Chemistry and sulfur isotopic composition of precipitation at Bologna, Italy

Individual and monthly precipitation samples from the polluted atmosphere of Bologna (Emilia-Romagna province) were collected during March 1996 to May 1997 and analyzed for major ions in solution and S isotopes in dissolved SO₄.Weighted mean enrichment factors relative to seawater are found to be 1.0 for Na, 15.2 for K, 105 for Ca, 3.3 for Mg, 17.3 for SO₄ and 663 for HCO⁻₃. Very good positive correlations are observed for the Ca²⁺–Mg²⁺–HCO⁻₃–SO²⁻₄–NO⁻₃ system, indicating that dissolution of Ca (±Mg)-carbonate particles by H₂SO₄ and HNO₃ from combustion of oil and gas is a major process controlling the chemical composition of rain and snow. Na⁺ and Cl⁻ in monthly precipitation derive essentially from sea spray, but the contribution of Na⁺ from continental sources is appreciable in a number of individual rains. NH⁺₄ appears to be on average more abundant in spring and summer precipitation, its main sources being microbial activity in soils and application of fertilizers. K⁺ is probably of continental origin from soil dust.The S isotopic composition of SO₄ is systematically positive, with mean δ³⁴S values of +3.2±1.6‰ (n=40) in individual precipitation and +2.8±1.4‰ (n=12) in monthly precipitation. These isotopic compositions are interpreted in terms of a dominant contribution of S from anthropogenic emissions and subordinate contributions from biogenic and marine sources. Pollutant SO₄ is estimated to have a δ³⁴S value in the range +2.5 to +4.5‰, whereas a distinctive δ³⁴S of −4.5‰ or lower indicates SO₄ from oxidation of biogenic gases.The isotopic and chemical compositions of SO₄ do not depend on wind direction, thus testifying to a mostly local source for pollutant S in the Bologna atmosphere.     

Sediments from Lake Cheko (Siberia), a possible impact crater for the 1908 Tunguska Event

Cheko, a small lake located in Siberia close to the epicentre of the 1908 Tunguska explosion, might fill a crater left by the impact of a fragment of a Cosmic Body. Sediment cores from the lake’s bottom were studied to support or reject this hypothesis. A 175‐cm long core, collected near the center of the lake, consists of an upper ～1 m thick sequence of lacustrine deposits overlaying coarser chaotic material. ²¹⁰Pb and ¹³⁷Cs indicate that the transition from lower to upper sequence occurred close to the time of the Tunguska Event. Pollen analysis reveals that remains of aquatic plants are abundant in the top post‐1908 sequence, but are absent in the lower pre‐1908 portion of the core. These results, including organic C, N and δ¹³C data, suggest that Lake Cheko formed at the time of the Tunguska Event.     

Modelling the long‐term deformation of the sedimentary substrate of Mt. Etna volcano (Italy)

This study investigates in detail the deformation events that have affected the sedimentary successions forming the substrate of Mt. Etna volcano (Italy). Based on the geometric reconstruction of a buried sedimentary marker, we have been able to identify and quantify the effects of three different mechanisms of deformation that have affected the area in the last 600 ka. Numerical results from Finite Element Method (FEM) applied to model viscoelastic deformation suggest the occurrence of a crustal doming process originating at the mantle‐crust transition (~16 km). We propose that the source of deformation is related to the diapiric uprise of hydrothermal material originating in altered ocean‐like crust and its emplacement at a shallower level in the crust. This process has great relevance in the volcanic system and should be considered for the full assessment of its origin and evolution.     

Decoding the spectra of SDSS early-type galaxies: new indicators of age and recent star formation

We apply principal component analysis (PCA) to a sample of early-type galaxies from the Sloan Digital Sky Survey (SDSS) in order to infer differences in their star formation histories from their unresolved stellar populations. We select a   z < 0.1  volume-limited sample comprising ∼7000 early-type galaxies from SDSS/Data Release 4. Out of the first few principal components (PC), we study four which give information about stellar populations and velocity dispersion. We construct two parameters (η and ζ) as linear combinations of PC1 and PC2. The four components can be presented as 'optimal filters' to explore in detail the properties of the underlying stellar populations. By comparing various photospectroscopic observables – including near-ultraviolet (NUV) photometry from Galaxy Evolution Explorer (GALEX) – we find ζ to be most sensitive to recent episodes of star formation, and η to be strongly dependent on the average age of the stellar populations. Both η and ζ also depend on metallicity. We apply these optimal filters to composite spectra assembled by Bernardi et al. The distribution of the η component of the composites appear to be indistinguishable between high- and low-density regions, whereas the distribution of ζ parameters have a significant skew towards lower values for galaxies in low-density regions. This result suggests that galaxies in lower density environments are less likely to present weak episodes of recent star formation. In contrast, a significant number of galaxies from our high-density subsample – which includes clusters (both outer regions and centres) and groups – underwent small but detectable recent star formation at high metallicity, in agreement with recent estimates targeting elliptical galaxies in Hickson Compact Groups and in the field.     

