Geochemistry and petrogenesis of a basalt-benmoreite-trachyte suite from the southern part of the Gregory Rift,Kenya

In the southern Gregory Rift valley a series of transitional basalt, ferrobasalt, and benmoreite flows (1.65–1.4 Myr) is overlain by flood trachyte lavas (1.3–0.9 Myr). Mass balance calculations for major element compositions of rocks of this suite and their phenocrysts and microphenocrysts suggest that the ferrobasalts and benmoreites formed from magma resembling the most primitive basalt by closed system fractionation of plagioclase, clinopyroxene, olivine, titanomagnetite, and apatite. The trachytes formed from evolved magmas largely by alkali feldspar fractionation. Estimates of phenocryst and liquid densities and Rayleigh-law modelling of trace element contents support these conclusions. From Rayleigh-law modelling, we derived a set of effective distribution coefficients. Partial melting of crustal rocks or volatile transfer processes had no significant effect on the petrogenesis of this suite. The duration of the eruptive cycle, cooling time calculations, and mass balance calculations suggest that fractionation occurred in a magma reservoir with volume of at least 3 × 10⁴ km³ during an interval of about 0.8 Myr. Temperatures during fractionation probably ranged from about 1200 °C to 900 °C, and pressures may have been roughly 5 to 8 Kb. We suggest that rift development was accompanied by large-scale injection of basaltic magma and dilation of the crust, extensive fractionation, preferential eruption of low-density and fluid trachytic flood lavas, and by several episodes of normal faulting.     

Twentieth century simulation of the southern hemisphere climate in coupled models. Part II: sea ice conditions and variability

We examine the representation of the mean state and interannual variability of Antarctic sea ice in six simulations of the twentieth century from coupled models participating in the Intergovernmental Panel on Climate Change fourth assessment report. The simulations exhibit a largely seasonal southern hemisphere ice cover, as observed. There is a considerable scatter in the monthly simulated climatological ice extent among different models, but no consistent bias when compared to observations. The scatter in maximum winter ice extent among different models is correlated to the strength of the climatological zonal winds suggesting that wind forced ice transport is responsible for much of this scatter. Observations show that the leading mode of southern hemisphere ice variability exhibits a dipole structure with anomalies of one sign in the Atlantic sector associated with anomalies of the opposite sign in the Pacific sector. The observed ice anomalies also exhibit eastward propagation with the Antarctic circumpolar current, as part of the documented Antarctic circumpolar wave phenomenon. Many of the models do simulate dipole-like behavior in sea ice anomalies as the leading mode of ice variability, but there is a large discrepancy in the eastward propagation of these anomalies among the different models. Consistent with observations, the simulated Antarctic dipole-like variations in the ice cover are led by sea-level pressure anomalies in the Amundsen/ Bellingshausen Sea. These are associated, to different degrees in different models, with both the southern annular mode and the El Nino-Southern Oscillation (ENSO). There are indications that the magnitude of the influence of ENSO on the southern hemisphere ice cover is related to the strength of ENSO events simulated by the different models.     

Thermal DNAPL Source Zone Treatment Impact on a CVOC Plume

The tetrachloroethene (PCE) source zone at a site in Endicott, New York had caused a dissolved PCE plume. This plume was commingled with a petroleum hydrocarbon plume from an upgradient source of fuel oil. The plume required a system for hydraulic containment, using extraction wells located about 360 m downgradient of the source. The source area was remediated using in situ thermal desorption (ISTD). Approximately 1406 kilograms (kg) of PCE was removed in addition to 4082 kg of commingled petroleum‐related compounds. The ISTD treatment reduced the PCE mass discharge into the plume from an estimated 57 kg/year to 0.07 kg/year, essentially removing the source term. In the 5 years following the completion of the thermal treatment in early 2010, the PCE plume has collapsed, and the concentration of degradation products in the PCE‐series plume area has declined by two to three orders of magnitude. Anaerobic dechlorination is the suspected dominant mechanism, assisted by the presence of a fuel oil smear zone and a petroleum hydrocarbon plume from a separate source area upgradient of the PCE source. Based on the post‐thermal treatment groundwater monitoring data, the hydraulic containment system was reduced in 2014 and discontinued in early 2015.     

