Late Miocene to Pliocene stratigraphy of the Kura Basin,a subbasin of the South Caspian Basin: implications for the diachroneity of stage boundaries

Relative ages of late Cenozoic stratigraphy throughout the Caspian region are referenced to regional stages that are defined by changes in microfauna and associated extreme (>1000 m) variations in Caspian base level. However, the absolute ages of these stage boundaries may be significantly diachronous because many are based on the first occurrence of either transgressive or regressive facies, the temporal occurrence of which should depend on position within a basin. Here, we estimate the degree of diachroneity along the Akchagyl regional stage boundary within the Caspian basin system by presenting two late Miocene‐Pliocene aged measured sections, Sarica and Vashlovani, separated by 50 km and exposed within the Kura fold‐thrust belt in the interior of the Kura Basin. The Kura Basin is a western subbasin of the South Caspian Basin and the sections presented here are located >250 km from the modern Caspian coast. New U‐Pb detrital zircon ages from the Sarica section constrain the maximum depositional age for Productive Series strata, a lithostratigraphic package considered correlative with the 2–3 Myr‐long regional Eoakchagylian or Kimmerian stage that corresponds to a period of extremely low (>500 m below the modern level) Caspian base level. This new maximum depositional age from the Productive Series at Sarica of 2.5 ± 0.2 Ma indicates that the regionally extensive Akchagyl transgression, which ended the deposition of the Productive Series near the Caspian coast at 3.2 Ma, may have appeared a minimum of 0.5 Myr later in the northern interior of the Kura Basin than at the modern Caspian Sea coast. The results of this work have important implications for the tectonic and stratigraphic history of the region, suggesting that the initiation of the Plio‐Pleistocene Kura fold‐thrust belt may have not been as diachronous along strike as previously hypothesized. More generally, these results also provide a measure of the magnitude of diachroneity possible along sequence boundaries, particularly in isolated basins. Comparison of accumulation rates between units in the interior of the Kura subbasin and the South Caspian main basin suggest that extremely large variations in these rates within low‐stand deposits may be important in identifying the presence of subbasins in older stratigraphic packages.     

Resolving frontal structures: on the payoff using a less diffusive but computationally more expensive advection scheme

This article presents some advantages using a shape-preserving total variation diminishing (TVD) advection scheme in an ecosystem model. The superbee flux-limiter has been used to the second-order Lax–Wendroff advection scheme to make it TVD. We performed simulations for three shelf sea regions with different characteristic time scales, namely, the North Sea, the Barents Sea, and the Baltic Sea. To explore the advantages, we also performed reference runs with the much simpler and computationally cheaper upwind advection scheme. Frontal structures are much better resolved with the TVD scheme. The bottom salinity in the Baltic Sea stays at realistic values throughout the 10-year simulation with the TVD scheme, while with the upwind scheme, it drifts towards lower values and the permanent haline stratification in the Baltic is almost completely eroded within one seasonal cycle. Only when applying TVD for both the vertical and horizontal advections the model succeeded to preserve haline stratification in the decadal simulation. Lower trophic level patterns are far better reproduced with the TVD scheme, and for the estimated cod larval survival, the advantages seem to be even stronger. Simulations using the TVD-derived prey fields identified distinct regions such as Dogger Bank to favor potential larvae survival (PLS), which did not appear as particularly favorable in the upstream simulations. The TVD scheme needs about 25 % more time on the central processing unit (CPU) in case of a pure hydrodynamic setup with only two scalar state variables (Barents Sea application). The additional CPU time cost increases for a coupled physical–biological model application with a large number of state variables. However, this is more than compensated by all the advantages found, and, hence, we conclude that it is worthwhile to use the TVD scheme in our ecosystem model.

     

Speciation and role of iron in cloud droplets at the puy de Dôme station

Iron is the most abundant transition metal in the atmosphere and can play a significant role in cloudwater chemistry where its reactivity is closely related to the partitioning between Fe(II) and Fe(III). The objective of this work is to determine the total iron content and the iron speciation in a free tropospheric site, and to understand which factors influence these parameters. We collected 147 samples of cloudwater during 34 cloud events over a period of four years at the puy de Dôme summit. Besides iron we measured other chemical compounds, solar radiation, physico-chemical and meteorological parameters potentially connected with iron reactivity. The total iron concentrations ranged from 0.1 to 9.1 μM with the major frequency occurring at low levels. The pH and presence of organic complexants seem to be the most significant factors connected with total dissolved iron; while the iron oxidation state seems to be an independent factor. Light intensity, presence of complexants or oxidants (H₂O₂) do not influence the Fe(II)/Fe(Total) ratio, that was quite constant at about 0.75. This could be due to the potential redox that forces the Fe(II)-Fe(III) couple to the reduced form or, more probably to the complexation by Natural Organic Matter, that can stabilize iron in its reduced form and prevent further oxidation. Our field measurements did not show the diurnal cycle observed in surface water and predicted by models of atmospheric chemistry. This result prompts a more careful review of the role of iron and, by analogy, all the transition metals in atmospheric liquid phase, often over-estimated in the literature.     

