Dissolved trace metals in the Western Mediterranean Sea: total concentration and fraction isolated by C18 Sep-Pak technique

An investigation of trace metal distributions in the Western Mediterranean Sea was carried out during the RRS Discovery cruise (July 1993) in which a transect from the Strait of Gibraltar to the Strait of Sicily was conducted. Organically complexed dissolved trace metals and their total concentrations were measured to investigate the end-members and to predict the environmental capacity of the Mediterranean for potential toxic metals. The distribution of trace metals can be accounted for by the mixing of several end-members and by some atmospheric inputs to the surface water. For Pb and Fe, the effects of the atmospheric inputs are more pronounced than for the other metals. Due to the rapid exchange of water masses, the Western Mediterranean may have the ability to assimilate the increased external inputs for some trace metals such as Cu, Cd, Ni and Zn. But the external inputs for Pb and Fe exceed the removal capacity of the Western Mediterranean and these elements may accumulate in the water column of the western basin. The C18 Sep-Pak technique and direct determination by DPASV were used to determine the amount of trace metal–organic complexes. The C18 Sep-Pak column isolates only a small fraction of trace metals except for Cu. The maximum hydrophobic fractions for the studied trace metals, except for Cd and Pb, which are not detectable, were found in the subsurface layer at all stations. This maximum may well be linked to picoplankton activity and the picoplankton, prochlorophytes may have an important role in the speciation of dissolved Cu as well as Synechococcus. These organic ligands for Cu were produced at the maximum of biological activity in the Western Mediterranean basin and seem to be accumulated at halocline level by Mediterranean hydrodynamic characteristics. However, direct determination by DPASV showed that the major part of Cu, Cd and Pb, complexed by organic materials, was not isolated by C18 Sep-Pak technique.     

Semipermeable membrane devices link site-specific contaminants to effects: PART II - A comparison of lingering Exxon Valdez oil with other potential sources of CYP1A inducers in Prince William Sound, Alaska

We deployed semipermeable membrane devices (SPMDs) on beaches for 28 days at 53 sites in Prince William Sound (PWS), Alaska, to evaluate the induction potential from suspected sources of cytochrome P450 1A (CYP1A)-inducing contaminants. Sites were selected to assess known point sources, or were chosen randomly to evaluate the region-wide sources. After deployment, SPMD extracts were analyzed chemically for persistent organic pollutants (POPs) and polycyclic aromatic hydrocarbons (PAH). These results were compared with hepatic CYP1A enzyme activity of juvenile rainbow trout injected with the same extracts prior to clean-up for the chemical analyses. Increased CYP1A activity was strongly associated with PAH concentrations in extracts, especially chrysene homologues but was not associated with POPs. The only apparent sources of chrysene homologues were lingering oil from Exxon Valdez, asphalt and bunker fuels released from storage tanks during the 1964 Alaska earthquake, creosote leaching from numerous pilings at one site, and PAH-contaminated sediments at Cordova Harbor. Our results indicate that PWS is remarkably free of pollution from PAH when nearby sources are absent as well as from pesticides and PCBs generally.     

Effects of artificial reefs on fish grazing in their vicinity: evidence from algae presentation experiments

Artificial reefs have been suggested as a tool for conservation and restoration of marine habitats. However, the relationships between coral reef habitats and man-made structures are poorly understood. We experimentally tested whether artificial reefs change grazing patterns in their surrounding environment. We exposed heaps of the macroalgae, Ulva lactuca, to natural grazing, at various distances from three artificial reefs. Results suggest that artificial reefs change grazing patterns in the neighboring area. In all the locations examined grazing was 2-3 times higher near the artificial reefs than in control sites (p < 0.05). We suggest that herbivorous fishes are attracted to the artificial reefs, creating a zone of increased grazing. Therefore, while planning deployment of such artificial reefs it is necessary to consider their overall influence on their natural surroundings, in order to maintain the natural community trophic dynamics.     

