Anatomy and facies distribution of terminal lobes in ephemeral fluvial successions: Jurassic Tordillo Formation,Neuquén Basin,Argentina

In terminal fluvial-fan systems, characteristic proximal to distal variations in sedimentary architectures are recognized to arise from progressive downstream loss of water discharge related to both infiltration and evaporation. This work aims to elucidate downstream trends in facies and architecture across the medial and distal zones of terminal-fan systems, which record transitions from deposits of channel elements to lobe-like and sheet-like elements. This is achieved via a detailed characterization of ancient ephemeral fluvial deposits of the well-exposed Kimmeridgian Tordillo Formation (Neuquén Basin, Argentina). The fine sand-prone and silt-prone succession associated with the medial to distal sectors of the system has been studied to understand relationships between depositional processes and resulting architectures. Facies and architectural-element analyses, and quantification of resulting sedimentological data at multiple scales, have been undertaken to characterize sedimentary facies, facies transitions, bed types, architectural elements and larger-scale architectural styles. Eight bed types with distinct internal facies transitions are defined and interpreted in terms of different types of flood events. Channelized and non-channelized architectural elements are defined based on their constituent bed types and their external geometry. The most common elements are terminal lobes, which are composite bodies within which largely unconfined sandy deposits are stacked in a compensational manner; a hierarchical arrangement of internal components is recognized. Proximal feeder-channel avulsion events likely controlled the evolution of terminal-lobe elements and their spatiotemporal shifts. Stratigraphic relations between architectural elements record system-wide trends, whereby a proximal sector dominated by channel elements passes downstream via a gradational transition to a medial sector dominated by sandy terminal-lobe elements, which in turn passes further downstream to a distal sector dominated by silty terminal lobe-margin and fringing deposits. This work enhances current understanding of the stratigraphic record of terminal fluvial systems at multiple scales, and provides insight that can be applied to predict the facies and architectural complexity of terminal fluvial successions.     

Intraslab seismicity and thermal stress in the subducted Cocos plate beneath central Mexico

We present a model of the subducting Cocos slab beneath Central Mexico, that provides an explanation for stresses causing the occurrence of the majority of the intraslab earthquakes which are concentrated in a long flat segment. Based on the recently developed thermal models for the Central Mexico subduction zone, the thermal stresses due to non-uniform temperature contrast in the subducting slab are calculated using a finite element approach. The slab is considered purely elastic but due to high temperature at its bottom the behavior is considered as ductile creep. The calculation results show a  20 km slab core characterized by a tensional state of stress with stresses up to 70 MPa. On the other hand, the top of the slab experiences high compressive thermal stresses up to 110 MPa, depending on the elastic constants used and location along the flat part of the subducting plate. These compressive stresses at the top of the slab are not consistent with the exclusive normal fault intraslab earthquakes, and two different sources of stress are proposed.

The trenchward migration of the Mexican volcanic arc for the last 7 Ma indicates an increase of the slab dip through time. This observation suggests that the gravity torque might exceed the suction torque. Considering the flat slab as an embedded plate subject to an applied clockwise net torque of 0.5 × 10¹⁶–1.5 × 10¹⁶ N m, the upper half would exhibit tensional stresses of 40–110 MPa that can actually balance the compressive thermally induced stresses.

An alternative stress source might come from the slab pull force caused by the slab positive density anomaly. Based on our density anomaly estimations (75 ± 20 kg/m³), a 350 km slab length, dipping at 20° into the asthenosphere, induces a slab pull force of 1.7 × 10¹²–4.6 × 10¹² N m. This force produces a tensional stress of 41–114 MPa, sufficient to balance the compressive thermal stresses at the top of the flat slab.

The linear superposition of the thermally and torque or slab pull induced stresses shows tensile stresses up to 60–180 MPa inside the flat slab core. Also, our results suggest that the majority of the intraslab earthquakes inside the flat slab are situated where the resultant stresses are larger than 40–80 MPa.

