Regional Seas and Sustainable Development Results of an International Workshop

Reports

Regional Seas and Sustainable Development Results of an International Workshop     

The role of principles and methods in loess-paleosol investigations

In the process of loessification, the development of loess fabric, the role of zonal, regional and partly of local environmental factors is regarded decisive. In the loess sequences various genetic types of loess pockets and paleosols occur and reflect different climatic and paleogeographical conditions.As a consequence, even within a single profile the colour, grain size and mineral composition, CaCO₃ content, degree of weathering and fabric of loess may vary. Zonal, regional or even local variations in such loess properties may equally derive from syngenetic or postgenetic processes. For similar reasons, spatially and temporally different forms, types and subtypes of paleosol also developed.This way, loess and soil formation resulted in various spatial types in the same glacial, interstadial or interglacial phase in the various geographical zones and regions. Although there exist major loess regions where the interglacial soils (eg brown forest soils) are markedly distinct from interstadial steppe soils or from other types of humic soils, continental loess areas can also be observed where the paleosols developed under interglacial and interstadial conditions (eg steppe or forest steppe soils) cannot be referred into different genetic types. In such cases the changes in paleoenvironments are difficult and uncertain to reconstruct.The interregional correlation of paleosols is occasionally hindered by the various terminologies applied to denote them. In addition, there are uncertainties concerning the dating and identification of paleoenvironments of polygenetic soils and of soil complexes consisting of paleosol units: how many soil formation phases they represent and how long erosional gaps can be reckoned with between these phases.     

Assessment of loess as parent material for agroecological potential

Due to its physical and chemical properties, areas with a loess mantle of proper thickness favour arable farming. Loess as a parent material promotes the formation of soils of good structure, nutrient supply and water budget. The ongoing land evaluation project places particular emphasis on the consideration of parent material in its scoring system as soil and climatic parameters are assessed in conjunction with the grain size composition of subsurface material and soil texture.A test area most suitable for the presentation of the method seems to be a sandy alluvial fan with loess mantle and this circumstance allows the contrasting of the agroecological potentials of soils developed on the two parent materials of different nature.The favourable water storage properties of loess make this deposit particularly valuable under the conditions of climatic aridification. The geographical information system applied here is capable of simulating the agroecological potential changes caused by reduced precipitation, increased evaporation and dropping groundwater levels.The research for this paper was carried out as part of the MEDALUS II (Mediterranean Desertification and Land Use) collaborative research project. MEDALUS II was funded by the EC under its Environment Progamme, contract no. EV5V 0128/0166. A grant was also provided by the OTKA (Hungarian National Science Foundation), project no 1278. The support is gratefully acknowledged.     

Klufttektonik und Grosstrukturen in den nördlichen Kalkalpen

Zusammenfassung Klufttektonische Untersuchungen in den Alpen sind spärlich. Nur die Arbeiten aus den bayerischen Kalkalpen lohnen eine vergleichende Betrachtung. Die in nichtalpinen Gebirgen zu Beginn der Faltung auftretenden kubischen Zerrungs-Kluftsysteme lassen sich in den nördlichen Kalkalpen nicht erkennen. Dort treten statt dessen Scherkluftsysteme auf, teils als gekreuzte Systeme, teils als Begleitklüfte streichender Störungen. Unbeeinflußt ziehen sie über Falten- und Deckenstrukturen hinweg, sind also jünger als diese. Das Diagonalkluftsystem geht auf seitliche Spannungen infolge Horizontalbeanspruchung zurück, die gegen Norden gerichtet war. Die Schernatur kommt in der vorwiegend horizontalen Striemung zum Ausdruck. Ein Vergleich mit den offenbar aus Scherklüften hervorgegangenen Diagonalstörungen, die mit den Klüften annähernd gleich alt sind, macht es wahrscheinlich, daß in Südbayern die Einbeziehung der Molasse in den Faltenbau jünger ist als die Diagonalstörungen. Scherkluftsystem und Diagonal-Blattverschiebungen sind für die nördlichen Kalkalpen mit ihrem flachen, nordvergenten Deckenbau besonders bezeichnend und scheinen in zentralen oder westlicheren Alpengebieten zurückzutreten oder ganz zu fehlen.     

