Paleoproterozoic Crustal Evolution of the São Luís Craton, Brazil: Evidence from Zircon Geochronology and Sm-Nd Isotopes

The São Luís Craton, northern Brazil, is composed of a few granitoid suites and a metavolcano-sedimentary succession. New single zircon Pb evaporation ages and Nd isotope data, combined with other available information, show that the metavolcano-sedimentary succession developed from 2240 Ma to approximately 2200-2180 Ma from juvenile protoliths. The subduction-related calc-alkaline suites of granitoids, spatially associated with the metavolcano-sedimentary sequence, formed in an oceanic island arc setting between 2168-2147 Ma. Most of these granitoids are tonalitic and formed from juvenile, mantle- or oceanic plate-derived protoliths, whereas minor true granites are the product of the reworking of the juvenile island arc material. These arc-related successions represent an accretionary event around 2.20±0.05 Ga, which is coincident with one of the main periods of crustal growth in the South American Platform. This accretionary orogen has subsequently been involved in a collision episode, at ca. 2100-2080 Ma, which is mainly recorded in the nearby Gurupi Belt. The rock associations, inferred geological settings, and the crustal evolution detected in the São Luís Craton are similar to what is described in Paleoproterozoic domains of major geotectonic units of the South American Platform, such as part of the São Francisco Craton, southeastern Guyana Shield, and of the West African Craton.     

Atmospheric gravity wave propagation direction observed by airglow imaging in the South American sector

Airglow all sky imaging observation has been carried out in three different locations in south America, at Cachoeira Paulista (22.7°S, 45.0°W) in 1999, São João do Cariri (7.5°S, 36.5°W) in 2001 and Boa Vista (2.8°N, 60.7°W) in 2002. Comparing the atmospheric gravity wave characteristics retrieved from the image data for the three different sites and including a previous work at Alcântara (2.3°S, 44.5°W) carried out by Taylor et al. [1997. Journal of Geophysical Research 102 (D22) 26,283–26,299], we found that there is a preferential propagation direction, from the Continent to the Atlantic Ocean. The observed wave propagation directions reveal that a major part of the waves have their direction from Continent toward Ocean. The possible source of the wave generation is discussed.     

Color centers in topaz: comparison between neutron and gamma irradiation

Neutron- and gamma irradiation-induced paramagnetic centers in natural colorless topaz from four different Brazilian localities were studied by electron paramagnetic resonance (EPR) and optical absorption as a function of irradiation dose and thermal treatment. Gamma irradiation doses were applied up to 1,000 kGy with a dose rate of 15 kGy h⁻¹. For the neutron irradiation experiments, a neutron flux of 4 × 10¹² cm⁻² s⁻¹ was used with an integrated flux of up to 1 × 10¹⁸ cm⁻². From the experiments, it is concluded that brownish colors are induced by gamma-rays and may be associated with a single broad isotropic EPR line with g = 2.015(2). Both the EPR line and the related optical absorption band at 460 nm (2.7 eV) are lost during thermal treatments between 150 and 200°C. Fast neutrons create the paramagnetic peroxyl radicals O₂ ⁻ and the paramagnetic O⁻ hole centers. The O⁻ centers have the same thermal stability as the optical absorption band at 620 nm (2.0 eV). It is confirmed that the absorption due to the O⁻ center is responsible for the blue color in topaz. Both color centers and their absorption bands are discussed in the context of O⁻ bound small polarons.     

Sources of mud volcano fluids in the Gulf of Cadiz—indications for hydrothermal imprint