This study provides a reasonable explanation for the existence of exclusively normal fault intraslab earthquakes in the flat slab beneath Central Mexico, and also it shows that thermal stresses due to non-uniform reheating of subducting slabs play a considerable role in the total stress field.     

Spectroscopic and photometric observations of symbiotic nova PU Vul during 2009–2016

A new set of low-resolution spectral and UBVJHKL-photometric observations of the symbiotic nova PU Vul is presented. The binary has been evolving after its symbiotic nova outburst in 1977 and now it is in the nebular stage. It is found that the third orbital cycle(after 1977) was characterized by great changes in associated light curves. Now, PU Vul exhibits a sine-wave shape in all the light curves(with an amplitude in the U band of about 0.7 mag), which is typical for symbiotic stars in the quiescent state. Brightness variability due to pulsations of the cool component is now clearly visible in the VRI light curves. The amplitude of the pulsations increases from 0.5 mag in the V band to 0.8 mag in the I band. These two types of variability, as well as a very slow change in the physical parameters of the hot component due to evolution after the outburst of 1977, influence the spectral energy distribution(SED)of the system. The variability of emission lines is highly complex. Only hydrogen line fluxes vary with orbital phase. An important feature of the third orbital cycle is the first emergence of the OVI, 6828  Raman scattering line. We determine the temperature of the hot component by means of the Zanstra method applied to the He II, 4686  line. Our estimate is about 150 000 K for the spectrum obtained near orbital maximum in 2014. The VO spectral index derived near pulsation minimum corresponds to M6 spectral class for the cool component of PU Vul.     

Characterization of the proteinaceous matter in marine aerosols

Marine aerosols play a dominant role in the transfer of oceanic material to the atmosphere. Most marine aerosol originates when air bubbles burst at the sea surface ejecting material from the sea surface microlayer and bubble surface layers into the air. Concentrations of chemical compounds in these surface layers often differ from their concentrations in bulk water. We examined the enrichment of aerosols with proteinaceous matter and attempted to characterize the physical nature and sources of this matter. We measured concentrations of dissolved free (DFAA), dissolved combined (DCAA), and particulate (PAA) amino acids, transparent stainable particles (TSP), and bacteria and virus-like particles as carriers of protein, in natural and simulated aerosols. We also evaluated D/L ratios certain amino acids in all amino acid fractions.DFAA and DCAA enriched the aerosols we sampled by 1.2–20 times compared to bulk seawater; PAA enrichment was usually higher (up to 50-fold). Aerosols contained particles typical of seawater, e.g., microorganisms, organic debris, inorganic particles with adsorbed organic matter, but also a large number of semitransparent gel-like particles, which all contained amino acids. Some of these particles were probably scavenged from bulk water, but new particles produced as bubbles burst at the surface comprised at least 10% of total proteinaceous matter in the aerosol. D/L ratios of certain amino acid suggested that the particles were most likely made from dissolved polymers secreted by phytoplankton that were concentrated on bubble surfaces and in the microlayer. Examination with Alcian Blue (a dye that targets carbohydrates) and Coomassie Blue (a dye that targets proteins) showed that most TSP in the aerosols contained both proteins and polysaccharides. Microorganisms enriched the aerosols by up to two orders of magnitude, but contributed less than 4% to the total protein pool.     

Radar and optical observations and physical modeling of triple near-Earth Asteroid (136617) 1994 CC

