Fluid-calcite-calcite dihedral angles have been measured for fluids in the system H2O−CO2−NaCl, between 1 and 2 kbar, and 550–750° C. It is found that the calcite-calcite-H2O dihedral angle decreases steadily with addition of NaCl from a value of about 80° (pure water) to 44° (60 wt% NaCl). The
CO2−H2O system displays a well-defined minimum at
, with a dihedral angle of 50°, in contrast to those of pure CO2 and H2O which are 90° and 80° respectively. Experiments containing fluids which are immiscible at run conditions showed a bimodal
distribution of dihedral angles in the CO2−H2O−NaCl system, which can be approximately correlated with the compositions of the two fluid phases. Such bimodality was only
observed for immiscible fluids in the H2O−NaCl system if the quench rate exceeded about 200°C per min. This is probably due to the extremely rapid establishment of
the single phase dihedral angle on quenching. The fluid phase topology in devolatilising marbles will only be a connected
network for very saline brines and fluids with
close to 0.5. Fluids trapped in fluid inclusions in calcite grains in marbles may be predominantly H2O-rich or CO2-rich, and of low salinity. All other fluid compositions in the H2O−CO2−NaCl-calcite system will occupy isolated pores, the largest of which will grow at the expense of the smallest. Escape of
fluid produced during devolatilisation reactions under such conditions will occur by fluid overpressuring and hydrofracture.
In contrast, previous experimental studies of quartz-fluid dihedral angles between 950° and 1100° C (Watson and Brenan 1987)
predict that quartz-dominated lithologies will permit pervasive flow of H2O−NaCl fluids, but not of H2O−CO2 fluids. Documented geological examples of differences in permeability and fluid flow mechanism between metamorphic argillites,
psammites and limestones which support the results of the experimental studies are discussed. 相似文献
The 168 m-thick Shiant Isles Main Sill is a composite body, dominated by an early, 24 m-thick, picrite sill formed by the intrusion of a highly olivine-phyric magma, and a later 135 m-thick intrusion of olivine-phyric magma that split the earlier picrite into a 22 m-thick lower part and a 2 m-thick upper part, forming the picrodolerite/crinanite unit (PCU). The high crystal load in the early picrite prevented effective settling of the olivine crystals, which retain their initial stratigraphic distribution. In contrast, the position of the most evolved rocks of the PCU at a level ~80% of its total height point to significant accumulation of crystals on the floor, as evident by the high olivine mode at the base of the PCU. Crystal accumulation on the PCU floor occurred in two stages. During the first, most of the crystal load settled to the floor to form a modally and size-sorted accumulation dominated by olivine, leaving only the very smallest olivine grains still in suspension. The second stage is recorded by the coarsening-upwards of individual olivine grains in the picrodolerite, and their amalgamation into clusters which become both larger and better sintered with increasing stratigraphic height. Large clusters of olivine are present at the roof, forming a foreshortened mirror image of the coarsening-upwards component of the floor accumulation. The coarsening-upwards sequence records the growth of olivine crystals while in suspension in a convecting magma, and their aggregation into clusters, followed by settling over a prolonged period (with limited trapping at the roof). As olivine was progressively lost from the convecting magma, crystal accumulation on the (contemporaneous) floor of the PCU was increasingly dominated by plagioclase, most likely forming clusters and aggregates with augite and olivine, both of which form large poikilitic grains in the crinanite. While the PCU is unusual in being underlain by an earlier, still hot, intrusion that would have enhanced any driving force for convection, we conclude from comparison with microstructures in other sills that convection is likely in tabular bodies >100 m thickness. 相似文献