Mud volcanism in the Gulf of Cadiz occurs over a large area extending from the shelf to more than 3500 m water depth and is triggered by compressional stress along the European-African plate boundary, affecting a deeply faulted sedimentary sequence of locally more than 5 km thickness. The investigation of six active sites shows that mud volcano (MV) fluids, on average, are highly enriched in CH₄, Li, B, and Sr and depleted in Mg, K, and Br. The purity of the fluids is largely controlled by the intensity of upward directed flow. Flow rates could be constrained by numerical modelling and vary between <0.05 and 15 cm yr⁻¹. Application of δD-δ¹⁸O systematics identifies clay mineral dehydration, most likely within Mesozoic and Tertiary shales and marls, as the major source of fluids. Hence, Cl and Na in the pore fluids are mostly depleted below seawater values, following a general trend of dilution. However, deviations from this trend occur and are likely caused by the dissolution of halite in evaporitic deposits. Other secondary processes overprinting the original fluid composition may occur along the flow path, such as dissolution of anhydrite or gypsum and/or the formation of calcite and dolomite. Different sources of fluids are also indicated by variations in ⁸⁷Sr/⁸⁶Sr, which range from 0.7086 to 0.7099 at the different sites. Dehydration may be induced primarily by overburden and tectonic compression; however, very high concentrations of Li and B, specifically at Captain Arutyunov MV (CAMV) indicate additional leaching at temperatures above 150 °C, which could be explained by the injection of hot fluids along deep penetrating, major E-W strike-slip fault systems. This hypothesis is supported by the occurrence of generally thermogenic, but significantly CH₄-enriched, light volatile hydrocarbon gases at CAMV which cannot be explained by shallow microbial methanogenesis. Li and Li/B ratios from different types of hot and cold vents are used to infer that high temperature signals seem to be preserved at various cold vent locations and indicate a closer coupling of both systems in continental margin environments than outlined in previous studies.     

Newly discovered reefs in the southern Abrolhos Bank,Brazil: Anthropogenic impacts and urgent conservation needs

The Abrolhos Bank is an area of high ecological, socio-economic importance and harbour the richest and most-extensive coral reefs in the South Atlantic. Here we report the discovery of shallow (12–25 m depth) reef complex with ten large biogenic structures, intermediate between the typical mushroom-shaped pinnacles of the northern Abrolhos Bank (17°–18° S) and the small patch reefs found on the central/southern coast of the Espírito Santo State (19°–20° S). The newly discovered reefs harbour a relatively rich and abundant reef community, with 73 fish and 14 benthic cnidarian species, including endangered and commercially important ones. We discuss on urgent needs of properly mapping and understanding the ecological functioning of this reef system. Information provided here is a baseline for future impact evaluations, particularly considering the recent worst environmental disaster of Brazil from a dam collapse in Doce river that affected the region.     

Influence of allochthonous organic matter on bacterioplankton biomass and activity in a eutrophic,sub-tropical estuary

Heterotrophic bacterial and phytoplankton biomass, production, specific growth rates, and growth efficiencies were studied in the Northern region of the Cananéia–Iguape estuarine system, which has recently experienced an intense eutrophication due to anthropogenic causes. Two surveys were carried out during spring and neap tide periods of the dry season of 2005 and the rainy season of 2006. This region receives large freshwater inputs with organic seston and phosphate concentrations that reach as high as 1.0 mg l⁻¹ and 20.0 μM, respectively. Strong decreasing gradients of seston and dissolved inorganic nutrients were observed from the river/estuary boundary to the estuary/coastal interface. Gradients were also observed in phytoplankton and bacterial production rates. The production rates of phytoplankton were 5.6-fold higher (mean 8.5 μg C l⁻¹ h⁻¹) during the dry season. Primary production rates (PP) positively correlated with salinity and euphotic depth, indicating that phytoplankton productivity was light-limited. On the other hand, bacterial biomass (BB) and production rates (BP) were 1.9- and 3.7-fold higher, respectively, during the rainy season, with mean values of up to 40.4 μg C l⁻¹ and 7.9 μg C l⁻¹ h⁻¹, respectively. Despite such a high BP, bacterial abundance remained <2 × 10⁶ cells ml⁻¹, indicating that bacterial production and removal were coupled. Mean specific growth rates ranged between 0.9 and 5.5 d⁻¹. BP was inversely correlated with salinity and positively correlated with temperature, organic matter, exopolymer particles, and particulate-attached bacteria; this last accounted for as much as 89.6% of the total abundance. During the rainy season, BP was generally much higher than PP, and values of BP/PP > 20 were registered during high freshwater input, suggesting that under these conditions, bacterial activity was predominantly supported by allochthonous inputs of organic carbon. In addition, BB probably represented the main pathway for the synthesis of high-quality (low C:N) biomass that may have been available to the heterotrophic components of the plankton food web, particularly nanoheterotrophs.     