We report radar, photometric, and spectroscopic observations of near-Earth Asteroid (136617) 1994 CC. The radar measurements were obtained at Goldstone (8560 MHz, 3.5 cm) and Arecibo (2380 MHz, 12.6 cm) on 9 days following the asteroid’s approach within 0.0168 AU on June 10, 2009. 1994 CC was also observed with the Panchromatic Robotic Optical Monitoring and Polarimetry Telescopes (PROMPT) on May 21 and June 1-3. Visible-wavelength spectroscopy was obtained with the 5-m Hale telescope at Palomar on August 25. Delay-Doppler radar images reveal that 1994 CC is a triple system; along with (153591) 2001 SN263, this is only the second confirmed triple in the near-Earth population. Photometry obtained with PROMPT yields a rotation period for the primary P = 2.38860 ± 0.00009 h and a lightcurve amplitude of ∼0.1 mag suggesting a shape with low elongation. Hale telescope spectroscopy indicates that 1994 CC is an Sq-class object. Delay-Doppler radar images and shape modeling reveal that the primary has an effective diameter of 0.62 ± 0.06 km, low pole-on elongation, few obvious surface features, and a prominent equatorial ridge and sloped hemispheres that closely resemble those seen on the primary of binary near-Earth Asteroid (66391) 1999 KW4. Detailed orbit fitting reported separately by Fang et al. (Fang, J., Margot, J.-L., Brozovic, M., Nolan, M.C., Benner, L.A.M., Taylor, P.A. [2011]. Astron. J. 141, 154-168) gives a mass of the primary of 2.6 × 10¹¹ kg that, coupled with the effective diameter, yields a bulk density of 2.1 ± 0.6 g cm⁻³. The images constrain the diameters of the inner and outer satellites to be 113 ± 30 m and 80 ± 30 m, respectively. The inner satellite has a semimajor axis of ∼1.7 km (∼5.5 primary radii), an orbital period of ∼30 h, and its Doppler dispersion suggests relatively slow rotation, 26 ± 12 h, consistent with spin-orbit lock. The outer satellite has an orbital period of ∼9 days and a rotation period of 14 ± 7 h, establishing that the rotation is not spin-orbit locked. Among all binary and triple systems observed by radar, at least 25% (7/28) have a satellite that rotates more rapidly than its orbital period. This suggests that asynchronous configurations with P_rotation < P_orbital are relatively common among multiple systems in the near-Earth population. 1994 CC’s outer satellite has an observed maximum separation from the primary of ∼5.7 km (∼18.4 primary radii) that is the largest separation relative to primary radius seen to date among all 36 known binary and triple NEA systems. 1994 CC, (153591) 2001 SN263, and 1998 ST27 are the only triple and binary systems known with satellite separations >10 primary radii, suggesting either a detection bias, or that such widely-separated satellites are relatively uncommon in NEA multiple systems.     

Évolution pression–température des amphibolites de la zone axiale au cours du métamorphisme hercynien des Pyrénées orientales

Thin levels of amphibolites from the Canigou, Albères and Cap de Creus massifs have been studied in order to investigate their pressure and temperature evolution during time. P and T values have been calculated using the amphibole–plagioclase–quartz thermo-barometer. Si, Al, Mg and Fe of zoned amphiboles have been analysed from core to rim by microprobe. By combining the results obtained from several (or different) crystals, P–T–t paths have been determined using the amphibole-plagioclase-quartz equilibriums. In the Canigou Massif, the amphibolites have recorded anti-clockwise P–T–t paths around a peak of metamorphism located at about 650?°C–6.1 kbar, whereas in the Albères Massif, the calculated P–T–t paths of amphibolites near the paragneisses are retrograde only, from 600?°C–5 kbar to 450?°C–2.5 kbar, but one cummingtonite-bearing amphibolite has also recorded an anti-clockwise evolution around 650?°C–4.5 kbar. The retrograde P–T–t paths recorded for amphibolites from the ‘Cap de Creus’ Massif are retrograde only, from 650?°C–6 kbar and 400?°C–1 kbar. To cite this article: C. Triboulet et al., C. R. Geoscience 337 (2005).     