Tomography of crustal seismic attenuation in Metropolitan France: implications for seismicity analysis

In this work, we map the absorption properties of the French crust by analyzing the decay properties of coda waves. Estimation of the coda quality factor \(Q_{c}\) in five non-overlapping frequency-bands between 1 and 32 Hz is performed for more than 12,000 high-quality seismograms from about 1700 weak to moderate crustal earthquakes recorded between 1995 and 2013. Based on sensitivity analysis, \(Q_{c}\) is subsequently approximated as an integral of the intrinsic shear wave quality factor \(Q_{i}\) along the ray connecting the source to the station. After discretization of the medium on a 2-D Cartesian grid, this yields a linear inverse problem for the spatial distribution of \(Q_{i}\). The solution is approximated by redistributing \(Q_{c}\) in the pixels connecting the source to the station and averaging over all paths. This simple procedure allows to obtain frequency-dependent maps of apparent absorption that show lateral variations of \(50\%\) at length scales ranging from 50 km to 150 km, in all the frequency bands analyzed. At low frequency, the small-scale geological features of the crust are clearly delineated: the Meso-Cenozoic basins (Aquitaine, Brabant, Southeast) appear as strong absorption regions, while crystalline massifs (Armorican, Central Massif, Alps) appear as low absorption zones. At high frequency, the correlation between the surface geological features and the absorption map disappears, except for the deepest Meso-Cenozoic basins which exhibit a strong absorption signature. Based on the tomographic results, we explore the implications of lateral variations of absorption for the analysis of both instrumental and historical seismicity. The main conclusions are as follows: (1) current local magnitude \(M_{L}\) can be over(resp. under)-estimated when absorption is weaker(resp. stronger) than the nominal value assumed in the amplitude-distance relation; (2) both the forward prediction of the earthquake macroseismic intensity field and the estimation of historical earthquake seismological parameters using macroseismic intensity data are significantly improved by taking into account a realistic 2-D distribution of absorption. In the future, both \(M_{L}\) estimations and macroseismic intensity attenuation models should benefit from high-resolution models of frequency-dependent absorption such as the one produced in this study.     

Target-oriented imaging using extended image volumes: a low-rank factorization approach

Imaging in geological challenging environments has led to new developments, including the idea of generating reflection responses by means of interferometric redatuming at a given target datum in the subsurface, when the target datum lies beneath a complex overburden. One way to perform this redatuming is via conventional model-based wave-equation techniques. But those techniques can be computationally expensive for large-scale seismic problems since the number of wave-equation solves is equal to two times the number of sources involved during seismic data acquisition. Also conventional shot-profile techniques require lots of memory to save full subsurface extended image volumes. Therefore, we can only form subsurface image volumes in either horizontal or vertical directions. To exploit the information hidden in full subsurface extended image volumes, we now present a randomized singular value decomposition-based approach built upon the matrix probing scheme, which takes advantage of the algebraic structure of the extended imaging system. This low-rank representation enables us to overcome both the computational cost associated with the number of wave-equation solutions and memory usage due to explicit storage of full subsurface extended image volumes employed by conventional migration methods. Experimental results on complex geological models demonstrate the efficacy of the proposed methodology and allow practical reflection-based extended imaging for large-scale five-dimensional seismic data.     

Early agriculture in the Eastern Grand Canyon of Arizona,USA

Abandoned fields in Colorado River alluvium in the eastern Grand Canyon show signs of primitive agriculture. Presence of maize pollen in association with buried soils near Comanche Creek suggests that farming began prior to 3130 yr B.P. Cotton pollen, identified in buried soils near Nankoweap Creek, dates to 1310 yr B.P., approximately 500 years earlier than previously reported anywhere on the Colorado Plateau. Farming spanned three millennia in this reach of the canyon. Entrenchment, starting approximately 700 yr B.P., making water diversion to fields infeasible, was likely responsible for field abandonment. © 2000 John Wiley & Sons, Inc.     

Persistent organic pollutants (POPs) in killer whales (Orcinus orca) from the Crozet Archipelago, southern Indian Ocean

Persistent organic pollutants (POPs), including polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), and dibenzofurans (PCDFs), are ubiquitous environmental contaminants of which significant concentrations are reported in upper trophic level animals. In 1998, we collected blubber biopsy samples (n = 11) from killer whales (Orcinus orca) inhabiting the coastal waters around Possession Island, Crozet Archipelago, southern Indian Ocean, for contaminant analyses. Despite inhabiting an isolated region far removed from industrial activities, these killer whales can presently be considered among the most PCB-contaminated cetaceans in the southern hemisphere, with concentrations ranging from 4.4 to 20.5 mg/kg lipid weight (lw). PCDD levels ranged from below the detection limit (5 ng/kg) to 77.1 ng/kg lw and PCDF levels from below the detection limit (7 ng/kg) to 36.1 ng/kg lw. Over 70% of our study animals had PCB concentrations which exceeded a 1.3 mg/kg PCB threshold established for endocrine disruption and immunotoxicity in free-ranging harbour seals, suggesting that organic contaminants cannot be ruled out as an additional threat to this declining population.     