Luminescence dating of Middle Pleistocene proglacial deposits from northern Switzerland: methodological aspects and stratigraphical conclusions

Optically stimulated luminescence (OSL) dating was applied to proglacial deposits from the Klettgau Valley in northern Switzerland, which is understood to record several phases of glaciation prior to the Last Interglacial. The aim was to provide an independent chronology for the different sedimentary units to understand better the complex depositional history of the region. This time range requires care when assessing the reliability of the luminescence protocols applied. Equivalent doses for fine‐ and coarse‐grain quartz remained below 300 Gy, while dose response curves for both fractions continued to display growth above 500 Gy. Dose recovery tests confirmed the ability of the single aliquot regenerative (SAR) protocol to recover laboratory doses of a similar size to burial doses, and isothermal decay measurements confirmed the stability of the quartz signal. Having passed rigorous testing criteria, quartz OSL ages of up to ～200 ka were considered reliable but significantly underestimated expected ages and prompt a reconsideration of earlier interpretations of the stratigraphy for this site. Rather than representing three separate glaciations, quartz luminescence ages instead suggest that these deposits record up to four independent ice advances during Marine Isotope Stage 6. For both single grain and single aliquot feldspar dating, it was not possible to separate the conflicting influences of anomalous fading and partial bleaching. However, uncorrected feldspar central age model ages were found to be in reasonable agreement with quartz age estimates, and suggest that feldspar ages may still offer useful additional information in this region.     

The Tajik Basin: A composite record of sedimentary basin evolution in response to tectonics in the Pamir

Investigation of a >6-km-thick succession of Cretaceous to Cenozoic sedimentary rocks in the Tajik Basin reveals that this depocentre consists of three stacked basin systems that are interpreted to reflect different mechanisms of subsidence associated with tectonics in the Pamir Mountains: a Lower to mid-Cretaceous succession, an Upper Cretaceous–Lower Eocene succession and an Eocene–Neogene succession. The Lower to mid-Cretaceous succession consists of fluvial deposits that were primarily derived from the Triassic Karakul–Mazar subduction–accretion complex in the northern Pamir. This succession is characterized by a convex-up (accelerating) subsidence curve, thickens towards the Pamir and is interpreted as a retroarc foreland basin system associated with northward subduction of Tethyan oceanic lithosphere. The Upper Cretaceous to early Eocene succession consists of fine-grained, marginal marine and sabkha deposits. The succession is characterized by a concave-up subsidence curve. Regionally extensive limestone beds in the succession are consistent with late stage thermal relaxation and relative sea-level rise following lithospheric extension, potentially in response to Tethyan slab rollback/foundering. The Upper Cretaceous–early Eocene succession is capped by a middle Eocene to early Oligocene (ca. 50–30 Ma) disconformity, which is interpreted to record the passage of a flexural forebulge. The disconformity is represented by a depositional hiatus, which is 10–30 Myr younger than estimates for the initiation of India–Asia collision and overlaps in age with the start of prograde metamorphism recorded in the Pamir gneiss domes. Overlying the disconformity, a >4-km-thick upper Eocene–Neogene succession displays a classic, coarsening upward unroofing sequence characterized by accelerating subsidence, which is interpreted as a retro-foreland basin associated with crustal thickening of the Pamir during India–Asia collision. Thus, the Tajik Basin provides an example of a long-lived composite basin in a retrowedge position that displays a sensitivity to plate margin processes. Subsidence, sediment accumulation and basin-forming mechanisms are influenced by subduction dynamics, including periods of slab-shallowing and retreat.     

Procedure of embedding biological action functions into the atmospheric transmittance

In order to perform calculations of biologically effective irradiance, the usual procedure is to modulate the ground-measured spectral solar irradiance with a specific biological action function. The inconvenience is that only a few meteorological stations worldwide are equipped to measure the spectral solar irradiance in the ultraviolet range. This motivates the search for a numerical substitute, which constitutes the subject of this report. An innovative approach based on generalized mean is used to infer the effective atmospheric transmittance. Its illustration resulted in a new parametric model for computing the biological dose under clear sky. The action spectrum for the growth response of plants, as a carrier of biological effects, is encapsulated into the atmospheric transmittance, leading to the calculation of the effective irradiance by simple algebra. The overall results indicate that the new parametric model performs accurately enough to be routinely used in practice. The procedure is general; therefore, it is described in detail to guide potential users in developing similar models incorporating other biological action spectra as needed. For speed-intensive applications, an executable file intended to run on any PC, which computes the effective irradiance with the proposed model, is provided.     

