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191.
Maria Czaja Mariola Kądziołka-Gaweł Radosław Lisiecki Sabina Bodył-Gajowska Zbigniew Mazurak 《Physics and Chemistry of Minerals》2014,41(2):115-126
For the first time ever, the luminescence spectra of Cr3+ centers in two chlorite crystals are presented. Chromium ions occupy the strong crystal-field site M4 in the brucite sheet and the intermediate crystal-field site in the inner octahedral sheet for purple and green chlorite, respectively. We discuss the influence of an effective positive charge on the Cr3+ ion and an effective negative charge of ligands on the differences in the values of the Dq and B parameters. It is concluded that the presence of Fe2+ ions and other point defects, as well as concentration quenching, causes the very short luminescence lifetimes of chromium ions. 相似文献
192.
Ionel Nicolae Ioan Seghedi Iuliu Boboş Maria do Rosário Azevedo Sara Ribeiro Mihai Tatu 《Chemie der Erde / Geochemistry》2014
An Early Permian volcanic assemblage is well exposed in the central-western part of the Apuseni Mountains (Romania). The rocks are represented by rhyolites, basalts and subordinate andesites suggesting a bimodal volcanic activity that is intimately associated with a post-orogenic (Variscan) syn-sedimentary intra-basinal continental molasse sequences. The mafic and mafic-intermediate rocks belong to sub-alkaline tholeiitic series were separated in three groups (I–III) showing a high Th and Pb abundances, depletion in Nb, Ta and Sr, and slightly enriched in LREE patterns (LaN/YbN = 1.4–4.4). Isotopically, the rocks of Group I have the initial ratios 87Sr/86Sr(i) = 0.709351–0.707112, 143Nd/144Nd(i) = 0.512490–0.512588 and high positive ?Nd270 values from 3.9 to 5.80; the rocks of Group II present for the initial ratios values 87Sr/86Sr(i) = 0.709434–0.710092, 143Nd/144Nd(i) = 0.512231–0.512210 and for ?Nd270 the negative values from −1.17 to −1.56; the rocks of Group III display for the initial ratios the values 87Sr/86Sr(i) = 0.710751–0.709448, 143Nd/144Nd(i) = 0.512347–0.512411 and for ?Nd270 the positive values from 1.64 to 2.35. The rocks resembling continental tholeiites, suggest a mantle origin and were further affected by fractionation and crustal contamination. In addition, the REE geochemistry (1 > SmN/YbN < 2.5; 0.9 > LaN/SmN < 2.5) suggests that these rocks were generated by high percentage partial melting of a metasomatized mantle in the garnet peridotite facies. The felsic rocks are enriched in Cs, Rb Th and U and depleted in Nb, Ta, Sr, Eu, and Ti. The REE fractionation patterns show a strong negative Eu anomaly (Eu/Eu* = 0.23–0.40). The felsic rocks show the initial ratios the values: 87Sr/86Sr(i) = 0.704096–0.707805, 143Nd/144Nd(i) = 0.512012–0.512021 and for ?Nd270 the negative values from −5.27 to −5.44. They suggest to be generated within the lower crust during the emplacement of mantle-derived magmas that provided necessary heat to crustal partial melting. 相似文献
193.
The Neogene quartz andesites from the Oa? and Gutâi Mountains (Romania) are mid-K calc-alkaline rocks and contain plagioclase-orthopyroxene-clinopyroxene-amphibole-magnetite phenocrysts as well as quartz crystals. They are associated with a volcanic sequence ranging from basalts and basaltic andesites to dacites and rhyolites, but form a separate magma group, mostly in respect to the trace elements. Based on the geochemical data combined with inferences from complex zoning patterns in plagioclase and pyroxene, the evolution of quartz andesites is interpreted in terms of fractional crystallization, AFC and magma mixing. A parental magma deriving from a MORB- or OIB-type source modified by fluids and melts originating from sediments is envisaged. 相似文献
194.
Corridor location: the multi-gateway shortest path model 总被引:2,自引:1,他引:1
Maria P. Scaparra Richard L. Church F. Antonio Medrano 《Journal of Geographical Systems》2014,16(3):287-309
The problem of corridor location can be found in a number of fields including power transmission, highways, and pipelines. It involves the placement of a corridor or rights-of-way that traverses a landscape starting at an origin and ending at a destination. Since most systems are subject to environmental review, it is important to generate competitive, but different alternatives. This paper addresses the problem of generating efficient, spatially different alternatives to the corridor location problem. We discuss the weaknesses in current models and propose a new approach which is designed to overcome many of these problems. We present an application of this model to a real landscape and compare the results to past work. Overall, the new model called the multi-gateway shortest path problem can generate a wide variety of efficient alignments, which eclipse what could be generated by past work. 相似文献
195.
