A comparison of shelf observation platforms for assimilation in an eddy-resolving ocean model

An assessment of the likely benefits of assimilating in situ temperature (T) and salinity (S) observations from repeat glider transects and surface velocity observations from high-frequency radar arrays into an eddy-resolving ocean model is presented. The deployment of new shelf observation platforms around Australia is being undertaken through the Australian Integrated Marine Observing System program. In this study, various options for an observing system along the coast of New South Wales, Australia, are assessed for their benefits to an ocean forecast and reanalysis system. The forecast system considered here uses ensemble optimal interpolation (EnOI) for data assimilation. Using error estimates from the EnOI scheme, estimates of the theoretical analysis errors are calculated for different observing systems that include a range of remotely sensed and in situ observations. The results demonstrate that if HF radar observations are assimilated along with the standard components of the global ocean observing system, the analysis errors are likely to reduce by as much as 80% for velocity and 60% for T, S and sea-level in the vicinity of the observations. Owing to the relatively short along-shore decorrelation length-scales for T and S near the shelf, the glider observations are likely to provide the forecast system with a more modest gain.     

Rosetta—one comet rendezvous and two asteroid fly-bys

One of the two planetary cornerstone missions of the European Space Agency is the Rosetta mission to comet 67P/Churyumov-Gerasimenko. Rosetta is a rendezvous mission with a comet nucleus, which combines an Orbiter with a Lander. It will monitor the evolution of the comet nucleus and the coma as a function of increasing and decreasing solar flux input along the comet’s pre- and post-perihelion orbit. Different instrumentations will be used in parallel, from multi-wavelength spectrometry to in-situ measurements of coma and nucleus composition and physical properties. Rosetta will go in orbit around the nucleus of its target comet 67P/Churyumov-Gerasimenko, when it is still far from the Sun and accompany the comet along its way to perihelion and beyond. In addition the Rosetta Lander Philae will land on the nucleus surface, before the comet is too active to permit such a landing (i.e. at around r = 3 AU) and examine the surface and subsurface composition of the comet nucleus as well as its physical properties.     

A Multi-Wavelength Simultaneous Study of the Composition of the Halley Family Comet 8P/Tuttle

We report on simultaneous optical and infrared observations of the Halley Family comet 8P/Tuttle performed with the ESO Very Large Telescope. Such multi-wavelength and coordinated observations are a good example of what can be done to support space missions. From high resolution optical spectroscopy of the CN (0,0) 388 nm and NH₂ (0,9,0) 610 nm bands using UVES at UT2 we determined ¹²C/¹³C = 90 ± 10 and ¹⁴N/¹⁵N = 150 ± 20 in CN and we derived a nuclear spin temperature of NH₃ of 29 ± 1 K. These values are similar to those found in Oort-Cloud and Jupiter Family comets. From low resolution long slit spectroscopy with FORS1 at UT2 we determined the CN, C₃ and C₂ production rates and the parent and daughter scale lengths up to 5.2 10⁵ km tailward. From high resolution IR spectroscopy with CRIRES at UT1 we measured simultaneously the production rates and mixing ratios of H₂O, HCN, C₂H₂, CH₄, C₂H₆, and CH₃OH.     

Editorial

In 2009 the Journal enters its 50^th year of publication –our "golden anniversary"! This is certainly good cause for celebrationand we will be doing just that in various ways throughout theyear. Volume 1 was published in February 1960. The very first paperby P.J. Wyllie and O.F. Tuttle on "The system CaO-CO₂-H₂O andthe origin of carbonatites" [J.Petrology 1:1-46] provided anidea for a special symposium at the 2009 Goldschmidt conference"Challenges to Our Volatile     

Breakdown of hydrous ringwoodite to pyroxene and spinelloid at high P and T and oxidizing conditions