Thermal behavior of ferric selenite hydrates (Fe2(SeO3)3·3H2O,Fe2(SeO3)3·5H2O) and the water content in the natural ferric selenite mandarinoite

Any progress in our understanding of low-temperature mineral assemblages and of quantitative physico-chemical modeling of stability conditions of mineral phases, especially those containing toxic elements like selenium, strongly depends on the knowledge of structural and thermodynamic properties of coexisting mineral phases. Interrelation of crystal chemistry/structure and thermodynamic properties of selenium-containing minerals is not systematically studied so far and thus any essential generalization might be difficult, inaccurate or even impossible and erroneous. Disagreement even exists regarding the crystal chemistry of some natural and synthetic selenium-containing phases. Hence, a systematic study was performed by synthesizing ferric selenite hydrates and subsequent thermal analysis to examine the thermal stability of synthetic analogues of the natural hydrous ferric selenite mandarinoite and its dehydration and dissociation to unravel controversial issues regarding the crystal chemistry. Dehydration of synthesized analogues of mandarinoite starts at 56–87?°C and ends at 226–237?°C. The dehydration happens in two stages and two possible schemes of dehydration exist: (a) mandarinoite loses three molecules of water in the first stage of the dehydration (up to 180?°C) and the remaining two molecules of water will be lost in the second stage (>180?°C) or (b) four molecules of water will be lost in the first stage up to 180?°C and the last molecule of water will be lost at a temperature above 180?°C. Based on XRD measurements and thermal analyses we were able to deduce Fe₂(SeO₃)₃·(6-x)H₂O (x?=?0.0–1.0) as formula of the hydrous ferric selenite mandarinoite. The total amount of water apparently affects the crystallinity, and possibly the stability of crystals: the less the x value, the higher crystallinity could be expected.     

The sources and seasonal fluxes of particulate organic carbon in the Yellow River

The Yellow River transports a large amount of sediment and particulate organic carbon (POC), which is thought to mainly derive from erosion of the Chinese Loess Plateau (CLP). However, the compositions, sources and erosional fluxes of POC in the Yellow River remain poorly constrained. Here we combined measurements of mineralogy, total organic carbon content (OC_total), stable organic carbon isotopes (δ¹³C_org), radiocarbon (¹⁴C) activity of organic matter in bulk suspended sediments collected seasonally from the upper and middle Yellow River, to quantify the compositions and fluxes of the POC and to assess its sources (biospheric and petrogenic POC, i.e. POC_bio and POC_petro, respectively). The results showed that the POC loading of sediments was controlled by mineralogy, grain size and specific surface area of loess particles. The F_mod of POC (0.71 to 0.31) can be explained by mixing of POC_petro with modern and aged POC_bio. A binary mixing model based on the hyperbolic relationship of the F_mod and OC_total revealed a wide range of ages of POC_bio from 1300 to 11100 ¹⁴C years. Relative to the upstream station, the annual POC_bio and POC_petro fluxes in the Yellow River are more than doubled after it flows crossing the CLP within 35% drainage area gain, resulting in POC_bio and POC_petro yields of the CLP at 3.50 ± 0.59 and 0.48 ± 0.49 tC/km²/yr, respectively. POC flux seasonal variation revealed that monsoon rainfall exerts a first-order control on the export of both POC_bio and POC_petro from the CLP to the Yellow River, resulting in more than 90% of the annual POC exported during the monsoon season. Around one third of annual POC erosional flux was transported during a storm event period, highlighting the important role of extreme events in POC export in this large river. © 2020 John Wiley & Sons, Ltd.     

Temporal and spatial changes in marine benthic habitats in relation to the EU Water Framework Directive: The use of sediment profile imagery

In 2002 to 2006, sediment profile imagery (SPI) was used to study the environmental impact of eutrophication-induced irregular and seasonal hypoxia on marine benthic habitats in six regions in the Skagerrak and Kattegat (West Sweden). The benthic habitat quality (BHQ) was assessed by parameterisation of biogenic structures observed by the SPI technique, and benthic quality status was related to the EU Water Framework Directive (EU-WFD). The temporal changes were analysed by a 5-factor nested ANOVA and significant temporal differences were recorded within three of the regions. Two of these were affected by hypoxia in the deeper parts and one was probably affected by hypoxia below the halocline. The environmental quality status according to the EU-WFD was bad to high in two regions, moderate to good in three regions, and good to high, i.e., acceptable according to the EU-WFD, in only one region. As BHQ is highly correlated to benthic faunal data, measures have to be taken to improve the coastal water quality in five of the six studied areas.