Some mineral stability relations in the system CaOMgOSiO2H2OHCl

Mineral-aqueous solution equilibria for the assemblages talc-quartz, tremolite-talc-quartz, diopside-tremolite-quartz, wollastonite-diopside-quartz and wollastonite-quartz have been studied at 2 kb total pressure, 500° to 700°C and chloride concentrations from 0.03 to 6.0 molal. Most work was at 1 m chloride. Both buffered and unbuffered data were obtained and a recalibration of the Ag-AgCl buffer is presented. Log equilibrium quotients at 500°, 600° and 700°C are respectively: Ta-Qz () 2.57, 1.71, 0.73; Tr-Ta-Qz and Di-Tr-Qz () 4.98, 3.99, 2.21 and 7.29, 5.30, 3.56; WoDi-Qz () 3.30, 3.00, 2.79: Wo-Qz () 5.15, 3.95, 2.68. Mineral stability fields plotted in terms of these concentration data more tangibly represent the compositional character of real systems and the mass transfer capabilities of their fluids than do the analogous theoretical activity diagrams.Overall dissociation constants of MgCl₂ and CaCl₂ were calculated from the experimental data using the calculated ionic activity constants for the reactions and the established dissociation constants of HCl. The negative log values are respectively: 3.88. 6.63, 9.20 for CaCl₂ and 4.60, 7.54, 10.37 for MgCl₂ at 500°, 600° and 700°C, 2 kb. The Ca values are about an order of magnitude more positive than the conductance-derived values by Frantz and Marshall (1982).The phase relations developed in this study have application to the genesis of talc, tremolite, and diopside-bearing assemblages in some regional metamorphic rocks, but more specifically to the calcsilicate skarn assemblages of many metasomatic aureoles. The equilibrium fluids are characterized by high concentrations of Ca relative to Mg and increasing $\text{Ca}\text{Mg}$ ratios with decreasing temperatures. The stability fields of talc, tremolite, and quartz expand relative to those of diopside and wollastonite with decreasing temperature, hence their more common appearance as retrograde products in skarn systems.     

Hydrological variability of major French rivers over recent decades,assessed from gauging station and GRACE observations

Abstract

This study was carried out in the framework of the Surface Water and Ocean Topography (SWOT) programme of the French National Centre of Space Studies (CNES). Based on discharge measurements and Gravity Recovery and Climate Experiment (GRACE) determination of total water storage (TWS), we have investigated the hydrological variability of the main French drainage basins (Seine, Loire, Garonne and Rhône) using a wavelet approach (continuous wavelet analyses and wavelet coherence analyses). The results of this analysis have shown a coherence ranging between 82% and 90% for TWS and discharge, thus demonstrating the potential use of TWS for characterization of the hydrological variability of French rivers. Strong coherence between the four basin discharges (between 73% and 92%) and between their associated TWS data (from 82% to 98%) suggested a common external influence on hydrological variability. To determine this influence, we investigated the relationship between hydrological variability and the North Atlantic Oscillation (NAO), considered as an index of prevailing climate in Europe. Basin discharges show strong coherence with NAO, ranging between 64% and 72% over the period 1959–2010. The coherence between NAO and TWS was 62% to 67% for 2003–2009. This is similar to the coherence between NAO and basin discharges detected for the same period. According to these results, strong influence of the NAO was clearly observed on the TWS and discharges of the major French river basins.

Editor Z.W. Kundzewicz     

Debris-flow susceptibility analysis using fluvio-morphological parameters and data mining: application to the Central-Eastern Pyrenees

Based on debris-flow inventories and using a geographical information system, the susceptibility models presented here take into account fluvio-morphologic parameters, gathered for every first-order catchment. Data mining techniques on the morphometric parameters are used, to work out and test three different models. The first model is a logistic regression analysis based on weighting the parameters. The other two are classification trees, which are rather novel susceptibility models. These techniques enable gathering the necessary data to evaluate the performance of the models tested, with and without optimization. The analysis was performed in the Catalan Pyrenees and covered an area of more than 4,000 km². Results related to the training dataset show that the optimized models performance lie within former reported range, in terms of AUC, although closer to the lowest end (near 70 %). When the models are applied to the test set, the quality of most results decreases. However, out of the three different models, logistic regression seems to offer the best prediction, as training and test sets results are very similar, in terms of performance. Trees are better at extracting laws from a training set, but validation through a test set gives results unacceptable for a prediction at regional scale. Although omitting parameters in geology or vegetation, fluvio-morphologic models based on data mining, can be used in the framework of a regional debris-flow susceptibility assessment in areas where only a digital elevation model is available.     