Apport de la cathodoluminescence à haute résolution à l'étude de la diagenèse météorique dans les formations sédimentaires carbonatées

Different diagenetic transformations and their relative chronological sequence are studied in the meteoric diagenetic zone from the Upper Oligocene limestone at the North of the Aquitaine Basin (France), by combining high-resolution cathodoluminescence spectroscopy and electron-microprobe analyses. More than 128 spot analyses by electron microprobe and 60 analyses by cathodoluminescence spectroscopy are done on different meteoric cements firstly identified by classic optical microscopy. Three cement types are identified according to the relative intensity of the bands of their respective cathodoluminescence spectra (350, 380, 430, 500, and 620 nm). From these investigations, we could identify for each meteoric cement different phases of crystalline growth and crystalline dissolution. As a result, a better and more realistic meteoric diagenetic model is proposed. It illustrates the cyclic transformations from vadose zone (unsaturated) to meteoric zone (saturated). To cite this article: R. Chapoulie et al., C. R. Geoscience 337 (2005).     

Halocinèse précoce associée au rifting jurassique dans l'Atlas central de Tunisie (région de Majoura–El Hfay)

Seismic and sequence stratigraphy analyses, petroleum-well control and surface data studies of the Majoura–El Hfay region in the Central Atlas of Tunisia had led to identify and calibrate Jurassic seismic horizons. Seismic stratigraphic sections, seismic tectonics analyses, isochron and isopach mapping of Jurassic sequences show a differentiated structuring of platform and depocentre blocks limited by deep-seated NE–SW, north–south east–west and NW–SE faults intruded by Upper Triassic salt. The early salt migration seems to have started by the platform fracturing during the Lower Liassic rifting event. These movements are fossilized by thickness variations of Jurassic horizons, aggrading and retrograding onlap and toplap structures between subsiding rim-syncline gutters and high platform flanks intruded by salt pillows and domes. The salt migration is also attested by Middle and Upper Jurassic space depocentre migrations. Around the Majoura–El Hfay study blocks bounded by master faults, Triassic salt have pierced the Cretaceous and Tertiary sedimentary cover in a salt diapir extrusion and salt wall structures. To cite this article: D. Tanfous Amri et al., C. R. Geoscience 337 (2005).     

Modélisation géométrique 3D des granites stéphaniens du massif du Pelvoux (Alpes,France)

The structural analysis and the 3D modelling of Stephanian granites of the Pelvoux Massif characterize an emplacement along sinistral NW–SE- and dextral NE–SW-trending shear zones in the Pelvoux and in the Aiguilles Rouges–Mont Blanc Massifs, respectively. This Carboniferous shear system is consistent with a north–south extension direction known in the whole Variscan belt at this time. To cite this article: P. Strzerzynski et al., C. R. Geoscience 337 (2005).     

Étude expérimentale de la réactivité du CO2 supercritique vis-à-vis de phases minérales pures. Implications pour la séquestration géologique de CO2

Carbon dioxide sequestration in deep aquifers and depleted oilfields is a potential technical solution for reducing green-house gas release to the atmosphere: the gas containment relies on several trapping mechanisms (supercritical CO₂, CO_2(sc), dissolution together with slow water flows, mineral trapping) and on a low permeability cap-rock to prevent CO_2(sc), which is less dense than the formation water, from leaking upwards. A leakproof cap-rock is thus essential to ensure the sequestration efficiency. It is also crucial for safety assessment to identify and assess potential alteration processes that may damage the cap-rock properties: chemical alteration, fracture reactivation, degradation of injection borehole seals, etc. The reactivity of the host-rock minerals with the supercritical CO₂ fluid is one of the potential mechanisms, but it is altogether unknown. Reactivity tests have been carried out under such conditions, consisting of batch reactions between pure minerals and anhydrous supercritical CO₂, or a two-phase CO₂/H₂O fluid at 200?°C and 105/160 bar. After 45 to 60 days, evidence of appreciable mineral-fluid reactivity was identified, including in the water-free experiments. For the mixed H₂O/CO₂ experiments, portlandite was totally transformed into calcite; anorthite displayed many dissolution patterns associated with calcite, aragonite, tridymite and smectite precipitations. For the anhydrous CO₂ experiments, portlandite was totally carbonated to form calcite and aragonite; anorthite also displayed surface alteration patterns with secondary precipitation of fibrous calcite. To cite this article: O. Regnault et al., C. R. Geoscience 337 (2005).     

The 2011 submarine volcanic eruption in El Hierro (Canary Islands)

Forty years after the Teneguía Volcano (La Palma, 1971), a submarine eruption took place off the town of La Restinga, south of El Hierro, the smallest and youngest island of the Canarian Archipelago. Precursors allowed an early detection of the event and its approximate location, suggesting it was submarine. Uncertainties derived from insufficient scientific information available to the authorities during the eruption, leading to disproportionate civil protection measures, which had an impact on the island's economy—based primarily on tourism—while residents experienced extra fear and distress.     

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.