Coastal Massachusetts pond development: edaphic,climatic, and sea level impacts since deglaciation

Kettle ponds in the Cape Cod National Seashore in southeastern Massachusetts differ in their evolution due to depth of the original ice block, the clay content of outwash in their drainage basins, and their siting in relation to geomorphic changes caused by sea-level rise, barrier beach formation, and saltmarsh development. Stratigraphic records of microfossil, carbon isotope, and sediment changes also document late-glacial and Holocene climatic changes.The ponds are separated into 3 groups, each of which follow different development scenarios. Group I ponds date from the late-glacial. They formed in clay-rich outwash, have perched aquifers and continuous lake sediment deposition. The earliest pollen and macrofossil assemblages in Group I pond sediments suggest tundra and spruce-willow parklands before 12 000 yr B.P., boreal forest between 12 000 and 10 500 yr B.P., bog/heath initiation and expansion during the Younger Dryas between 11 000 and 10 000 yr B.P., northern conifer forest between 10 500 and 9500 yr B.P., and establishment of the Cape oak and pitch pine barrens vegetation after 9500 yr B.P. Sedimentation rate changes suggest lowered freshwater levels between 9000 and 5000 yr B.P. caused by decreased precipitation on the Atlantic Coastal Plain. Lake sediment deposition began in the middle Holocene in Group II ponds which formed in clay-poor outwash. These ponds date from about 6000-5000 yr B.P. In these ponds sediment deposition began as sea level rose and the freshwater lens intersected the dry basins. The basal radiocarbon dates of these ponds and stable carbon isotope analyses of the pond sediments suggest a sea-level curve for Cape Cod Bay. Holocene topographic changes in upland and the landscape surrounding the ponds is reconstructed for this coastal area.Group III ponds in the late Holocene landscape of the Provincelands dunes originated as interdunal bogs about 1000 yr B.P. and became ponds more recently as water-levels increased. Peat formation in the Provincelands reflects climatic changes evident on both sides of the Atlantic region.This is the 8th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.     

Formic and acetic acids in atmospheric condensate in Wilmington,North Carolina

Formic and acetic acids occurred in atmospheric condensate with concentrations similar to rainwater collected in Wilmington, North Carolina, during the sampling period from June to October of 1990. Atmospheric concentrations of these acids (calculated from the condensate concentrations) were higher in continental versus maritime air masses. Concentrations of formic and acetic acids were correlated with each other in both condensate and air. Traffic was a source of acetic acid and of bisulfite to atmospheric condensate in this study.     

Mapping the Geographical Diffusion of a Finnish Smallpox Epidemic from Historical Population Records

Smallpox mortality from an early 19th century epidemic in Finland is mapped at the parish village level. First, geographically referenced historical materials are used to construct a map showing the spread of smallpox mortality among villages. Next, the diffusion of smallpox morbidity is simulated by computer for the same set of villages. These two maps are then compared. Results indicate that at this scale maps of mortality diffusion can show general trends but have no direct spatial correspondence to the underlying pattern of morbidity diffusion. Mortality maps cannot be used as a surrogate measure of infectious contact behavior at micro scales of analysis.     

Chemistry of alkali extraction of brown coals—I. Kinetics, characterisation and implications to coalification

Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state ¹³C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils.     

Consequences of explosive eruptions on small Solar System bodies: the case of the missing basalts on the aubrite parent body

Aubrite meteorites are composed of constituents which are almost certainly of igneous origin. If they were generated by the melting and fractionation of enstatite chondrite-like parental material, as seems very likely, then plagioclase-rich, basaltic complements to the aubrites should have formed. However, such materials are not known as individual meteorites, and the compositions of two plagioclase-silica clasts and one albite-silica-(diopside-anorthite) clast (probably an impact melt) in the Norton County aubrite breccia suggest that they are not the putative enstatite-plagioclase basalts. We propose a new mechanism that explains the absence of these materials, showing that the expansion of even very small amounts of volatiles present in a melt approaching the surface of a small, low-gravity body will be enough to disrupt the melt into a spray of droplets moving faster than the local escape velocity. This explosive volcanic process of melt removal requires larger melt volatile contents on larger bodies, and data on the solubility of volatiles in basaltic melts suggest that the process was limited to bodies smaller than about 100 km in radius.     