鲜水河断裂带色拉哈—康定段新发现的活动断层：木格措南断裂

鲜水河断裂带位于青藏高原东缘,是中国大陆内部地震活动性最强的大型活动断裂带之一。大量研究证据表明,鲜水河断裂带色拉哈—康定段未来几十年内发生破坏性强震的风险较高。目前正在规划建设的国家重大交通基础建设工程——川藏铁路,将在康定折多山地区直接穿越鲜水河活动断裂带。本研究通过高分辨率卫星影像的地质地貌解译和详细的野外构造地质填图,新发现一条发育于色拉哈断裂和折多塘断裂之间折多山花岗岩体内的长约24km的全新世活动断层,该断裂空间上可分成北、中、南三段,呈(正滑)左旋右阶雁行状排列,并将其命名为“木格措南断裂”。该活动断裂的发现对完善鲜水河断裂带色拉哈—康定段的精细几何图像和构造组合特征,准确评价鲜水河断裂带的地震危险性具有重要意义,并为川藏铁路施工建设和安全运营提供了重要科学数据支撑。     

The excitation of the forbidden coronal lines

The excitation of the 2s²2p² ground configuration of Caxv is calculated for coronal densities and temperatures. The calculations include electron and proton excitation of the forbidden transitions and electron excitation via the first excited (2s2p³) configuration. It is shown that measurements of the line intensity ratio I( 5694)/I( 5446) are in good agreement with the predictions. The line to continuum observations for limb flares and coronal condensations are discussed. It is suggested that the calcium abundance in condensations is enhanced owing to diffusion processes.Present address: Department of Astronomy, University of Texas, Austin, Texas, U.S.A.     

Constraints on the late Quaternary glaciations in Tibet from cosmogenic exposure ages of moraine surfaces

This contribution provides new constraints on the timing of Tibetan glacial recessions recorded by the abandonment of moraines. We present cosmogenic radionuclide ¹⁰Be inventories at 17 sites in southern and western Tibet (32 crests, 249 samples) and infer the range of permissible emplacement ages based on these analyses. Individual large embedded rock and boulder samples were collected from the crests of moraine surfaces and analyzed for ¹⁰Be abundance. We consider two scenarios to interpret the age of glacial recession leading to the moraine surface formation from these sample exposure ages: 1) Erosion of the moraine surface is insignificant and so the emplacement age of the moraines is reflected by the mean sample age; and 2) Erosion progressively exposes large boulders with little prior exposure, and so the oldest sample age records the minimum moraine emplacement age. We found that depending on the scenario chosen, the moraine emplacement age can vary by > 50% for ～100 ka-old samples. We consider two scaling models for estimating the production rates of ¹⁰Be in Tibet, which has an important, although lesser, effect on inferred moraine ages. While the data presented herein effectively increase the database of sample exposure ages from Tibet by ～20%, we find that uncertainties related to the interpretation of the ¹⁰Be abundance within individual samples in terms of moraine emplacement ages are sufficient to accommodate either a view in which glacial advances are associated with temperature minima or precipitation maxima that are recorded by independent paleoclimate proxies. A reanalysis of published data from moraines throughout Tibet shows that the variation we observe is not unique to our dataset but rather is a robust feature of the Tibetan moraine age database. Thus, when viewed in a similar way with other samples collected from this area, uncertainties within moraine exposure ages obscure attribution of Tibetan glacial advances to temperature minima or precipitation maxima. Our work suggests that more reliable chronologies of Tibetan glaciations will come from improvements in production rate models for this portion of the world, as well as a better understanding of the processes that form and modify these geomorphic surfaces.     

Co-seismic and cumulative offsets of the recent earthquakes along the Karakax left-lateral strike-slip fault in western Tibet

The 400 km-long Karakax left-lateral strike-slip fault is the westernmost segment of the Altyn Tagh fault. It separates northwestern Tibet to the south from the Tarim basin to the north. The western section of the Karakax fault exhibits clear co-seismic surface ruptures of past large earthquakes. Geomorphic offset measurements from the field and high-resolution Ikonos images along 1.5 km across the Sanshiliyingfang fan and along 55 km of the fault, range from 3 to 28 m, with distinct clusters at 6 ± 2(3), 14 ± 2, 19 ± 2 and 24 ± 3 m. The cluster of the smallest offsets around 6 m (full range from 3 to 10 m) distributed over a minimum length of 55 km, is attributed to the last largest surface rupturing event that testifies of the occurrence of a magnitude Mw 7.4-7.6 earthquake along the Karakax fault. We interpret the other offset clusters as the possible repetition of similarly sized events thus favoring a characteristic slip model for the Karakax fault. In a 3 m-deep trench dug across the active trace of the fault we can identify the main rupture strands of the last and penultimate events. The penultimate event horizon, a silty-sand layer, has been radiocarbon dated at 975-1020 AD (AMS ¹⁴C age). It is proposed that large Mw 7.4-7.6 events with co-seismic slip of about 6 m rupture the Karakax fault with a return time of about 900 years implying an average slip-rate of about 6-7 mm/years during the late Holocene. These results suggest that the Karakax fault is the largest left-lateral strike-slip fault at the rim of northwestern Tibet accommodating eastward movement of Tibet due to the India-Eurasia collision.     

