully injected into cracks. In borehole cores, such sills can easily be misinterpreted as normal sedimentary beds, which can have important implications for hydrocarbon exploration.     

Some types of small clinoforms in latest continental deposits

Some rare types of small clinoforms found in the latest continental deposits of lowland platform and mountain regions are described. The clinoforms are represented by prodelta deposits of mountain lakes, oblique-bedded horizons of floodplain alluvium of strongly meandering rivers, thick and short lenses of mountain alluvium, and alluvium horizons of great lowland rivers with oblique bedding grading into horizontal bedding. Such structures bear information on paleogeographic, morphological, and lithodynamic features of continental sedimentation.     

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.     

The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Fluid and source magma evolution of the Questa porphyry Mo deposit,New Mexico,USA

Combined fluid inclusion microthermometry and microanalysis by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) are used to constrain the hydrothermal processes forming a typical Climax-type porphyry Mo deposit. Molybdenum mineralisation at Questa occurred in two superimposed hydrothermal stages, a magmatic-hydrothermal breccia and later stockwork veining. In both stages, texturally earliest fluids were single-phase, of low salinity (~7 wt.% NaCl_equiv.) and intermediate-density. Upon decompression to ~300 bar, they boiled off a vapour phase, leaving behind a residual brine (up to 45 wt.% NaCl_equiv) at temperatures of ~420°C. The highest average Mo concentrations in this hot brine were ~500 μg/g, exceeding the Mo content of the intermediate-density input fluid by about an order of magnitude and reflecting pre-concentration of Mo by fluid phase separation prior to MoS₂ deposition from the brine. Molybdenum concentrations in brine inclusions, then, decrease down to 5 μg/g, recording Mo precipitation in response to cooling of the saline liquid to ~360°C. Molybdenite precipitation from a dense, residual and probably sulphide-depleted brine is proposed to explain the tabular shape of the ore body and the absence of Cu-Fe sulphides in contrast to the more common Cu-Mo deposits related to porphyry stocks. Cesium and Rb concentrations in the single-phase fluids of the breccia range from 2 to 8 and from 40 to 65 μg/g, respectively. In the stockwork veins, Cs and Rb concentrations are significantly higher (45–90 and 110–230 μg/g, respectively). Because Cs and Rb are incompatible and hydrothermally non-reactive elements, the systematic increase in their concentration requires two distinct pulses of fluid exsolution from a progressively more fractionated magma. By contrast, major element and ore metal concentrations of these two fluid pulses remain essentially constant. Mass balance calculations using fluid chemical data from LA-ICPMS suggest that at least 25 km³ of melt and 7 Gt of deep input fluid were necessary to provide the amount of Mo contained in the stockwork vein stage alone. While the absolute amounts of fluid and melt are uncertain, the well-constrained element ratios in the fluids together with empirical fluid/melt partition coefficients derived from the inclusion analyses suggest a high water content of the source melt of ~10%. In line with other circumstantial evidence, these results suggest that initial fluid exsolution may have occurred at a confining pressure exceeding 5 kbar. The source of the molybdenum-mineralising fluids probably was a particularly large magma chamber that crystallised and fractionated in the lower crust or at mid-crustal level, well below the shallow intrusions immediately underlying Questa and other porphyry molybdenum deposits. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.