Isotopic fractionation associated with biosynthesis of fatty acids by a marine bacterium under oxic and anoxic conditions

Shewanella putrefaciens (Strain MR-4), a gram negative facultative marine bacterium, was grown to stationary phase under both aerobic and anaerobic conditions using lactate as the sole carbon source. Aerobically-produced cells were slightly enriched in ¹³C (+1.5‰) relative to the lactate carbon source, whereas those from anaerobic growth were depleted in ¹³C (−2.2‰). The distribution of fatty acids produced under aerobic conditions was similar to that resulting from anaerobic growth, being dominated by C_16:1 ω7 and C_16:0 fatty acids with a lesser amount of the C_18:1 ω7 component. Low concentrations of saturated even numbered normal fatty acids in the C₁₄ to C₁₈ range, and iso-C_15:0 were synthesized under both conditions. Fatty acids from anaerobic cultures (average δ¹³C=−37.8‰) were considerably depleted in ¹³C relative to their aerobically-synthesized counterparts (−28.8‰). The distinct differences in isotopic composition of both whole cells and individual fatty acid components result from differences in assimilation pathways. Under aerobic conditions, the primary route of assimilation involves the pyruvate dehydrogenase enzyme complex which produces acetyl-CoA, the precursor to lipid synthesis. In contrast, under anaerobic conditions formate, and not acetate, is the central intermediate in carbon assimilation with the precursors to fatty acid synthesis being produced via the serine pathway. Anaerobically-produced bacterial fatty acids were depleted by up to 12‰ relative to the carbon source. Therefore, detection of isotopically depleted fatty acids in sediments may be falsely attributed to a terrestrial origin, when in fact they are the result of bacterial resynthesis.     

Evaluation of anthropogenic carbon in the Nordic Seas using observed relationships of N, P and C versus CFCs

Several methods to compute the anthropogenic component of total dissolved inorganic carbon () in the ocean have been reported, all in some way deducing (a) the effect by the natural processes, and (b) the background concentration in the pre-industrial scenario. In this work we present a method of calculating using nutrient and CFC data, which takes advantage of the linear relationships found between nitrate (N), phosphate (P) and CFC-11 in the Nordic Seas sub-surface waters. The basis of the method is that older water has lower CFC-11 concentration and also has been exposed to more sinking organic matter that has decayed, resulting in the slopes of P versus CFC-11 and N versus CFC-11 being close to the classic Redfield ratio of 1:16. Combining this with the slope in total alkalinity (A_T) versus CFC-11 to correct for the dissolution of metal carbonates gives us the possibility to deduce the concentration of anthropogenic C_T in the Nordic Seas. This further allowed us to compute the inventory of anthropogenic C_T below 250 m in the Nordic Seas in spring 2002, to ∼1.2 Gt C.     

Mantle-derived heat recorded by conodont colour alteration in the Carboniferous of the Isle of Man

A range of colour alteration index (CAI) values between 3.0 and 6.0 is recorded for conodont elements recovered from the Arundian to Brigantian (Dinantian, Lower Carboniferous) sequence around Castletown, Isle of Man. Mantle-derived heat, channelled through the Caledonian South Barrule pluton, is proposed as the major cause of these elevated values. A lower CAI of 2.5 is obtained from elements recovered from a borehole sunk into the concealed Namurian (Upper Carboniferous) deposits near Shellag Point; the Glen Mona pluton acted as the medium for mantle-derived heat in this instance. The CAI values which may have been established during a late Dinantian volcanic episode around Castletown were overprinted by the greater effects of heat emanating from the South Barrule pluton. The record of CAI 6.0 for a sample taken from the immediate vicinity of a dyke indicates a high level of very localized CAI elevation in the early Tertiary.     

Large-scale current lineations on the central New Jersey shelf: Investigations by side-scan sonar