Charcoal analysis for paleoenvironmental interpretation: A chemical assay

Pollen and charcoal analysis of radiocarbon-dated sediment cores from Duck Pond in the Cape Cod National Seashore provide a continuous 12,000-yr vegetation and climate history of outer Cape Cod. A Picea-Hudsonia parkland and then a Picea-Pinus banksiana-Alnus crispa boreal forest association grew near the site between 12,000 and 10,000 yr B.P. This vegetation was replaced by a northern conifer forest of Pinus strobus-P. banksiana, and, subsequently, by a more mesophytic forest (Pinus strobus, Tsuga, Quercus, Fagus, Acer, Ulmus, Fraxinus, Ostrya) as the climate became warmer and wetter by 9500 yr B.P. By 9000 yr B.P. a Pinus rigida-Quercus association dominated the landscape. High charcoal frequencies from this and subsequent levels suggest that the pine barrens association developed during a warmer and drier climate that lasted from 9000 to about 5000 yr B.P. Increased percentages of Pinus strobus pollen indicate a return to moister and cooler conditions by about 3500 yr B.P. A doubled sedimentation rate, increased charcoal, and increased herb pollen suggest land disturbance near the pond before European settlement. These results suggest a rapid warming in the northeast in the early Holocene and support a hypothesis of a rapid sea level rise at that time. Comparison of the pollen results from Duck Pond with those from Rogers Lake, Connecticut, illustrates the importance of edaphic factors in determining the disturbance frequency and vegetation history of an area.     

Use of ritz vectors in wave propagation and foundation response

The accuracy of a numerical method is demonstrated for the dynamic analysis of large complex finite element systems in which the spatial distribution of the loading is constant. The method is based on the use of a special class of Ritz vectors which were previously proposed and can be generated with minimum numerical effort. The purpose of this paper is to extend the use of these vectors to the solution of wave propagation and foundation response problems. The method is applied to one-, twoand three-dimensional problems in order to illustrate the efficiency and accuracy of the technique. Unless it is necessary to evaluate the very high-frequency behaviour of a structural system, it is shown that a small number of Ritz vectors will produce excellent results. Therefore, they can be very effective in the solution of three-dimensional soil-structure systems subjected to earthquake loading.     

Tarawera 1886, New Zealand — A basaltic plinian fissure eruption

New Zealand's biggest and most destructive volcanic eruption of historical times was that of Tarawera in 1886. The resulting scoria fall has a dispersal very similar in extent to that of the Vesuvius A.D. 79 pumice fall and is one of the few known examples of a basaltic deposit of plinian type. A new estimate of the volume (2 km³) is significantly greater than previous estimates. The basalt came mainly from a 7-km length of fissure, and emission and exit velocity were fairly uniform along at least 4 km of it, this is one of the few documented examples of a plinian eruption from a fissure vent. Primary welding of the scoria fall resulted where the accumulation rate exceeded about 250 mm min⁻¹. A model of the eruption dynamics is proposed which leads to an estimate of 28 km for the height of the eruption cloud and implies a magma volatile fraction of 1.5–3%. Violent phreatic explosions occurred in the southwestern extension of the fissure across the Rotomahana geothermal field, and it is thought that some of the water responsible for the power of the plinian eruption came from this source, though its amount was not sufficient to turn the eruption into a phreatoplinian one.     

Oxygen isotope fractionation and disequilibrium displayed by some granulite facies rocks from the Fraser Range,Western Australia

The granulites of the Fraser Range are assumed to have formed in a carbon-rich fluid, and are generally devoid of hornblende, and lack obvious hydrous retrograde features. In these granulites, pyroxene, garnet, plagioclase and quartz are the minerals most likely to retain the oxygen isotope ratios fixed at an early stage of initial granulite metamorphism. Temperature estimates using these minerals commonly suggest that oxygen isotopic exchange ceased in the range 600 to 680°C. The peak metamorphic temperature was probably ～ 850°C as based on the stability fields of the coexisting minerals and some cation temperatures from coexisting pyroxenes in these rocks. Ilmenite may be slightly out of isotopic equilibrium with the other minerals. Thus, grains of quartz, feldspar, pyroxene and ilmenite have suffered considerable oxygen isotopic exchange during the retrogressive phase of the metamorphism, in spite of the fact that very little water was present in these granulites. The observed deviation from the peak metamorphic temperatures can be explained by essentially closed system solid-state diffusion (on at least a scale of centimetres) during slow cooling of the rocks from ~850 to 650°C, followed by more rapid cooling down to ～ 300°C. Such an explanation is not at variance with the radiometric data available for rocks from the area, which suggest that the latter phase could have involved uplift rates of ?0.5 mm/yr for a period of about 40 Ma. Wholerock δ¹⁸O values on non-quartzose mafic granulites, about 7.2%., fall within the range of basalts affected by seafloor weathering.