Javier Tomasella Laura S. Borma José A. Marengo Daniel A. Rodriguez Luz A. Cuartas Carlos A. Nobre Maria C. R. Prado 《水文研究》2011,25(8):1228-1242
Severe hydrological droughts in the Amazon have generally been associated with strong El Niño events. More than 100 years of stage record at Manaus harbour confirms that minimum water levels generally coincide with intense warming in the tropical Pacific sea waters. During 2005, however, the Amazon experienced a severe drought which was not associated with an El Niño event. Unless what usually occurs during strong El Niño events, when negative rainfall anomalies usually affect central and eastern Amazon drainage basin; rainfall deficiencies in the drought of 2005 were spatially constrained to the west and southwest of the basin. In spite of this, discharge stations at the main‐stem recorded minimum water levels as low as those observed during the basin‐wide 1996–1997 El Niño‐related drought. The analysis of river discharges along the main‐stem and major tributaries during the drought of 2004–2005 revealed that the recession on major tributaries began almost simultaneously. This was not the case in the 1996–1997 drought, when above‐normal contribution of some tributaries for a short period during high water was crucial to partially counterbalance high discharge deficits of the other tributaries. Since time‐lagged contributions of major tributaries are fundamental to damp the extremes in the main‐stem, an almost coincident recession in almost all tributaries caused a rapid decrease in water discharges during the 2005 event. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
196.
In the summer of 2008 the Prut river recorded a historical flow of 7140 m3/s at its entrance into Romania. This flow was the highest ever recorded of any Romanian river. The high value was generated by high amounts of rainfall recorded first on the territory of Ukraine and then in Romania. Unfortunately, there were some discrepancies between the data transmitted and intercepted from the Meteorology National Agency and Hydrology and Water Management National Agency. This is why the amount of precipitation which fell over the territory of Ukraine could not be monitored in time and punctually. Nor could the high flood wave moving rapidly from the upper basin to the lower basin. The high flow of the upper Prut caused the accumulation of an immense quantity of water in the Stanca–Costesti reservoir. Under the conditions of precipitation occurring in the lower river basin as well, the levels reached the flood quota and the reservoir reached the maximum accepted capacity, with 0·1% insurance. The release of supplementary water quantities from the reservoir would have produced catastrophic floods downstream. Keeping the water in the reservoir could have broken it and the flooding, through backwater eddies, or the riverbank settlements. In such a case, it would have produced the greatest tragedy in the hydrological history of Europe. The most significant damage was produced upstream of the barrage, next to the localities of Radauti Prut and Baranca–Hudesti, as well as in the area of the reservoir, as a result of the phenomenon known as ‘remuu’, or backwater eddies. The floods of the Prut river occurred between the end of July and the end of August. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
197.
Anne M. Larson Maria Brockhaus William D. Sunderlin Amy Duchelle Andrea Babon Therese Dokken Thu Thuy Pham I.A.P. Resosudarmo Galia Selaya Abdon Awono Thu-Ba Huynh 《Global Environmental Change》2013,23(3):678-689
A number of international donors, national governments and project proponents have begun to lay the groundwork for REDD+, but tenure insecurity – including the potential risks of land grabbing by outsiders and loss of local user rights to forests and forest land – is one of the main reasons that many indigenous and other local peoples have publicly opposed it. Under what conditions is REDD+ a threat to local rights, and under what conditions does it present an opportunity? This article explores these issues based on available data from a global comparative study on REDD+, led by the Center for International Forestry Research, which is studying national policies and processes in 12 countries and 23 REDD+ projects in 6 countries. The article analyses how tenure concerns are being addressed at both national and project level in emerging REDD+ programs. The findings suggest that in most cases REDD+ has clearly provided some new opportunities for securing local tenure rights, but that piecemeal interventions by project proponents at the local level are insufficient in the absence of broader, national programs for land tenure reform. The potential for substantial changes in the status quo appear unlikely, though Brazil – the only one with such a national land tenure reform program – offers useful insights. Land tenure reform – the recognition of customary rights in particular – and a serious commitment to REDD+ both challenge the deep-rooted economic and political interests of ‘business as usual’. 相似文献
198.
