The migration of plate boundaries in SE Sicily: Influence on the large-scale kinematic model of the African promontory in southern Italy

A detailed field mapping, coupled with structural analyses and morphological investigation, has been carried out along the northern and western borders of the Hyblean Plateau (SE Sicily), in order to define the nature and the kinematics of a major Quaternary fault belt. This, here designed as the Scicli Line Fault Belt, is composed of two N50 oriented extensional basins that, linked by a regional N10 trending transfer zone, originated during the Early Pleistocene and experienced, since the Late Quaternary, a positive tectonic inversion. In both the two stages of deformation, the Scicli Line Fault Belt has been characterised by displacement-rate comparable with the relative velocities measured between the distinct plates composing the central Mediterranean region. In the period going from 1.5–1.2 to 0.85 Ma, the fault belt accommodated the entire divergence between Adria and Nubia. At present, the Scicli Line Fault Belt absorbs most of the Nubia–Eurasia convergence, while the western divergent margin of the Adria microplate has jumped to the eastern and the southern margins of the Hyblean Plateau, along the Late Quaternary Siculo–Calabrian Rift Zone. The off-shore prolongation of the two tectonic boundaries of the Hyblean Plateau has been recognised in the Sicily Channel, where they are both interrupted by a WNW-ESE oriented dextral fault. According to our reconstruction, the Hyblean Plateau represents an isolated lithospheric block, whose evolution can be related to the propagation of the western divergent margin of the Adria microplate, accompanied with the southward migration of the triple junction between Eurasia, Nubia and Adria. In this new large-scale kinematic picture, the GPS velocity measured in the Hyblean region, at the permanent site of NOTO, is actually representative of the local kinematics, rather than of the entire African promontory of southern Italy. This implies a correction of previous regional kinematic models based on combination of GPS vectors. In particular, our data constrain a new interpretation both for the kinematics along the E–W oriented Nubia–Eurasia margin, dominated by prevalent dextral deformation rather than reverse motions, and for the intraplate deformation in the Sicily Channel, within the Africa promontory, which would be dominated by a roughly N110° oriented extension. This conclusion has implication also on the mechanism and the origin of the Pantelleria–Linosa–Malta Rift that is here interpreted as a transtensive feature developed along a major transform fault, rather than the result of passive rifting induced by the Nubia–Eurasia collision, as it is currently interpreted.     

Evaluation of microwave-assisted acid extraction procedures for the determination of metal content and potential bioavailability in sediments

Acid extractions represent a simple and effective tool for the assessment of metal contamination, origin and bioavailability in the aquatic environment. Optimized microwave-assisted procedures utilizing two extractions (8 M HNO₃ and 1 M HCl) were developed. Particular attention was given to the evaluation of efficiency and selectivity of the developed procedures. This involved an examination of the sediment and the extraction residues by Mössbauer spectroscopy and X-ray diffractometry. These instrumental approaches were used to identify the geochemical phases associated with acid decomposition. Microwave digestion with 8 M HNO₃ produced an efficient solubilization of the most important metal-bearing phases and left unaffected only the minerals (quartz, feldspars, muscovite) with a negligible metal content, thus providing a good estimate of the total metal concentrations. The 1 M HCl extraction, despite the limitation due to the incomplete solubilization of pyrite and to the partial dissolution of sheet silicates, represents a simple and effective technique for providing an estimate of the bioavailable metal fraction in sediments. The combined use of the two microwave-assisted acid extractions can provide a rapid and simple approach for the risk assessment of metal-polluted sediments.     

Self-standing bent silicon crystals for very high efficiency Laue lens

Silicon mono-crystals have been bent thanks to a series of parallel superficial indentations on one of the largest faces of the crystals. This technique relies on irreversible compression of the crystal beneath and beside the indentations. This latter causes deformation with no need for external device, resulting in a uniform self-standing curvature within the crystal. Indented Si crystals have been characterized at European Synchrotron Radiation Facility using a monochromatic beam ranging from 150 to 700 keV. Crystals exhibited very high diffraction efficiency over a broad range of energy, peaking 95% at 150 keV. Measured angular spread of the diffracted beam was always very close to the morphological curvature of the sample under investigation, proving that the energy passband of bent crystals can be controlled by simply imparting a selected curvature to the sample. The method of superficial indentations was found to offer high reproducibility and easy control of diffraction properties of the crystals. Moreover the method is cheap and simple, being based on mass production tools. A Laue lens made of crystals bent by superficial indentations can provide high-efficiency concentration of hard x-ray photons, leading significant improvement in many astrophysical applications.     

3D Subsoil Model of the San Biagio ‘Salinelle’ Mud Volcanoes (Belpasso,Sicily) derived from Geophysical Surveys

Mud volcanoes are common in active mountain fronts. At Mt. Etna, located just between the Apennine front in Sicily and its foredeep, there are some manifestations of mud volcanism in the lower border of the volcanic edifice. The activity of these mud volcanoes is characterized by persistent emission of muddy water mixed with salts, which rises to the surface due to the gas pressure in the subsoil. The San Biagio Salinelle is one of the three mud volcano fields located around the Paternò eruptive monogenic apparatus; this old volcanic structure was one of the first subaerial volcanic manifestations that formed in the pre-Etnean phase. It is not fully clear whether and how the activity of the mud fields is connected with the volcanic activity of Mt. Etna. Noninvasive geophysical surveys were carried out in the area of the active cone of the San Biagio Salinelle, in order to identify the probable ascent path of the emitted products. Seismic ambient noise records were collected at the nodes of a specially designed grid and, subsequently, the V _s values were obtained from an active seismic survey. A digital elevation model (DEM) of the area was obtained by a topographic survey, carried out with the GNSS technique (global navigation satellite system), in real-time kinematic mode. The DEM and the topographic benchmark installed will represent the reference surface for future periodic monitoring of the ongoing deformation in the area. Our results provide an accurate and detailed 3D subsurface model showing the shallower feeding system of the investigated mud volcano.     

Guagua pichincha volcano, Ecuador: fluid geochemistry in volcanic surveillance

The densely populated metropolitan area of Quito is located on the slopes of the active Guagua Pichincha volcano at only 10 km from the crater. Recently, the Italian Ministry of Foreign Affairs sponsored a project for the mitigation of volcanic hazard in this area. The geochemical study carried out as part of this project was aimed at constructing a geochemical model of the zone for use in volcanic surveillance.According to this geochemical model, a hydrothermal aquifer (T = 200–240°C), fed both by meteoric waters and by fluids released by a magma body, lies at shallow levels beneath Guagua Pichincha crater. The crater fumaroles are essentially fed by steam boiled off from the hydrothermal aquifer. The high flow rate fumaroles located in the dome area show significant SO₂ contents, which suggest a relatively high contribution of magmatic fluids in the zone of the aquifer feeding them. The absence of SO₂ in the fumarolic discharges near the southern crater wall indicates instead that the magmatic fluids dissolve entirely into the aquifer here. The hot springs located at the western end of the crater represent the lateral discharge of the hydrothermal aquifer.On the basis of this model, it is likely that an increment in the flux of both the magmatic fluids and the heat from a magma body produces an increase, albeit small, of the pressure-temperature conditions of the hydrothermal system and consequent changes in flow rate and fluid chemistry of the fumarolic vents. In particular, total sulphur and possibly hydrochloric acid may increase in all the vents and sulphur dioxide may appear in other fumarolic discharges. The varying thermodynamic conditions in the hydrothermal aquifer can be evaluated on the basis of the equilibria among carbon species and hydrogen. Only minor delayed changes are expected in the physical-chemical characteristics of the springs located at the western end of the crater.