Deep mining of mineral resources causes extensive changes in rock environment and ground morphology and must be considered in the land use planning. Subsidence as a result of underground mining activities in terrains is one of the serious geological hazards because they can effect slopes and damage engineering structures, settlement areas, natural lakes and allow infiltration of contaminant into the groundwater. The main aim of this article was implementation of the building site categories of underground mining regions into the land use plans. This case study area was selected from the region of Orlova town within the Ostrava-Karvina Coal district, and this region is one of the most affected areas by underground mining of black coal in the Czech Republic. Certain risk categories of land, where the individual categories express generalized influence of deep mining of coal in current and planned constructions were also represented in this article. Extensive variations caused by underground mining were identified within a wide variability of risk categories. An important finding was also the extensive variability over time, manifested by spatial variations in the stated categories in the studied time periods. Moreover, technical documentation of environmental impacts related to underground mining activities was provided; importance of existing and proposed underground mining projects that may significantly impact the land use was discussed and pointed out in this article, especially. 相似文献
A new mechanism for the generation of the electric ring current is presented. During the radial bombardment of a rotating
gas torus by a neutral beam, electrons and protons are dragged by rotating gas. Due to collisions electrons obtain the torus
velocity faster than protons, therefore in some layer there is a difference in electron and proton beam toroidal velocities;
the electric current is thus generated. This current is discussed as the seed magnetic field in early stages of evolving galaxies,
which is then amplified by the dynamo process to present values of the magnetic field.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
Abstract– On April 9, 2009, at 3:00 CEST, a very bright fireball appeared over Carinthia and the Karavanke Mountains. The meteoroid entered the atmosphere at a very steep angle and disintegrated into a large number of objects. Two main objects were seen as separate fireballs up to an altitude of approximately 5 km, and witnesses reported loud explosions. Three stones were found with a total weight of approximately 3.611 kg. The measured activity of short‐lived cosmogenic radionuclides clearly indicates that two specimens result from a very recent meteorite fall. All cosmogenic radionuclide concentrations suggest a rather small preatmospheric radius of <20 cm; a nominal cosmic‐ray exposure age based on 21Ne is approximately 4 Ma, but the noble gas and radionuclide results in combination indicate a complex irradiation. Jesenice is a highly recrystallized rock with only a few relic chondrules visible in hand specimen and thin section. The texture, the large grain size of plagioclase, and the homogeneous compositions of olivines and pyroxenes clearly indicate that Jesenice is a L6 chondrite. The bulk composition of Jesenice is very close to the published average element concentration for L ordinary chondrites. The chondrite is weakly shocked (S3) as indicated by the undulatory extinction in olivine and plagioclase and the presence of planar fractures in olivine. Being weakly shocked and with gas retention ages of >1.7 Ga (4He) and approximately 4.3 Ga (40Ar), Jesenice seems not to have been strongly affected by the catastrophic disruption of the L‐chondrite parent body approximately 500 Ma ago. 相似文献
WITS-1 is a sample of silicified komatiite collected from close to the Komati River type section, near Barberton in South Africa. Two thousand kg of this komatiite was crushed and prepared for standardization. Noble metal analysis of WITS-1 has been carried out by six laboratories using four different analytical methods. The data obtained from these sources were subjected to statistical analysis (F ratio and Student t test) and a suite of "preferred" values for the noble metal concentrations are reported. 相似文献
An understanding of solar variability over a broad spectral range and broad range of timescales is needed by scientists studying Earth’s climate. The Total and Spectral Solar Irradiance Sensor (TSIS) Spectral Irradiance Monitor (SIM), is designed to measure solar spectral irradiance (SSI) with unprecedented accuracy from 200 nm to 2400 nm. SIM started daily observations in March 2018. To maintain its accuracy over the course of its anticipated 5-year mission and beyond, TSIS SIM needs to be corrected for optical degradation, common for solar viewing instruments. The differing long-term trends of various independent solar-irradiance records attest to the challenge at hand.
The correction of TSIS SIM for optical degradation is based on piecewise linear fits that bring the three instrument channels into agreement. It is fundamentally different to the correction applied to the TSIS SIM predecessor on SORCE. The correction facilitates reproducibility, uncertainty estimation and is measurement-based. Corrected, integrated TSIS SIM SSI agrees with independent observations of total solar irradiance to within 45 ppm as well as various solar-irradiance models. TSIS SIM SSI is available at: http://lasp.colorado.edu/lisird/.