To get deeper insight into the phase relations in the end-member system Fe₂SiO₄ and in the system (Fe, Mg)₂SiO₄ experiments were performed in a multi-anvil apparatus at 7 and 13 GPa and 1,000–1,200°C as a function of oxygen fugacity. The oxygen fugacity was varied using the solid oxygen buffer systems Fe/FeO, quartz–fayalite–magnetite, MtW and Ni/NiO. The run products were characterized by electron microprobe, Raman- and FTIR-spectroscopy, X-ray powder diffraction and transmission electron microscopy. At fO₂ corresponding to Ni/NiO Fe-ringwoodite transforms to ferrosilite and spinelloid according to the reaction: 9 Fe₂SiO₄ + O₂ = 6 FeSiO₃ + 5 Fe_2.40Si_0.60O₄. Refinement of site occupancies in combination with stoichiometric Fe³⁺ calculations show that 32% of the total Fe is incorporated as Fe³⁺ according to From the Rietveld refinement we identified spl as spinelloid III (isostructural with wadsleyite) and/or spinelloid V. As we used water in excess in the experiments the run products were also analyzed for structural water incorporation. Adding Mg to the system increases the stability field of ringwoodite to higher oxygen fugacity and the spinel structure seems to accept higher Fe³⁺ but also water concentrations that may be linked. At oxygen fugacity corresponding to MtW conditions similar phase relations in respect to the breakdown reaction in the Fe-end-member system were observed but with a strong fractionation of Fe into spl and Mg into coexisting cpx. Thus, through this strong fractionation it is possible to stabilize very Fe-rich wadsleyite with considerable Fe³⁺ concentrations even at an intermediate Fe–Mg bulk composition: assuming constant K _D independent on composition and a bulk composition of x _Fe = 0.44 this fractionation would stabilize spl with x _Fe = 0.72. Thus, spl could be a potential Fe³⁺ bearing phase at P–T conditions of the transition zone but because of the oxidizing conditions and the Fe-rich bulk composition needed one would expect it more in subduction zone environments than in the transition zone in senso stricto.

Die Altersfolge der primär ausgeschiedenen sulfidischen Mineralien in den oberschlesischen Zink- und Bleierzlagerstätten und die Bedeutung der Altersfolge der primär ausgeschiedenen Mineralien der Erzlagerstätten überhaupt

Ohne Zusammenfassung     

The Wadden Sea in transition - consequences of sea level rise

The impact of sea level rise (SLR) on the future morphological development of the Wadden Sea (North Sea) is investigated by means of extensive process-resolving numerical simulations. A new sediment and morphodynamic module was implemented in the well-established 3D circulation model GETM. A number of different validations are presented, ranging from an idealized 1D channel over a semi-idealized 2D Wadden Sea basin to a fully coupled realistic 40-year hindcast without morphological amplification of the Sylt-Rømøbight, a semi-enclosed subsystem of the Wadden Sea. Based on the results of the hindcast, four distinct future scenarios covering the period 2010–2100 are simulated. While these scenarios differ in the strength of SLR and wind forcing, they also account for an expected increase of tidal range over the coming century. The results of the future projections indicate a transition from a tidal-flat-dominated system toward a lagoon-like system, in which large fractions of the Sylt-Rømøbight will remain permanently covered by water. This has potentially dramatic implications for the unique ecosystem of the Wadden Sea. Although the simulations also predict an increased accumulation of sediment in the back-barrier basin, this accumulation is far too weak to compensate for the rise in mean sea level.     

Transfer functions simulating the coprecipitation of trace elements in unsaturated soils

Transfer functions describing the coprecipitation of various trace elements (TE; As, Cd, Co, Cu, Cr, Mo, Ni, Pb, Zn), precipitating with iron(oxihydr)oxides from an aqueous solution, were developed and implemented in the computer model ‘Seeper’. ‘Seeper’ was developed to predict the progression of the concentrations of inorganic pollutants in unsaturated soils underneath contaminated areas and to evaluate the prospective contamination of the groundwater. Transfer functions provide a straight and simple relation between the coprecipitation of TE and easy to obtain standard soil parameters, without excessive repercussions on the usability and computation time of the model. Laboratory experiments were conducted to quantify coprecipitation in solutions with pH values ranging from 5 to 12 and containing various iron and TE concentrations. For the examined TE, the transfer functions describe the coprecipitated fraction as a function of the pH value and the concentration ratio between precipitated iron and a TE. The transfer functions yielded a good prediction of cadmium, cobalt, copper, molybdenum, nickel, and zinc (R ² from 0.73 to 0.83). As for arsenic, chromium, and lead the correlation was not as good albeit a significant influence of precipitating iron on the mobility of these elements was observed and represented in the corresponding transfer functions.