Geostatistical Data Integration Model for Contamination Assessment

Soil contamination assessments can be improved with new methods aimed at the accurate estimation of the volume and extension of contaminated soil to be remediated. Geostatistical models that use secondary information to characterize soil contamination are incorporated into a new integration model to provide accurate three-dimensional maps. The proposed integration model is based on a stochastic inversion approach and uses sequential indicator simulation. A two-dimensional reference image representing the areal extension of the contamination is combined with local measurements of contamination in the vertical direction, to render a three-dimensional contamination map. To demonstrate how well the integration model performs, the case study presented focuses on geophysical data and how it can be integrated with soil contamination measurements to improve the characterization of a contaminated site. The results show that the model reproduces successfully the reference image thus providing an accurate three-dimensional contamination map.     

Impacts of wildfire and post-fire land management on hydrological and sediment processes in a humid Mediterranean headwater catchment

The extensive afforestation of the Mediterranean rim of Europe in recent decades has increased the number of wildfire disturbances on hydrological and sediment processes, but the impacts on headwater catchments is still poorly understood, especially when compared with the previous agricultural landscape. This work monitored an agroforestry catchment in the north-western Iberian Peninsula, with plantation forests mixed with traditional agriculture using soil conservation practices, for one year before the fire and for three years afterwards, during which period the burnt area was ploughed and reforested. During this period, continuous data was collected for meteorology, streamflow and sediment concentration at the outlet, erosion features were mapped and measured after major rainfall events, and channel sediment dynamics were monitored downstream from the agricultural and the burnt forest area. Data from 202 rainfall events with over 10 mm was analysed in detail. Results show that the fire led to a notable impact on sediment processes during the first two post-fire years, but not on streamflow processes; this despite the small size of the burnt area (10% of the catchment) and the occurrence of a severe drought in the first year after the fire. During this period, soil loss at the burnt forest slopes was much larger than that at most traditionally managed fields, and, ultimately, led to sediment exhaustion. At the catchment scale, storm characteristics were the dominant factor behind streamflow and sediment yield both before and after the fire. However, the data indicated a shift from detachment-limited sediment yield before the fire, to transport-limited sediment yield afterwards, with important increases in streamflow sediment concentration. This indicates that even small fires can temporarily change sediment processes in agroforestry catchments, with potential negative consequences for downstream water quality.     

Ionization of the earth’s atmosphere by solar and galactic cosmic rays

A brief review of the research of atmospheric effects of cosmic rays is presented. Numerical models are discussed, that are capable to compute the cosmic ray induced ionization at a given location and time. Intercomparison of the models, as well as comparison with fragmentary direct measurements of the atmospheric ionization, validates their applicability for the entire atmosphere and the whole range of the solar activity level variations. The effect of sporadic solar energetic particle events is shown to be limited on the global scale, even for the most severe event, but can be very strong locally in polar regions, affecting the physical-chemical properties of the upper atmosphere, especially at high altitudes. Thus, a new methodology is presented to study cosmic ray induced ionization of the atmosphere in full detail using realistic numerical models calibrated to direct observations.     

Diffuse instabilities with transition to localization in loose granular materials

This paper is concerned with diffuse and other ensuing failure modes in geomaterials when tested under homogeneous states of shearing in various loading programs and drainage conditions. Material instability is indeed the basic property that accounts for the instability of an initially homogeneous deformation field leading to diffuse failure and strain localization in geomaterials. The former is normally characterized by a runaway type of failure accompanied with a sudden and violent collapse of the material in the absence of any localization phenomena. Against this backdrop, we present a brief overview of material instability in elastoplastic solids where one finds a rich source of theoretical concepts including bifurcation, strain localization, diffuse failure and second‐order work, as well as a considerable body of experiments. Some compelling laboratory experimental studies of material instability with focus to diffuse failure are then presented and interpreted based on the second‐order work. Finally, various material instability analyses using an elastoplastic constitutive and a general finite element analysis of the above‐mentioned laboratory experimental tests are presented as a boundary value problem. It is shown that instability can be captured from otherwise uniform stress, density and hydraulic states, whereas uniform deviatoric loads are being applied on the external boundaries of a specimen. Although the numerical simulations reproduce well the laboratory experimental results, they also highlight the hierarchy of failure modes where localization phenomena emerge in the post‐bifurcation regime as a result of a degradation of homogeneity starting from a diffuse mode signalled by a zero second‐order work. Copyright © 2012 John Wiley & Sons, Ltd.