南海海域新生代沉积盆地构造演化的动力学特征及其油气资源

通过对构造环境、地球物理场特征、盆地生储盖层发育等方面对比研究, 讨论南海南北部沉积盆地的油气资源分布特征, 为在南海进行油气勘查指明方向.目前油气勘探实践证明, 南海南部的油气资源比北部丰富, 究其原因, 南海北部为被动大陆边缘, 张性沉积盆地的烃源岩体积较小, 而南部挤压环境下形成的沉积盆地的烃源岩体积大; 北部的地热流较南部小, 因此地温梯度也较小, 如北部陆架上的珠江口盆地的热流值在5 3~ 87mW /m2之间, 平均6 7mW /m2, 而南海南部大曾母盆地平均热流值达97mW /m2, 最大值达130mW /m2, 故南部边缘烃源岩的成熟度比北部高; 由于南部边缘处于挤压构造环境, 因此在沉积盆地中形成了许多挤压构造, 而北部边缘一直处于张性构造环境, 形成的构造较少且较小; 同时, 南部边缘沉积盆地中, 烃源岩生烃与构造形成在时间上搭配较好.因此, 在南海南部边缘沉积盆地中形成了许多大型油气田, 而南海北部边缘沉积盆地中, 大型油气田较少, 中小型油气田较多.这就是为什么南海南部边缘的油气资源比北部丰富的地质原因.      

Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to sati...     

Distribution of nutrients and eutrophication assessment in the Bohai Sea of China

Water samples were collected in 120 stations in the Bohai Sea of China to analyze the distribution of dissolved nutrients and assess the degree of eutrophication in August 2002. The result shows that the average concentration of DIN increased and the PO4-P concentration sharply decreased compared to the previous data of corresponding period. The high concentrations of DIN and PO4-P occurred in coastal waters, especially in the bays and some river estuaries, while the high concentrations of SiO3-Si in the surface and middle depth occurred in the central area of the Bohai Sea. The average ratio of DIN/ PO4-P was much higher than the Redfield Ratio (16:1). Apparently, PO4-P was one of the limiting nutrient for phytoplankton growing in the sea. The average concentrations of DON and DOP were higher than their inorganic forms. The results of eutrophication assessment show that 22.1% of all stations were classified as violating the concentration levels of the National Seawater Quality Standard (GB 3097-1997) for DIN and only 3.9% for PO4-P. The average eutrophication index in the overall area was 0.21±0.22 and the high values occurred in Bohai Bay, Liaodong Bay and near the Yellow River estuary. This means that the state of eutrophication was generally mesotrophic in the Bohai Sea, but relatively worse in the bays, especially some river estuaries.     

Environmental anomalies in the northeastern East China Sea during the last 3 000 years:implications for El Nio activity in the Holocene

To reconstruct the productivity changes for the last 10 500 a in the northeastern East China Sea (ECS),biogenic compounds (such as carbonate,organic carbon and opal),marine micropaleontological fossils (planktonic foraminifera,benthic foraminifera,radiolarian and silicoflagellate) and the compositional characters of benthic foraminifera fauna analyses were carried out on a sediment core DOC082 obtained from the western slope of Okinawa Trough (29°13.93'N,128°08.53'E;1 128 m water depth).The long-term changes of biogenic and micropaleontological proxies display some similarities through the last 10 500 a,which show three different phases:lower values are recorded during the early and middle Holocene (before about 4 000 a BP),followed by an abrupt and remarkable increase at about 4 000 a BP,the late Holocene (after about 3 000 a BP) is characterized by continuously high values.The multi-proxy data of paleoproductivity and percents of benthic foraminifera genera (Uvigerina and Bulimina) show that during the early and middle Holocene (10 500-4 000 a BP) productivity was relatively low with a sudden and distinct increase at about 4 000 a BP,and the late Holocene (3 400-0 a BP) is marked by significantly higher productivity.Also,the radiolarian-based sea surface temperature (SST) records reveal a distinct decline in SST in the late Holocene after 3 200 a BP,very different from the early and middle Holocene.For the last 3 000 a,the enhanced biological productivity and distinctly lower SST indicate a major change of oceanographic conditions in the northeastern ECS.These marine environmental anomalies are consistent with other paleoclimatic records for the late Holocene in the Chinese continent and its surrounding regions.After analyzing the mechanisms of modern productivity and SST changes in the northeastern ECS,and based on the climatic anomalies in the Chinese continent and variations in the Kuroshio Current during modern El Nio periods,we suggest that the anomalous environmental conditions in the northeastern ECS may imply intensified El Nio activity during the late Holocene.     

冲绳海槽千年来陆源物质输入历史与东亚季风变迁

为解决近1000年以来东海沿岸地区气候演化及其对南冲绳海槽陆源物质输入的影响, 对取自南冲绳海槽的MD05-2908孔上部(0~810cm) 共78份孢粉样品和199份有机碳同位素样品进行了分析.结果显示, 近1000年以来南冲绳海槽陆源物质输入存在着显著波动, 其中1100~1040aBP、960~880aBP和800~480aBP期间, 陆源物质输入比例增加; 1040~960aBP和480~230aBP期间, 陆源物质输入比例减少.将陆源物质输入指标与陕西佛爷洞δ13C含量记录对比分析, 发现陆源物质输入比例变化与季风的变化密切相关.当夏季风减弱时, 导致降雨带长时间集中在南部地区, 增强的降雨量提高了风化剥蚀以及沉积物向海洋搬运的能力, 使得陆源物质供应量增加.      