Experimental and discrete element modeling studies of the trapdoor problem: influence of the macro-mechanical frictional parameters

Granular soils have the inherent ability to develop load transfers in their mass. Mechanisms of load transfers are used as a basic principle of many civil and geotechnical engineering applications. However, their complexity makes it difficult to formulate relevant design methods for such works. The trapdoor problem is one of the ways to reproduce load transfers by the arching effect in a granular layer in non-complex conditions. In addition, many analytical solutions for the prediction of load transfer mechanisms are based on the trapdoor problem. However, some of the parameters required are still being widely discussed, in particular the ratio of horizontal stress to vertical stress. For this paper, an experimental device for trapdoor tests in plane strain conditions was created and several geomaterials were tested. Three phases in the response of the materials were consistently observed. Each of these phases corresponded to a specific displacement of the trapdoor. A first phase of high load transfer was observed followed by a transition phase which was followed by a critical phase for which the load transfer amplitude increased and stabilized. Analytical solutions and experimental values of load transfers were compared. Considerable differences between the stress ratio needed to fit the experimental data and the stress ratio proposed in the analytical models were noted. Based on the conclusions of the experimental study, the discrete element method was used to model the same trapdoor problem. A wide range of granular materials was modeled and tested in the trapdoor problem. The three phases in the response of the layer were also observed in the numerical modeling. In addition, it was shown that the shear strength of the material is the key parameter of load transfers: peak shear resistance for the small displacements of the trapdoor and critical shear strength for the larger displacements. A micro-mechanical analysis showed that the effective stress ratio in the sheared zone does not vary as much with shear strength. Stress ratios here were again greater than those proposed in the analytical solutions. Nevertheless, the relevance of the solution of Terzaghi was confirmed as soon as the stress ratio was correctly chosen.     

Chlorine-rich metasomatic H2O-CO2 fluids in amphibole-bearing peridotites from Injibara (Lake Tana region, Ethiopian plateau): Nature and evolution of volatiles in the mantle of a region of continental flood basalts

Petrological and geochemical study of volatile bearing phases (fluid inclusions, amphibole, and nominally anhydrous minerals) in a spinel lherzolite xenolith suite from Quaternary lavas at Injibara (Lake Tana region, Ethiopian plateau) shows compelling evidence for metasomatism in the lithospheric mantle in a region of mantle upwelling and continental flood basalts. The xenolith suite consists of deformed (i.e., protogranular to porphyroclastic texture) Cl-rich pargasite lherzolites, metasomatized (LILE and Pb enrichment in clinopyroxene and amphibole) at T ? 1000 °C. Lherzolites contain chlorine-rich H₂O-CO₂ fluid inclusions, but no melt inclusions. Fluid inclusions are preserved only in orthopyroxene, while in olivine, they underwent extensive interaction with the host mineral. The metasomatic fluid composition is estimated: X_CO2 = 0.64, X_H2O = 0.33, X_Na = 0.006, X_Mg = 0.006, X_Cl = 0.018, (salinity = 14-10 NaCl eq. wt.%, a_H2O = 0.2, Cl = 4-5 mol.%). Fluid isochores correspond to trapping pressures of 1.4-1.5 GPa or 50-54 km depth (at T = 950 °C). Synchrotron sourced micro-infrared mapping (ELECTRA, Trieste) shows gradients for H₂O-distribution in nominally anhydrous minerals, with considerable enrichment at grain boundaries, along intragranular microfractures, and around fluid inclusions. Total water amounts in lherzolites are variable from about 150 up to 400 ppm. Calculated trace-element pattern of metasomatic fluid phases, combined with distribution and amount of H₂O in nominally anhydrous minerals, delineate a metasomatic Cl- and LILE-rich fluid phase heterogeneously distributed in the continental lithosphere. Present data suggest that Cl-rich aqueous fluids were important metasomatic agents beneath the Ethiopian plateau, locally forming a source of high water content in the peridotite, which may be easily melted. High Cl, LILE, and Pb in metasomatic fluid phases suggest the contribution of recycled altered oceanic lithosphere component in their source.     

Shock metamorphism and impact melting in small impact craters on Earth: Evidence from Kamil crater,Egypt

Kamil is a 45 m diameter impact crater identified in 2008 in southern Egypt. It was generated by the hypervelocity impact of the Gebel Kamil iron meteorite on a sedimentary target, namely layered sandstones with subhorizontal bedding. We have carried out a petrographic study of samples from the crater wall and ejecta deposits collected during our first geophysical campaign (February 2010) in order to investigate shock effects recorded in these rocks. Ejecta samples reveal a wide range of shock features common in quartz‐rich target rocks. They have been divided into two categories, as a function of their abundance at thin section scale: (1) pervasive shock features (the most abundant), including fracturing, planar deformation features, and impact melt lapilli and bombs, and (2) localized shock features (the least abundant) including high‐pressure phases and localized impact melting in the form of intergranular melt, melt veins, and melt films in shatter cones. In particular, Kamil crater is the smallest impact crater where shatter cones, coesite, stishovite, diamond, and melt veins have been reported. Based on experimental calibrations reported in the literature, pervasive shock features suggest that the maximum shock pressure was between 30 and 60 GPa. Using the planar impact approximation, we calculate a vertical component of the impact velocity of at least 3.5 km s^?1. The wide range of shock features and their freshness make Kamil a natural laboratory for studying impact cratering and shock deformation processes in small impact structures.