Landslide susceptibility assessment using the bivariate statistical analysis and the index of entropy in the Sibiciu Basin (Romania)

The Sibiciu Basin is located in Romania between the Buzău Mountains and the Buzau Subcarpathians (Curvature Carpathians and Subcarpathians). The geology of the basin consists of Paleogene flysch deposits represented by an alternation of sandstones, marls, clays and schists and Neogene deposits represented by marls, clays and sands. The area is affected by different types of landslides (shallow, medium-deep and deep-seated failures). In Romania, in the last decades, direct and indirect methods have been applied for landslide susceptibility assessment. The most utilized before 2000 were based on qualitative approaches. This study evaluates the landslide susceptibility in the Sibiciu Basin using a bivariate statistical analysis and an index of entropy. A landslide inventory map was prepared, and a susceptibility estimate was assessed based on the following parameters which influence the landslide occurrence: slope angle, slope aspect, curvature, lithology and land use. The landslide susceptibility map was divided into five classes showing very low to very high landslide susceptibility areas.     

Messinian sea level fall in the Dacic Basin (Eastern Paratethys): palaeogeographical implications from seismic sequence stratigraphy

The signature of the Mediterranean Messinian Salinity Crisis (MSC) in the Paratethys has received wide attention because of the inferred changes in connectivity and base level. In this article, we present sequence stratigraphic interpretations on a seismic transect across the western part of the semi-isolated Late Miocene–Pliocene Dacic Basin (Eastern Paratethys, Romania), chronologically constrained by biostratigraphic field observations and well data. They reveal significant sea level changes during the middle Pontian that are coeval with the MSC. These changes were most likely transmitted to the western Dacic Basin from the downstream Black Sea and controlled by the sill height of the interconnecting gateway. During the middle Pontian lowstand of the western Dacian Basin, sedimentation continued in a remnant ∼300 m deep lake with a positive water balance. Our observations show that the evolution of semi-isolated sedimentary basins is strongly dependent on the communication with other depositional realms through its control on base level and sediment supply.     

Impacts of cyclic hypoxia on reproductive and gene expression patterns in the grass shrimp: field versus laboratory comparison

Identification of organisms able to act as biological indicators of hypoxia exposure is important given the increasing frequency of hypoxic events worldwide. Grass shrimp, Palaemonetes pugio, are ubiquitous estuarine residents in the southeastern US, where they commonly experience cyclic hypoxia. We hypothesized that reproductive and gene expression patterns of grass shrimp in cyclic hypoxic field sites relative to normoxic sites would be similar to previous results from cyclic hypoxia laboratory experiments showing differential up- and down-regulation of hypoxia-responsive genes. There were few differences in gene expression of indigenous shrimp collected during summer from two Gulf of Mexico estuarine systems [East Bay, FL (EB) and Weeks Bay, AL (WB)], although down-regulation of the gene coding for vitellogenin-1 corresponded with a decreased relative fecundity and fewer ovigerous females at cyclic hypoxic field sites, suggesting an overall impact on reproduction. The gene expression profiles of grass shrimp caged for 7 days in field sites differed by estuary, but few hypoxia-responsive genes identified in laboratory studies were differentially expressed in field shrimp. Overall, genes coding for protein synthesis, protein degradation, carbohydrate and lipid metabolism and electron transport were mostly up-regulated in EB caged shrimp but generally down-regulated in WB caged shrimp and laboratory shrimp. Thus, caged grass shrimp from different bay systems exhibited profoundly different gene expression profiles. Such profiles may serve as sensitive bioindicators of differences in water quality, habitat quality or food resources among estuaries but are not effective as indicators of hypoxia exposure.     

Thunderstorm Hazard vulnerability for the Atlanta,Georgia metropolitan region

Most U.S. metropolitan regions have experienced urban “sprawl,” or the outward spreading of urban development from city centers. For cities lying in areas prone to severe weather, the sprawl phenomenon exposes greater numbers of developed areas and inhabitants to a variety of thunderstorm hazards. This study’s principal goal is to determine how urbanization growth patterns affect a region’s vulnerability to severe weather events. To assess how sprawl may impact vulnerability to tornadoes, hail, and convective wind events, an analysis examining potential loss may be utilized. This study employs two distinct approaches to examine how the Atlanta area’s rapid and extensive development during the latter half of the twentieth Century has affected its overall potential exposure to thunderstorm hazards. First, archived census data are used to estimate overall impacts from hypothetical significant tornado, nontornadic convective wind, and hail events occurring at different time periods throughout several locations in the Atlanta metropolitan region. Second, economic factors are integrated into the analysis, which assists in determining how these hypothetical severe event scenarios may have changed from a cost standpoint if they were to occur in 2006 as opposed to 1960.