María Eugenia Varela Gero Kurat Ernst Zinner Peter Hoppe Theodoros Ntaflos Mikhail A. Nazarov 《Meteoritics & planetary science》2005,40(3):409-430
Abstract— D'Orbigny is an exceptional angrite. Chemically, it resembles other angrites such as Asuka‐881371, Sahara 99555, Lewis Cliff (LEW) 87051, and LEW 86010, but its structure and texture are peculiar. It has a compact and porous lithology, abundant glasses, augite‐bearing druses, and chemical and mineralogical properties that are highly unusual for igneous rocks. Our previous studies led us to a new view on angrites: they can possibly be considered as CAIs that grew to larger sizes than the ones we know from carbonaceous chondrites. Thus, angrites may bear a record of rare and special conditions in some part of the early solar nebula. Here we report trace element contents of D'Orbigny phases. Trace element data were obtained from both the porous and the compact part of this meteorite. We have confronted our results with the popular igneous genetic model. According to this model, if all phases of D'Orbigny crystallized from the same system, as an igneous origin implies, a record of this genesis should be expressed in the distribution of trace elements among early and late phases. Our results show that the trace element distribution of the two contemporaneous phases olivine and plagioclase, which form the backbone of the rock, seem to require liquids of different composition. Abundances of highly incompatible elements in all olivines, including the megacrysts, indicate disequilibrium with the bulk rock and suggest liquids very rich in these elements (>10,000 x CI), which is much richer than any fractional crystallization could possibly produce. In addition, trace element contents of late phases are incompatible with formation from the bulk system's residual melt. These results add additional severe constraints to the many conflicts that existed previously between an igneous model for the origin of angrites and the mineralogical and chemical observations. This new trace element content data, reported here, corroborate our previous results based on the shape, structure, mineralogy, chemical, and isotopic data of the whole meteorite, as well as on a petrographic and chemical composition study of all types of glasses and give strength to a new genetic model that postulates that D'Orbigny (and possibly all angrites) could have formed in the solar nebula under changing redox conditions, more akin to chondritic constituents (e.g., CAIs) than to planetary differentiated rock. 相似文献
199.
Maria Dina Vivarelli 《Celestial Mechanics and Dynamical Astronomy》1994,60(3):291-305
This paper is an attempt to bring unity in the study of the classical Kepler problem by combining, through simple vectorial and quaternionic techniques, its two peculiar aspects: the determination of the constants of the motion and the regularization at the origin.Research supported by the Consiglio Nazionale delle Ricerche of Italy (C.N.R.-G.N.F.M.). 相似文献
200.
Shiro Kohshima Nozomu Takeuchi Jun Uetake Takayuki Shiraiwa Ryu Uemura Naohiro Yoshida Sumito Matoba Maria Angelica Godoi 《Global and Planetary Change》2007,59(1-4):236
Snow algae in a 45.97-m-long ice core from the Tyndall Glacier (50°59′05″S, 73°31′12″W, 1756 m a.s.l.) in the Southern Patagonian Icefield were examined for potential use in ice core dating and estimation of the net accumulation rate. The core was subjected to visual stratigraphic observation and bulk density measurements in the field, and later to analyses of snow algal biomass, water isotopes (18O, D), and major dissolved ions. The ice core contained many algal cells that belonged to two species of snow algae growing in the snow near the surface: Chloromonas sp. and an unknown green algal species. Algal biomass and major dissolved ions (Na+, K+, Mg2+, Ca2+, Cl−, SO42−) exhibited rapid decreases in the upper 3 m, probably owing to melt water elution and/or decomposition of algal cells. However, seasonal cycles were still found for the snow algal biomass, 18O, D-excess, and major ions, although the amplitudes of the cycles decreased with depth. Supposing that the layers with almost no snow algae were the winter layers without the melt water essential to algal growth, we estimated that the net accumulation rate at this location was 12.9 m a− 1 from winter 1998 to winter 1999, and 5.1 m from the beginning of winter to December 1999. These estimates are similar to the values estimated from the peaks of 18O (17.8 m a− 1 from summer 1998 to summer 1999 and 11.0 m from summer to December 1999) and those of D-excess (14.7 m a− 1 from fall 1998 to fall 1999 and 8.6 m a− 1 from fall to December 1999). These values are much higher than those obtained by past ice core studies in Patagonia, but are of the same order of magnitude as those predicted from various observations at ablation areas of Patagonian glaciers. 相似文献