The Effects of Quality Control on Decreasing Error Propagation in the LandScan USA Population Distribution Model: A Case Study of Philadelphia County

LandScan USA is a 90 m population distribution model that is used for a variety of applications, including emergency management. Models should have a measure of accuracy; however, the accuracy of population distribution models is difficult to determine due to the inclusion of multiple input datasets and the lack of quantifiable, observable (validated) data to confirm model output. Validated data enables quantification of: (1) overall model accuracy and (2) changes in model output at different levels of quality control. This article examines the effect of quality control for two national school datasets incorporated as input in LandScan USA for Philadelphia County, Pennsylvania; which had a local, validated school dataset available. The effect of each stage of quality control efforts utilized throughout the LandScan USA process were assessed to determine what level of quality control was required to have a statistically significant change of the model's population distribution. The typical level of quality control for LandScan USA resulted in 36% of schools being moved to the correct location and 20% of missing student enrollments were found, compared to 87% and 98% respectively for the validated dataset. The costs of increasing quality control resulted in a six-fold increase in labor time; however, the additional quality control did not produce statistically significant improvements in the LandScan USA model. Thus, typical quality control efforts for schools in LandScan USA produced a population distribution similar to the validated level of quality control, and can be applied with confidence for policy, planning, and emergency situations.     

Interactions between groundwater and seasonally ice‐covered lakes: Using water stable isotopes and radon‐222 multilayer mass balance models

Interactions between lakes and groundwater are of increasing concern for freshwater environmental management but are often poorly characterized. Groundwater inflow to lakes, even at low rates, has proven to be a key in both lake nutrient balances and in determining lake vulnerability to pollution. Although difficult to measure using standard hydrometric methods, significant insight into groundwater–lake interactions has been acquired by studies applying geochemical tracers. However, the use of simple steady‐state, well‐mixed models, and the lack of characterization of lake spatiotemporal variability remain important sources of uncertainty, preventing the characterization of the entire lake hydrological cycle, particularly during ice‐covered periods. In this study, a small groundwater‐connected lake was monitored to determine the annual dynamics of the natural tracers, water stable isotopes and radon‐222, through the implementation of a comprehensive sampling strategy. A multilayer mass balance model was found outperform a well‐mixed, one‐layer model in terms of quantifying groundwater fluxes and their temporal evolution, as well as characterizing vertical differences. Water stable isotopes and radon‐222 were found to provide complementary information on the lake water budget. Radon‐222 has a short response time, and highlights rapid and transient increases in groundwater inflow, but requires a thorough characterization of groundwater radon‐222 activity. Water stable isotopes follow the hydrological cycle of the lake closely and highlight periods when the lake budget is dominated by evaporation versus groundwater inflow, but continuous monitoring of local meteorological parameters is required. Careful compilation of tracer evolution throughout the water column and over the entire year is also very informative. The developed models, which are suitable for detailed, site‐specific studies, allow the quantification of groundwater inflow and internal dynamics during both ice‐free and ice‐covered periods, providing an improved tool for understanding the annual water cycle of lakes.     

Conceptual rainfall–runoff model with a two‐parameter,infinite characteristic time transfer function

A two‐parameter transfer function with an infinite characteristic time is proposed for conceptual rainfall–runoff models. The large time behaviour of the unit response is an inverse power function of time. The infinite characteristic time allows long‐term memory effects to be accounted for. Such effects are observed in mountainous and karst catchments. The governing equation of the model is a fractional differential equation in the limit of long times. Although linear, the proposed transfer function yields discharge signals that can usually be obtained only using non‐linear models. The model is applied successfully to two catchments, the Dud Koshi mountainous catchment in the Himalayas and the Durzon karst catchment in France. It compares favourably to the linear, non‐linear single reservoir models and to the GR4J model. With a single reservoir and a single transfer function, the model is capable of reproducing hysteretic behaviours identified as typical of long‐term memory effects. Computational efficiency is enhanced by approximating the infinite characteristic time transfer function with a sum of simpler, exponential transfer functions. This amounts to partitioning the reservoir into several linear sub‐reservoirs, the output discharges of which are easy to compute. An efficient partitioning strategy is presented to facilitate the practical implementation of the model. Copyright © 2015 John Wiley & Sons, Ltd.