南海晚渐新世滑塌沉积指示的地质构造事件

南海北部ODP1148站晚渐新世至早中新世沉积以滑塌堆积和长时间沉积缺失为主要特征.由构造活动引起的沉积间断始于渐新世中期28.5 Ma至早中新世23 Ma左右结束.主间断面位于25 Ma, 亦即滑塌沉积层的底界.4次沉积间断总共造成至少3 Ma沉积记录的缺失.综合岩性、古生物年代测定、地球化学等分析结果, 表明南海晚渐新世的海底扩张模式呈多次跳跃式, 并以“25 Ma事件”为型变高峰.这一系列构造活动是欧亚、澳大利亚、菲律宾-太平洋板块相互作用的结果, 直接导致南海向前期裂谷更发育, 红河大断裂左擦拉张更强的南部扩张的转型.1148站的滑塌沉积为此次南海扩张转型提供了直接的证据.      

Mechanism and Modes of Microbial Minerogenesis of Polymetallic Nodules on the Ocean Floor

This paper presents a quantitative analysis of the relations of the occurrence of polymetallic nodules with the geochemical actions of microbes in the seawater, pore water and sediments at the bottom of the eastern Pacific Ocean basin. Emphasis is laid on the relations of the activity intensity and biochemical transformation rate of aerobic bacteria (iron bacteria, Thiobacillus thioparus, halobacteria and manganese-oxidizing bacteria) and anaerobic bacteria (sulphate-reducing bacteria, denitrifying bacteria, Thiobacillus denitrificans) with mineralization. The experimental research on the migration and accumulation of ore-forming elements caused by microbial and chemical actions shows that the microbes have changed the conditions of oxidation and reduction in the system, and their effect on the element precipitation is much stronger than the chemical actions and accelerates the enrichment of Fe and Mn. It demonstrates that the microbes can change the environment to promote the accumulation of ore-formin     

苏皖地块－－特提斯演化阶段独立的构造单元

基于苏皖地区的基底性质、晚元古代-中生代特征的沉积-火成建造、区域成矿和构造专属性，结合古地磁资料，提出了苏皖地块是特提斯演化阶段独立的构造单元的观点。它以苏鲁洋与华北克拉通间隔。震旦纪-早古生代的建造及变形特征与扬子克拉通有差异。石炭纪末和早二叠世的沉积和生物群表明它当时是古特提斯洋域里的一个中间地块，此时它已独立于扬子克拉通之外。三叠纪时苏鲁洋发生过大规模的消减但未闭合，因而苏皖地块的晚三叠世植物群与扬子克拉通有较明显区别。苏皖地块与华北克拉通（指胶辽地块）碰撞可能发生在早白垩世，该地区超高压变质岩的折返与之有关。之后，苏皖地块成为亚洲大陆雏形的一部分。     

南海东沙海域天然气水合物地震数据多次压制及速度特征

多次波衰减是海洋地震数据处理中的一个关键问题。东沙海域多次波极其发育,由于地形的急剧变化和地质条件的影响,多次波变形严重(不符合双曲线规律)。采用常规的处理方法效果并不明显,并可能造成成果剖面上出现明显的多次压制痕迹,很难达到保幅处理。针对此区多次波的特点,提出一种频率分离的方法将数据分离后再进行不同处理,可以很好地解决多次波的压制并突出有效波;在没有有效反射的位置,剖面的背景噪音也更符合视觉习惯;更重要的是,处理中没有频率损失,处理结果更和谐。另外,叠前偏移处理技术的运用可以使含水合物地层的接触关系、反射特征更清楚。叠前时间偏移所建立的速度模型也能够表现含水合物地层、BSR与含游离气层的相对速度关系。     

新生代亚洲形变与海陆相互作用

在现今各个大陆中, 亚洲经历的新生代形变最强. 白垩纪到老第三纪时的亚洲大陆, 不仅面积较今为小, 而且形态偏瘦"; 自从始新世印度与亚洲碰撞之后, 亚洲的面积与高度急剧增大. 随着青藏高原隆升和边缘海的张裂, 东亚原来西倾的地势发生倒转, 形成了从大陆中央隆升区向周围辐射的亚洲大河流系. 亚洲隆升有可能是北极冰盖形成与发展的重要因素, 因为隆升不仅改变大气环流、加剧风化作用, 而且还使西伯利亚河系改向北流, 通过注入北冰洋的淡水促使海水结冰、导致冰盖形成. 新生代亚洲形变, 也使得亚洲季风系统在早中新世形成, 又在约8 Ma与约3 Ma时强化. 同时, 西太平洋边缘海系列的形成, 也改变了亚洲大陆与太平洋之间的物质与能量的交换. 流经边缘海的太平洋西部边界流, 对于洋面升降和构造运动极为敏感, 在冰期低海面时边界流位于边缘海之外, 使大洋输向大陆的热量和水分大为减少. 今天, 亚洲与太平洋之间的能流与物流最为活跃, 可惜亚洲在全球气候环境演变中的重要性至今未能获得学术界的充分认识.