Two morphological orders of ridge and trough topography can be recognized on a terraced segment (at 37 m) of the central New Jersey shelf: (1) a first-order system with ridges to 14 m high, 2–6 km apart, in a Z-shaped pattern trending to the NNE, and (2) a second-order system with ridges 2–5 m high, 0.5-1.5 km apart and trends to the NE.Side-scan mapping together with submersible observations and bottom samples indicate a third-order system of large-scale current lineations which has been imprinted across the first- and second-order systems. The lineations are low relief forms (to 1.5 m high) which occur as elongate zones of textural contrast arranged in furrows, bands, patches and ribbons and display a uniform directional trend to the ENE.The morphology of the lineations appear to vary in response to the nature of the bottom. The lineations are narrow (10–25 m apart) and have no detectable relief in troughs and wider (to 75 m apart) and higher (to 1.5 m high) on ridges, especially second-order ridges of fine sand. Also revealed are wave ripple patterns and a pattern related to the outcropping of Pleistocene/Holocene units in trough bottoms and lower flanks.It is suggested that the first- and second-order systems developed during earlier stages of the Holocene transgression in response to a hydraulic regime of the inner shelf. The first-order system may have inherited some of its morphology from an older system, but did respond to a Holocene tidal regime adjacent to a major estuary. The second-order system developed in slightly deeper water, subsequent to the resumption of the transgression after the 37-m stillstand.The third-order lineations appear to be a response to the helical-flow structure within the flow field of a major shelf storm. Ridges of the central shelf may be maintained by alternate periods of oblique sweeping during storms, resulting in a net transport of fine sand out of the troughs and up on the ridges. Subsequent wave reworking returns the fine sand to the troughs.     

A molecular and isotopic study of the macromolecular organic matter of the ungrouped C2 WIS 91600 and its relationship to Tagish Lake and PCA 91008

Abstract– Insight into the chemical history of an ungrouped type 2 carbonaceous chondrite meteorite, Wisconsin Range (WIS) 91600, is gained through molecular analyses of insoluble organic matter (IOM) using solid‐state ¹³C nuclear magnetic resonance (NMR) spectroscopy, X‐ray absorption near edge structure spectroscopy (XANES), and pyrolysis‐gas chromatography coupled with mass spectrometry (pyr‐GC/MS), and our previous bulk elemental and isotopic data. The IOM from WIS 91600 exhibits similarities in its abundance and bulk δ¹⁵N value with IOM from another ungrouped carbonaceous chondrite Tagish Lake, while it exhibits H/C, δ¹³C, and δD values that are more similar to IOM from the heated CM, Pecora Escarpment (PCA) 91008. The ¹³C NMR spectra of IOM of WIS 91600 and Tagish Lake are similar, except for a greater abundance of CH_xO species in the latter and sharper carbonyl absorption in the former. Unusual cross‐polarization (CP) dynamics is observed for WIS 91600 that indicate the presence of two physically distinct organic domains, in which the degrees of aromatic condensation are distinctly different. The presence of two different organic domains in WIS 91600 is consistent with its brecciated nature. The formation of more condensed aromatics is the likely result of short duration thermal excursions during impacts. The fact that both WIS 91600 and PCA 91008 were subjected to short duration heating that is distinct from the thermal history of type 3 chondrites is confirmed by Carbon‐XANES. Finally, after being briefly heated (400 °C for 10 s), the pyrolysis behavior of Tagish Lake IOM is similar to that of WIS 91600 and PCA 91008. We conclude that WIS 91600 experienced very moderate, short duration heating at low temperatures (<500 °C) after an episode of aqueous alteration under conditions that were similar to those experienced by Tagish Lake.     

Consortium study of the unusual H chondrite regolith breccia,Noblesville

Abstract— The Noblesville meteorite is a genomict, regolith breccia (H6 clasts in H4 matrix). Mössbauer analysis confirms that Noblesville is unusually fresh, not surprising in view of its recovery immediately after its fall. It resembles “normal” H4–6 chondrites in its chemical composition and induced thermoluminescence (TL) levels. Thus, at least in its contents of volatile trace elements, Noblesville differs from other H chondrite, class A regolith breccias. Noblesville's small pre-atmospheric mass and fall near Solar maximum and/or its peculiar orbit (with perihelion <0.8 AU as shown by natural TL intensity) may partly explain its levels of cosmogenic radionuclides. Its cosmic ray exposure age of ～ 44 Ma, is long, is equalled or exceeded by <3% of all H chondrites, and also differs from the 33 ± 3 Ma mean exposure age peak of other H chondrite regolith breccias. One whole-rock aliquot has a high, but not unmatched, ¹²⁹Xe/¹³²Xe of 1.88. While Noblesville is now among the chondritic regolithic breccias richest in solar gases, elemental ratios indicate some loss, especially of He, perhaps b; impacts in the regolith that heated individual grains. While general shock-loading levels in Noblesville did not exceed 4 GPa, individual clasts record shock levels of 5–10 GPa, doubtless acquired prior to lithification of the whole-rock meteoroid.