Field determination of the spatial variation of resistance to flow along a steep Alpine stream

Accurate field data have been collected along the Febbraro River (central Italian Alps) during quasi‐steady, low‐flow conditions to investigate the spatial variations of hydraulic and geomorphologic quantities potentially affecting resistance to flow. Detailed uncertainty analysis and weighted least‐squares fitting of simple power function relationships to field‐derived data are carried out to identify possible interdependencies between observed variables. Mean flow velocity is found to depend on water‐surface slope, bed material particle size, and upstream drainage area, whereas its dependence on hydraulic depth appears less susceptible to quantification. Upstream drainage area is found to explain the variations of hydraulic depth, water‐surface slope, Gauckler–Strickler conductance coefficient, and (although less significantly) flow discharge. Specifically, a highly significant positive dependence of the Gauckler–Strickler conductance coefficient on the upstream drainage area is found to exist, although anomalies in the variations of hydraulic depth and flow discharge are observed along the stream. The combined use of uncertainty analysis, hydraulic equations, and geomorphological relationships allows a possible characterization of resistance to flow along a steep Alpine stream and, perhaps more importantly, provides useful guidelines for future investigative efforts. Copyright © 2006 John Wiley & Sons, Ltd.     

Comparison of the ENEAR peculiar velocities with the PSCz gravity field

We present a comparison between the peculiar velocity field measured from the ENEAR all-sky D _n– σ catalogue and that derived from the galaxy distribution of the IRAS Point Source Catalog Redshift Survey (PSC z ). The analysis is based on a modal expansion of these data in redshift space by means of spherical harmonics and Bessel functions. The effective smoothing scale of the expansion is almost linear with redshift reaching 1500 km s⁻¹ at 3000 km s⁻¹. The general flow patterns in the filtered ENEAR and PSC z velocity fields agree well within 6000 km s⁻¹, assuming a linear biasing relation between the mass and the PSC z galaxies. The comparison allows us to determine the parameter     where Ω is the cosmological density parameter and b is the linear biasing factor. A likelihood analysis of the ENEAR and PSC z modes yields     in good agreement with values obtained from Tully–Fisher surveys.     

Temporal Variations of Benthic Bacterial Microflora on the Northwestern Mediterranean Continental Shelf and Slope

Abstract. Bacterial (direct and heterotrophic counts, heterotrophic potentials) and organic matter (org C, org N) parameters were studied over 2 years in the surface sediments of 3 stations located on the continental shelf (station A: 15m; station B: 35m) and slope (station C: 910m) in the northwestern Mediterranean Basin.
Although logistic constraints did not allow a satisfactory sampling periodicity in the offshore survey, some seasonal trends were still observable at the deepest station. Variations were quantitatively more important in the two shallow sediments (from 3×10² heterotrophic bacteria – ml^-1 in December 1984 to 10⁷ heterotrophic bacteria-ml^-1 in March 1986). Epifluorcsccncc direct counts were relatively constant (5×10⁸ cells-ml^-1), while heterotrophic potentials (with ¹⁴C labelled glucose and glutamic acid) showed a succession of very short pulses over the year. Different concentrations of organic matter (from 0.2% orgC at 15m to 0.8% orgC at 35m) appeared to sustain very similar bacterial numbers. Nevertheless, a certain relation between the seasonal evolution of bacterial and organic matter parameters was discernable. Although depth apparently had no measurable effect on maximal spring bacterial densities, it seemed to lessen the summer and winter decreases in the two shallow stations.     

A long-term annual water balance analysis of the Araçuaí River Basin,Brazil

Semi-arid and arid areas exhibit great temporal variability in water availability. In some of these regions, a one- or two-day rainfall is followed by intervening dry periods of variable length. In recent decades, many rivers of the semi-arid portion of the Jequitinhonha Basin have been undergoing a progressive discharge reduction, mainly of their base flow, the Araçuaí River is one of them. In order to understand this transformation, a long-term analysis of the annual water balance of the Araçuaí River Basin was performed, the results of which are presented herein. Satellite images, hydrometeorological and river discharge data were analyzed; mean and variance tests were conducted to determine temporal homogeneity. Historical pluviometric data analysis shows no corresponding precipitation reduction and temperature undergoes only a slight increase in the same period. On the other hand, evaporation is extremely high, higher than precipitation during most of the year, leaving almost no water for infiltration (aquifer recharge) and runoff. Furthermore, the Araçuaí headwaters of its tributaries are now occupied by a monoculture, Eucaliptus sp., used for paper production. Because of the decreased fluvial discharges, its lowlands, usually used for agriculture and pasture, are abandoned and partially eroded.     

巴西Ara(c)uaí河流域长期水量平衡分析

Semi-arid and arid areas exhibit great temporal variability in water availability. In some of these regions, a one- or two-day rainfall is followed by intervening dry periods of variable length. In recent decades, many rivers of the semi-arid portion of the Jequitinhonha Basin have been undergoing a progressive discharge reduction, mainly of their base flow, the are presented herein. Satellite images, hydrometeorological and river discharge data were analyzed; mean and variance tests were conducted to determine temporal homogeneity.Historical pluviometric data analysis shows no corresponding precipitation reduction and temperature undergoes only a slight increase in the same period. On the other hand,evaporation is extremely high, higher than precipitation during most of the year, leaving alwaters of its tributaries are now occupied by a monoculture, Eucaliptus sp., used for paper production. Because of the decreased fluvial discharges, its lowlands, usually used for agriculture and pasture, are abandoned and partially eroded.